CAS: 87-39-8; Violuric Acid

该化合物是一种有机化合物,属于七环化合物类别,其特征是其结构,包括一个含有尿素的火水环,该化合物一般是黄色晶状固体,以其在水和有机溶剂中的溶解性而著称.Violuric酸表面酸特性,由于存在碳oxylic酸功能组,允许其参与各种化学反应,包括酸基反应.它经常用于染色化学,并用作其他有机化合物合成的中间体.此外,紫色酸可与金属离子形成复杂体,这在化学协调中很有意义.它独特的结构特征和再活动使它成为有机合成和材料科学的研究对象.在处理该化合物时,应像处理许多有机化学品一样采取安全防范措施,以避免潜在健康危害.

结构式图片

相似化合物

3051-09-0 3051-09-0 26351-19-9

物理性质

MSDS等安全信息

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CAS号61066-33-9 pyrimidine-2,4,... | CAS号69-93-2 尿酸 | CAS号412341-12-9 5-nitrosopyrimi... | CAS号67-52-7 巴比妥酸 | CAS号76-24-4 双阿脲 | CAS号463-04-7 亚硝酸戊酯 | CAS号10544-73-7 三氧化二氮 | CAS号7732-18-5 水 | CAS号480-68-2 5-硝基巴比妥酸 | CAS号511-67-1 5,5-二溴巴比妥酸 | CAS号83-88-5 核黄素 | CAS号699-40-1 5,5-二氯巴比妥酸 | CAS号118-78-5 乌拉米尔 | CAS号120-89-8 仲班酸 | CAS号124-47-0 硝酸脲 | CAS号17376-76-0 8-(dimethylamin... | CAS号57-13-6 尿素 | CAS号7147-37-7 6,8-diamino-1H-...

合成工艺路线路线简述

  • 87-39-8 + 28966-81-6 = 87-39-8
    反应条件:1.1 Reagents: Potassium Hydroxide Solvents: Methanol; 9 H,Heated
    标题:Antiproliferative Effects Of Palladium(Ii) Complexes Of 5-Nitrosopyrimidines And Interactions With The Proteolytic Regulatory Enzymes Of The Renin-Angiotensin System In Tumoral Brain Cells
    作者:Illan-Cabeza,Nuria A.; Et Al
    参考文献:Journal Of Inorganic Biochemistry 日期:2013 卷标:126 页码:118-127]

    6632-68-4 = 87-39-8
    反应条件:1.1 Reagents: Hydrochloric Acid Solvents: Water; Rt; 5 H,80 °C
    标题:Efficient Adsorption Of Toxic Heavy Metal Ions On The Surface Engineered Violuric Acid-Reduced Graphene Oxide Nanomaterial
    作者:Kumar,Pramanand; Et Al
    参考文献:Acs Applied Engineering Materials 日期:2023 卷标:1(5) 页码:1343-1355]

    6642-31-5 = 87-39-8
    反应条件:1.1 Reagents: Sodium Nitrite Solvents: Water; 0 - 5 °C1.2 Reagents: Acetic Acid; Acidified,Rt; 2 H,Acidified,Rt2.1 Reagents: Hydrochloric Acid Solvents: Water; Rt; 5 H,80 °C
    标题:Efficient Adsorption Of Toxic Heavy Metal Ions On The Surface Engineered Violuric Acid-Reduced Graphene Oxide Nanomaterial
    作者:Kumar,Pramanand; Et Al
    参考文献:Acs Applied Engineering Materials 日期:2023 卷标:1(5) 页码:1343-1355
📜巴比妥酸置于sodium Perchlorate,Sodium Nitrite体系中,化学反应生成 紫脲酸
参考文献:重新审视烯醇亚硝化:确定环境亲核试剂的反应性
标题:重新审视烯醇亚硝化:确定环境亲核试剂的反应性
摘要:烯醇是最重要的环境亲核试剂之一,被广泛用作有机化学中的试剂.烯醇的相关性引起了人们对开发确定其亲核中心反应性的方法的极大兴趣.从这个意义上说,关于这个主题的主流文献工作结合了总速率常数和反应产物的分析.通过了解产品比率,可以确定每个站点的反应速率之间的比率.因此,可以获得每个亲核位置的反应性.只要可以进行反应产物的分离或原位表征,这是一种可靠的方法.在不稳定和/或可相互转化的产品的情况下,
DOI:10.1002/ejoc.200900498

