CAS: 13463-28-0; (S)-2-(3,4-Dihydroxyphenyl)-5-Hydroxy-7-(((2S,3R,4S,5S,6R)-3,4,5-Trihydroxy-6-((((2R,3R,4R,5R,6S)-3,4,5-Trihydroxy-6-Methyltetrahydro-2H-Pyran-2-yl)Oxy)Methyl)Tetrahydro-2H-Pyran-2-yl)Oxy)Chroman-4-One
该化合物是一种主要在柑橘水果,特别是柠檬和柠檬中发现的氟芳烃化合物,以其抗氧化性特性而著称,有助于其潜在的健康惠益,包括抗炎效应和心脏保护效应;乙酰丙烯是一种花草甘甘烃,其特征是其结构包括一种含糖味的氟芳烃脊椎;该化合物在水中溶解,呈现出一种黄色的颜色,是许多花草的典型;其化学公式反映了多种氢氧化合物的存在,这些化合物是其反应和与自由基体互动的原因;乙酰丙烯因其在增强食品稳定性和储存寿命方面的潜在作用,以及其在预防慢性疾病方面可能的治疗用途,因此对食品科学和营养产生了兴趣;此外,目前正在进行的研究正在探讨其对代谢性健康的影响及其在改变各种生物途径方面的作用.
- 英文名称(S)-2-(3,4-Dihydroxyphenyl)-5-Hydroxy-7-(((2S,3R,4S,5S,6R)-3,4,5-Trihydroxy-6-((((2R,3R,4R,5R,6S)-3,4,5-Trihydroxy-6-Methyltetrahydro-2H-Pyran-2-yl)Oxy)Methyl)Tetrahydro-2H-Pyran-2-yl)Oxy)Chroman-4-One
- 中文名称圣草次甙
- IUPAC名称(S)-2-(3,4-dihydroxyphenyl)-5-hydroxy-7-(((2S,3R,4S,5S,6R)-3,4,5-trihydroxy-6-((((2R,3R,4R,5R,6S)-3,4,5-trihydroxy-6-methyltetrahydro-2H-pyran-2-yl)oxy)methyl)tetrahydro-2H-pyran-2-yl)oxy)chroman-4-one
- 其它别名(S)-7-((6-O-(6-Deoxy-Alpha-L-Mannopyranosyl)-Beta-D-Glucopyranosyl)Oxy)-2-(3,4-Dihydroxyphenyl)-2,3-Dihydro-5-Hydroxy-4H-Benzopyran-4-One; Omqadrgfmlgfjf-Mnpjbklosa-N; 4H-1-Benzopyran-4-One, 7-[[6-O-(6-Deoxy-.Alpha.-L-Mannopyranosyl)-.Beta.-D-Glucopyran
- CAS编号13463-28-0
- MFCD编号:MFCD00017472
- EINECS号:236-668-7
- FDA UNII编号:AS293HR5XQ
- 分子式:C27H32O15
- 分子量:596.54
- 产品CID: 527394
- 产品分类生物化工 → 提取物
物理性质
MSDS等安全信息
合成工艺路线路线简述
专利信息
专利号:US-11773128-B2
优先权日:2019-03-28
标题 :Electrocatalytic synthesis of dihydrochalcones
发明人：REDKO MIKHAIL; SAFFRON CHRISTOPHER M; JACKSON JAMES E
权利人:UNIV MICHIGAN STATE
摘要:The disclosure relates to methods of forming a dihydrochalcone using electrocatalytic dehydrogenation. In particular, the disclosure relates to methods of forming a dihydrochalcone electrocatalytically hydrogenating (ECH) a reactant compound over a catalytic cathode in a reaction medium having a non-alkaline pH value, thereby forming a dihydrochalcone product; wherein the reactant compound has a structure according to Formula (I). The method can be used to prepare dihydrochalcone sweeteners, such as, for example, naringin dihydrochalcone and neohesperidin dihydrochalcone.
