CAS: 13885-09-1; 2-(Diphenylphosphino)Biphenyl

上下游产品

CAS号2113-51-1 2-碘联苯 | CAS号829-85-6 二苯基膦 | CAS号1942-82-1 (biphenyl-2-yl)... | CAS号2052-07-5 邻溴联苯 | CAS号1079-66-9 氯代二苯基膦 | CAS号583-55-1 2-溴碘苯 | CAS号2051-60-7 2-氯联苯 | CAS号98-80-6 苯硼酸 | CAS号62336-24-7 (2-溴苯基)二苯基膦 | CAS号88652-74-8 1-bromo-2-diphe... | CAS号1088-00-2 5-苯基-5H-苯并[b]磷代吲哚

邻碘溴苯置于potassium Phosphate,四(三苯基膦)钯,三氯硅烷,双氧水,三乙胺,三苯基膦,Bis(Dibenzylideneacetone)-Palladium(0)体系中,用 1,4-二氧六环,甲醇,水,甲苯 用作溶剂,化学反应 29.0H,反应生成2-二苯基膦-联苯
参考文献:钌催化的叔膦c-h芳基化
标题:钌催化的叔膦c-h芳基化
摘要:设计了一种由钌(II)配合物催化的叔膦配体位点优先单ch芳基化的通用方案.该协议可以以中等到极好的收率获得一系列以克为单位的修饰的布赫瓦尔德-联芳基单膦.从通过esi-Ms观测到的中间体的知识中提出了催化循环.重要的是,这些单芳基化产物可以进一步转化为二苯并磷腈衍生物.
Doi:10.1021/acs.Orglett.9B00888

专利信息

专利号:US-11718584-B2
优先权日:2019-02-22
标题 :Process for the synthesis anthranilic diamide compounds and intermediates thereof
发明人：KARRI PHANEENDRASAI; PABBA JAGADISH; SHINDE BHARAT UTTAMRAO; KALWAGHE AMOL DNYANESHWAR; MADHAVRAO KAMBLE MARUTI; KLAUSENER ALEXANDER G M; PANMAND DEEPAK SHANKAR
权利人:PI INDUSTRIES LTD
摘要:The present invention disclosed a process for the synthesis of anthranilic diamide compound of formula (I), n n n n n n n n n n wherein, R 1 , R 2 , R 3a , R 3b , R 3c , R 4 , R 5 , R 6 and Z are as defined in the detailed description. The process comprising the step of obtaining a mono- or dicyano substituted aniline compound of formula (IV) which is then converted to an anthranilic acid compound of formula (V) or an anthranilic amide compound of formula (Va). Further, the compound of formula (VI) can be optionally synthesized from compound of formula (IV or V or Va)

专利号:US-5110955-A
优先权日:1989-04-14
标 题:Tocopherol synthesis: chromane cyclization and catalysis
发明人：KNIERZINGER ANDREAS; SCALONE MICHELANGELO
权利人:HOFFMANN LA ROCHE
摘要:The invention relates to a process for the manufacture of vinylchromanes. This process is concerned with the manufacture of the compounds having the formula ##STR1## wherein R o is hydrogen or a cleavable protecting group, and comprises cyclizing a compound having the formula ##STR2## wherein R o is defined above and R 1 is n n --CH.sub.2 --CH.sub.2 --C(W)(CH.sub.3)--CHâ•?CH.sub.2 or n n n --CH.sub.2 --CH.sub.2 C(CH.sub.3)â•?CH--CH.sub.2 --W n n where W is a leaving group, n by means of a chiral transition metal-diphosphine complex. n The compounds of formula I are useful intermediates, e.g. in the manufacture of (R,R,R)-α-tocopherol.

专利号:US-9884842-B2
优先权日:2013-04-19
标题 :Combretastatin analogs
发明人：PENTHALA NARSIMHA REDDY; CROOKS PETER; SONAR VIJAYAKUMAR
权利人:UNIV ARKANSAS; BIOVENTURES LLC
摘要:The present invention relates novel heterocyclic analogs of combretastatin, their synthesis, and their use as anti-cancer compounds. In particular, compounds of Formula (I), Formula (II), and Formula (V) are provided.

专利号:CN-107903276-A
优先权日:2017-11-17
标题 :A kind of asymmetric synthesis method of ring E of harringtonine skeleton

专利号:CN-107903276-B
优先权日:2017-11-17
标 题 :A kind of asymmetric synthesis method of ring E of harringtonine skeleton

专利号:CN-112250709-A
优先权日:2020-10-22
标 题 :Synthesis method of ortho-aryl substituted tertiary phosphine compound