CAS: 21797-13-7; Tetrakis(Acetonitrile)Palladium(Ii) Tetrafluoroborate

该化合物是一个协调综合体,以+2氧化状态中的为主,与四种丙烯-相协调,与4种丙诺-丁基离子相联,与一种四氟基反差相关,其特点是黄色和浅褐色表面,可溶于丙诺三烯和二甲基硫氧化物等极地有机溶剂中.中心展示了一种平方平面平面几何测量法,这是d8金属复合体中常见的,有助于其稳定性和再活动.在有机合成中经常使用四氟乙烷(二)四氟丁酸,特别是交叉相撞反应,因为其能够促进碳结的形成.其再活动可能受到四氟丙酸聚物离子的存在的影响,这是一种微弱的协调离子,使得中心能够与子基相协调.在处理该复合物时,应当注意安全防范措施,因为钚复合物可以是有毒的,应当与防护性设备加以妥善管理.

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CAS号429-42-5 四丁基四氟硼酸铵 | CAS号3375-31-3 醋酸钯 | CAS号75-05-8 乙腈

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    专利信息


    专利号:US-11059835-B2
    优先权日:2014-08-15
    标 题 :Synthesis of cephalosporin compounds
    发明人:WALLER DAVID; GAZDA GREGORY; MINDEN ZACHARY; BARTON LISA; LEIGH CLIFTON
    权利人:MERCK SHARP & DOHME
    摘要:Provided herein is a method for the synthesis of cephalosporin antibiotic compounds comprising a palladium-catalyzed coupling reaction.

    专利号:US-5703201-A
    优先权日:1995-10-10
    标题:Catalyst for polymerization of polyketone formed by treatment with carbon monoxide and olefin
    发明人:HANNA PAUL K
    权利人:AKZO NOBEL NV
    摘要:A process for the synthesis of a catalyst for the polymerization of carbon monoxide and at least one olefin which comprises treating a mixture of a compound of palladium, such as tetrakis(acetonitrile) palladium, and a Lewis acid anion, such as a fluoride of a metal selected from Group III to Group V of the Periodic Table (e.g., boron trifluoride), with carbon monoxide and an olefin followed by reaction of the resulting composition with a bidentate ligand reagent, such as a 1,3-bis(diphenyl-phosphino) alkane (e.g., 1,3-bis(diphenyl-phosphino) propane).

    专利号:US-10457640-B2
    优先权日:2016-10-19
    标 题:Synthesis of inhibitors of EZH2
    发明人:VASWANI RISHI G; HEWITT MICHAEL CHARLES
    权利人:CONSTELLATION PHARMACEUTICALS INC
    摘要:Provided herein are synthetic methods for the preparation of EZH2 inhibitors.

    专利号:US-7071314-B2
    优先权日:2001-05-30
    标题:Arylation method for the functionalization of O-allyl erythromycin derivatives
    发明人:ZHANG WEIJANG; HSU MARGARET CHI-PING; HAIGHT ANTHONY R; PETERSON MATTHEW JOHN; NARAYANAN BIKSHANDARKOIL A
    权利人:ABBOTT LAB
    摘要:An efficient arylation technique for use in the synthesis of erythromycin derivatives, involving a modified Heck reaction which employs less than six mole percent of palladium catalyst and no phosphine is disclosed. With this modified Heck reaction, an O-alkenylaryl macrolide can be obtained in a much shorter reaction time than under conventional Heck reaction conditions. The modified Heck reaction can be utilized in a method for phosphine-free arylation of an O-allylic erythromycin derivative, in a method for preparing an O-alkenylaryl erythromycin A derivative, or in a method for preparing a 2′, 4″-hydroxyl protected 6-O-alkenylaryl erythromycin A derivative.

    专利号:US-2019233375-A1
    优先权日:2016-10-19
    标题:Synthesis of inhibitors of ezh2

    专利号:EP-3180347-B1
    优先权日:2014-08-15
    标 题:Synthesis of cephalosporin compounds

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    合成参考文献


    摘要:Bubnov, Yu. N.; Kolomnikova, G. D., Science of Synthesis Knowledge Updates, (2012) 3, 287.
    摘要:Silva, V. L. M.; Pinto, D. C. G. A.; Santos, C. M. M.; Rocha, D. H. A., Science of Synthesis Knowledge Updates, (2022) 3, 229.
    摘要:Kubik, S., Science of Synthesis Knowledge Updates, (2013) 3, 286.
    摘要:González-Bello, C., Science of Synthesis Knowledge Updates, (2018) 1, 233.
    摘要:Anderson, E. A.; Gockel, B., Science of Synthesis Knowledge Updates, (2010) 3, 216.
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