专利号:US-2007232495-A1
优先权日:2006-03-24
标题:Compositions and methods to add value to plant products, increasing the commercial quality, resistance to external factors and polyphenol content thereof
发明人：NAPPA ALVARO O; LORENZINI FELIPE C; SANHUEZA ANDRES L
权利人:NAPPA ALVARO O; LORENZINI FELIPE C; SANHUEZA ANDRES L
摘要:The invention is related to compositions and methods that naturally protect plant tissues against ultraviolet radiation and temperature, thus giving protection against sunburn to plants, plant parts, fruits and/or flowers during their development. The invention is also related to compositions and methods to naturally improve the color of plants, plant parts, fruits and/or flowers by inducing the natural synthesis of flavonoids and anthocyanins present in plants. Likewise, the present invention is directed to improving the nutritional value of plants, plant parts, fruits and/or flowers by increasing the normal levels of polyphenolic compounds, especially flavonoids, present therein. Additionally, the present invention is related to compositions and methods that give more resistance to plants, plant parts, fruits and/or flowers against pathogens as bacteria and fungi. Finally, the present invention is related to plants, plant parts, fruits, flowers and/or propagating material treated with the compositions described in the present document.
专利号:WO-2020198578-A1
优先权日:2019-03-28
标 题:Electrocatalytic synthesis of dihydrochalcones
专利号:US-2022089630-A1
优先权日:2019-03-28
标 题 :Electrocatalytic synthesis of dihydrochalcones
专利号:EP-3947781-A1
优先权日:2019-03-28
标题 :Electrocatalytic synthesis of dihydrochalcones
专利号:CN-114891807-B
优先权日:2022-05-30
标题:Application of CYP450 gene in regulating and controlling soybean isoflavone synthesis
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主要参考文献
1. Horowitz, R.M., and Gentili, B. Flavonoid compounds of citrus. III. Isolation and structure of eriodictyol glycoside J. Am. Chem. Soc. 82(11), 2803-2806 (1960). 2. Miyake, Y., Yamamoto, K., and Osawa, T. Isolation of eriocitrin (eriodictyol 7-rutinoside) from lemon fruit (Citrus limon BURM. f.) and its antioxidative activity Food Sci. Technol. Int. Tokyo 3(1), 84-89 (1997). 3. Miyake, Y., Shimoi, K., Kumazawa, S., et al. Identification and antioxidant activity of flavonoid metabolites in plasma and urine of eriocitrin-treated rats J. Agric. Food Chem. 48(8) , 3217-3224 (2000). 4. Minato, K., Miyake, Y., Fukumoto, S., et al. Lemon flavonoid, eriocitrin, suppresses exercise-induced oxidative damage in rat liver Life Sci. 72(14) , 1609-1616 (2003). 5. Carradori, S., Gidaro, M.C., Petzer, A., et al. Inhibition of human monoamine oxidase: Biological and molecular modeling studies on selected natural flavonoids J. Agric. Food Chem. 64(47) , 9004-9011 (2016).合成参考文献
参考文献:10.1016/s0021-9673(01)01038-x
摘要:Gel-Moreto N, Streich R, Galensa R. Chiral separation of six diastereomeric flavanone-7-O-glycosides by capillary electrophoresis and analysis of lemon juice. J Chromatogr A. 2001 Aug 03;925(1-2):279–89. doi: 10.1016/s0021-9673(01)01038-x.
参考文献:10.1021/jf0304775
摘要:Gil-Izquierdo A, Riquelme MT, Porras I, Ferreres F. Effect of the rootstock and interstock grafted in lemon tree (Citrus limon (L.) Burm.) on the flavonoid content of lemon juice. J Agric Food Chem. 2004 Jan 28;52(2):324–31. doi: 10.1021/jf0304775.
参考文献:10.1021/jf0400967
摘要:Aturki Z, Brandi V, Sinibaldi M. Separation of flavanone-7-O-glycoside diastereomers and analysis in citrus juices by multidimensional liquid chromatography coupled with mass spectrometry. J Agric Food Chem. 2004 Aug 25;52(17):5303–8. doi: 10.1021/jf0400967.
参考文献:10.1021/jf040097z
摘要:Kamara BI, Brand DJ, Brandt EV, Joubert E. Phenolic metabolites from honeybush tea (Cyclopia subternata). J Agric Food Chem. 2004 Aug 25;52(17):5391–5. doi: 10.1021/jf040097z.
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