CAS: 12035-64-2; Nickel Phosphide

该化合物是一种无机化合物,其特点是其金属特性和镍和磷的合成物,其特点是灰或黑固体,通常以其高热稳定性和耐氧化性而著称,因此适合各种高温应用;镍磷(Ni2P)表现出半导体行为,并引起对催化的兴趣,特别是氢化反应和石油产品氢化的催化剂;该化合物还因其与其他金属形成合金的能力而引人注目,增强了其在材料科学中的效用;就结构而言,六角或正角的镍磷酸结晶在六角或正角的熔化物中,视具体阶段而定,可通过各种方法,包括固态反应和化学蒸气沉积,实现合成;尽管普遍认为其毒性较低,但鉴于镍的暴露潜力,应当注意如何采取预防措施.

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统一分类与标签ECHA物质工作场所安全标识要求食品接触材料-禁用CMR物质化妆品禁用物质清单C&L通报REACH预注册废弃物危险特性清单

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    专利信息


    专利号:US-8920688-B2
    优先权日:2008-06-18
    标题:Microwave-assisted synthesis of transition metal phosphide
    发明人:VISWANATHAN TITO
    权利人:VISWANATHAN TITO; UNIV ARKANSAS
    摘要:A method of synthesizing transition metal phosphide. In one embodiment, the method has the steps of preparing a transition metal lignosulfonate, mixing the transition metal lignosulfonate with phosphoric acid to form a mixture, and subjecting the mixture to a microwave radiation for a duration of time effective to obtain a transition metal phosphide.

    专利号:US-8167973-B2
    优先权日:2008-06-18
    标题 :Microwave-assisted synthesis of carbon and carbon-metal composites from lignin, tannin and asphalt derivatives
    发明人:VISWANATHAN TITO
    权利人:VISWANATHAN TITO; UNIV ARKANSAS
    摘要:A process for synthesizing carbon-metal nanocomposites. In one embodiment, the process includes the steps of preparing a metal derivative or a metal chelated derivative of a carbon-containing precursor in solid form, and subjecting the metal derivative or metal chelated derivative of a carbon-containing precursor in solid form to microwave radiation at a frequency in the range of 900 MHz to 5.8 GHz, for a period of time effective to generate a heat flow from inside of the metal derivative or metal chelated derivative of a carbon-containing precursor in solid form to the outside such that the temperature of the metal derivative or metal chelated derivative of a carbon-containing precursor in solid form reaches 1,000° C. in less than 6 minutes with a temperature (T) derivative over time (t), ΔT/Δt, no less than 2.5° C./second to form carbon-metal nanocomposites.

    专利号:WO-2010115199-A1
    优先权日:2009-04-03
    标 题:Microwave-assisted synthesis of transition metal phosphide
    发明人:VISWANATHAN TITO
    权利人:UNIV ARKANSAS; VISWANATHAN TITO
    摘要:A method of synthesizing transition metal phosphide. In one embodiment, the method has the steps of preparing a transition metal lignosulfonate, mixing the transition metal lignosulfonate with phosphoric acid to form a mixture, and subjecting the mixture to a microwave radiation for a duration of time effective to obtain a transition metal phosphide.

    专利号:US-11271193-B2
    优先权日:2017-03-13
    标题:Synthesis of metal metaphosphate for catalysts for oxygen evolution reactions
    发明人:REN ZHIFENG; CHEN SHUO; YU FANG; ZHOU HAIQING
    权利人:UNIV HOUSTON SYSTEM
    摘要:A method of manufacturing an electrode by disposing a three-dimensional substrate in a metal nitrate solution, drying, and thermally phosphatizing with a phosphorus source under inert gas to form a metal based phosphate catalyst on the substrate. An electrocatalyst and electrode produced via the method are also provided.

    专利号:US-5364442-A
    优先权日:1991-06-14
    标题 :Composite electrode for electrochemical processing having improved high temperature properties and method for preparation by combustion synthesis
    发明人:SEKHAR JAINAGESH A
    权利人:MOLTECH INVENT SA
    摘要:A composite electrode for electrochemical processing having improved high temperature properties, and a process for making the electrode by combustion synthesis. A composition from which the electrode is made by combustion synthesis comprises from about 4% to about 90% by weight of a particulate or fibrous combustible mixture which, when ignited, is capable of forming an interconnected network of a ceramic or metal-ceramic composite, and from about 10% to about 60% by weight of a particulate or fibrous filler material capable of providing the electrode with improved oxidation resistance and maintenance of adequate electrical conductivity at temperatures above 1000 DEG C. The filler material is molybdenum silicide, silicon carbide, titanium carbide, boron carbide, boron nitride, zirconium boride, cerium oxide, cerium oxyfluoride, or mixtures thereof.

    专利号:CN-115282992-A
    优先权日:2022-05-09
    标题 :A kind of preparation method of in-situ synthesis of amorphous nickel phosphide catalyst supported by hierarchical porous ZSM-5 molecular sieve

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