CAS: 16727-30-3; Malvidin 3,5-Di-O-β-Glucopyranoside Chloride

该化合物是一种自然产生的炭疽素,一种在各种水果,特别是葡萄和红酒中发现的花粉色,其特点是深红色至紫色,导致许多浆果和葡萄酒制品的染色.该化合物是一个糖质,意思是它由附于aglycone(anthocyanin部分)的糖份组成,具体地说,是marvidin,它有助于水的稳定性和溶解性. Malvidin 3,5-diglucoside因其抗氧化性特性而著称,它能够帮助保护细胞免受氧化性压力,并可能有助于与水果和红酒的消费相关的各种健康利益.该化合物对pH变化十分敏感,因为它会影响其颜色和稳定性,使它成为食品科技的一个重要因素.此外,还研究过它对于它在提高食品和饮料的感官质量方面的潜在作用,以及它对健康和营养的影响.

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上下游产品

29H36O18C29H36O18hirsutrin 29H36O18C29H36O18

合成工艺路线路线简述

  • 合成目标产物 Malvin Chloride 主要起始原料 Ethanamine, N-[(3,5-Dichlorophenyl)Methylene]-2,2-Diethoxy-
  • (文献来源)合成步骤主要原料 Ethanamine, N-[(3,5-Dichlorophenyl)Methylene]-2,2-Diethoxy-
📜以 重水 用作溶剂,化学反应生成氯化锦葵色素苷
参考文献:一维和二维核磁共振法阐明马尔文在水溶液中的多重平衡
标题:一维和二维核磁共振法阐明马尔文在水溶液中的多重平衡
摘要:摘要 一维和二维 NMR 用于表征在 Ph 值范围 0.3-4.5 的水溶液中存在的几种形式的马尔文,并确定它们的摩尔分数作为 Ph 值的函数.除了黄酮阳离子,两种半缩醛形式以及查耳酮的顺式和反式两种形式都得到了明确的鉴定.推导出了不同形式相互转化的途径,并通过耦合 NMR 和 Uv/vis 数据计算了物质的摩尔吸光度.在不同温度下确定平衡常数,并计算互变过程的焓和熵变化.这些结论得到了分子轨道计算的支持.
Doi:10.1016/0031-9422(93)85054-U

海关参考信息

专利信息


专利号:US-2007232495-A1
优先权日:2006-03-24
标题:Compositions and methods to add value to plant products, increasing the commercial quality, resistance to external factors and polyphenol content thereof
发明人:NAPPA ALVARO O; LORENZINI FELIPE C; SANHUEZA ANDRES L
权利人:NAPPA ALVARO O; LORENZINI FELIPE C; SANHUEZA ANDRES L
摘要:The invention is related to compositions and methods that naturally protect plant tissues against ultraviolet radiation and temperature, thus giving protection against sunburn to plants, plant parts, fruits and/or flowers during their development. The invention is also related to compositions and methods to naturally improve the color of plants, plant parts, fruits and/or flowers by inducing the natural synthesis of flavonoids and anthocyanins present in plants. Likewise, the present invention is directed to improving the nutritional value of plants, plant parts, fruits and/or flowers by increasing the normal levels of polyphenolic compounds, especially flavonoids, present therein. Additionally, the present invention is related to compositions and methods that give more resistance to plants, plant parts, fruits and/or flowers against pathogens as bacteria and fungi. Finally, the present invention is related to plants, plant parts, fruits, flowers and/or propagating material treated with the compositions described in the present document.

专利号:EP-2163619-B1
优先权日:2007-06-20
标 题 :Rose containing flavone and malvidin, and method for production thereof
发明人:TANAKA YOSHIKAZU; KATSUMOTO YUKIHISA; FUKUI YUKO; MIZUTANI MASAKO; NAKAMURA NORIKO; TOGAMI JUNICHI
权利人:SUNTORY HOLDINGS LTD
摘要:Disclosed is a rose characterized by containing a flavone and a malvidin by a genetic recombination technique. Typically, the flavone and the malvidin are produced by the expression of a flavone synthesis enzyme gene and the expression of a flavonoid 3',5'-hydroxylase gene originated from pansy (Viola x wittrockiana) and an anthocyanin methyltransferase gene, respectively, all introduced into the rose. The flavone synthesis enzyme gene may be one originated from a plant belonging to the family Scrophulariaceae, such as one originated from common snapdragon (Scrophulariaceae, Antirrhinum majus) and one originated from torenia (Scrophulariaceae, Torenia hybrida). The flavonoid 3',5'-hydroxylase gene may be one originated from pansy (Viola x wittrockiana). The anthocyanin methyltransferase gene may be one originated from torenia (Scrophulariaceae, Torenia hybrida).

专利号:US-5699479-A
优先权日:1995-02-06
标 题:Tonality for perceptual audio compression based on loudness uncertainty
发明人:ALLEN JONATHAN BRANDON; DORWARD SEAN MATTHEW; JOHNSTON JAMES DAVID; SYDORENKO MARK R
权利人:LUCENT TECHNOLOGIES INC
摘要:A new technique for the determination of the masking effect of an audio signal is employed to provide transparent compression of an audio signal at greatly reduced bit rates. The new technique employs the results of recent research into the psycho-physics of noise masking in the human auditory system. This research suggests that noise masking is a function of the uncertainty in loudness as perceived by the brain. Measures of loudness uncertainty are employed to form noise masking thresholds for use in the compression of audio signals. These measures are employed in an illustrative subband, analysis-by-synthesis framework. In accordance with the illustrative embodiment, provisional encodings of the audio signal are performed to determine the encoding which achieves a loudness differential, between the original and coded audio signal, which is less than (but not too far below) the loudness uncertainty.

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主要参考文献

参考标题:Synthesis Of 3-Methoxy- And 3-( -D-Glucopyranosyloxy)Flavylium Ions. Influence Of The Flavylium Substitution Pattern On The Reactivity Of Anthocyanins In Aqueous Solution
作者:Olivier Dangles,Hakima Elhajji |发布日期:1994.9.21
摘要:The Synthesis Of 3-Glycosyloxylated Flavylium Ions (Anthocyanins), In Particular Of Callistephin (4), A Natural Anthocyanin, Is Described. The Structural Transformations In Aqueous Solution And Molecular Complexation With Chlorogenic Acid (7) And Caffeine (8) Of The Synthesized Pigments 3 And 4 Are Investigated And Compared To Those Of The Corresponding 3-Methoxyflavylium Ions 1 And 2 And To Those

合成参考文献


参考文献:10.1021/jf9037419
摘要:Cruz L, Brás NF, Teixeira N, Mateus N, Ramos MJ, Dangles O, De Freitas V. Vinylcatechin dimers are much better copigments for anthocyanins than catechin dimer procyanidin b3. J Agric Food Chem. 2010 Mar 10;58(5):3159–66. doi: 10.1021/jf9037419.
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