海关参考信息

专利信息


专利号:US-2024425890-A1
优先权日:2022-02-11
标 题:Process for the synthesis of alpha-methylene-gamma-butyrolactone
发明人：TADEN ANDREAS; BECK HORST; MYRTOLLARI KAMELA; KOURIST ROBERT; NIGL ANDREA
权利人:HENKEL AG & CO KGAA
摘要:The present application provides a process for the preparation of α-methylene-γ-butyrolactone, said process comprising the steps of:a) acetylating the C1-hydroxyl group of isoprenol to yield isoprenyl acetate;b) forming 4-acetoxy-2-methylene-butan-1-ol from said isoprenyl acetate by whole cell biotransformation, said step comprising:i) contacting a cell (CB) with a culture medium containing said isoprenyl acetate or with a culture medium contiguous with an organic phase containing said isoprenyl acetate under conditions that enable the cell to form 4-acetoxy-2-methylene-butan-1-ol from isoprenyl acetate; and,ii) optionally isolating the resultant 4-acetoxy-2-methylene-butan-1-ol, wherein said cell (CB) exhibits activity of at least one alkane monooxygenase enzyme which catalyzes the formation of 4-acetoxy-2-methylene-butan-1-ol from isoprenyl acetate;c) oxidizing said 4-acetoxy-2-methylene-butan-1-ol to yield 4-acetoxy-2-methylene butyric acid; and,d) converting said 4-acetoxy-2-methylene butyric acid to α-methylene-γ-butyrolactone by hydroxylysis to γ-hydroxy-α-methylenebutyric acid and subsequent cyclization of said γ-hydroxy-α-methylenebutyric acid.

专利号:US-6150403-A
优先权日:1997-10-14
标 题 :Topical compositions for regulating the oily/shiny appearance of skin
发明人：BIEDERMANN KIMBERLY A; SCHUBERT HARRY L; PARRAN JR JOHN J
权利人:PROCTER & GAMBLE
摘要:The present invention relates to methods for inhibiting sebaceous gland activity in mammalian skin comprising administration of a topical composition comprising dehydroacetic acid or pharmaceutically acceptable salts thereof, and a dermatologically-acceptable carrier. The present invention also relates to methods and topical compositions further comprising agents which regulate the oily and/or shiny appearance of skin, and agents which treat acne and related skin disorders in mammalian skin and scalp. Methods of reducing sebum synthesis with the use of dehydroacetic acid, methods of regulating the oily and/or shiny appearance of skin, and methods of treating acne and other skin disorders are also encompassed by the present invention.

专利号:WO-2008145620-A1
优先权日:2007-05-25
标题 :Process for the deprotection of aryl group protected amines employing oxidases
发明人：QUAEDFLIEG PETER JAN LEONARD MARIO; SCHOEMAKER HANS EGBERT; SCHUERMANN MARTIN; VERKADE JORGE MERIJN MATHIEU; RUTJES FLORIS PETRUS JOHANNES THEODORUS
权利人:DSM IP ASSETS BV; QUAEDFLIEG PETER JAN LEONARD MARIO; SCHOEMAKER HANS EGBERT; SCHUERMANN MARTIN; VERKADE JORGE MERIJN MATHIEU; RUTJES FLORIS PETRUS JOHANNES THEODODRUS
摘要:In organic synthesis, amine functionalities are often protected by a protecting group. The invention relates to a process for the deprotection of a protected amine compound, wherein the protect ed amine compound which comprises a protecting group attached to the N-atom of the amine, is contacted with an oxidative enzyme and an oxidising agent that may optionally be formed in situ. The invention also relates to the use of oxidative enzymes in a process for deprotection of a protected amine compound, in particular protected secondary or tertiary amine compounds.

专利号:US-2007161095-A1
优先权日:2005-01-18
标 题:Biomass Fuel Synthesis Methods for Increased Energy Efficiency
发明人：GURIN MICHAEL H
权利人:GURIN MICHAEL H
摘要:A high efficiency method for synthesizing biomass fuels leveraging the synergistic impact of ionic liquids on both the significant gains in pretreatment of biomass and the utilization of the combination of ionic liquids and carbon dioxide under supercritical conditions for energy generation is provided. The strategic use of heat exchangers, preferably microchannel heat exchangers and microchannel reactors further increase the efficiency and performance of the system by extensive heat recovery and the direct utilization of the biomass solution as the working fluid of a thermodynamic cycle.

专利号:RU-2179968-C1
优先权日:2001-01-12
标 题:Method of synthesis of aromatic aldehydes

专利号:WO-2023151894-A1
优先权日:2022-02-11
标题:Process for the synthesis of alpha-methylene-gamma-butyrolactone

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主要参考文献

[参考文献]: Isabel Pardo, Et Al. Colorimetric High-Throughput Screening Assays For The Directed Evolution Of Fungal Laccases. Methods Mol Biol. 2018;1685:247-254.
[参考文献]: Zhenyu Shi, Et Al. Enhanced Transformation Of Emerging Contaminants By Permanganate In The Presence Of Redox Mediators. Environ Sci Technol. 2020 Feb 4;54(3):1909-1919.

合成参考文献


摘要:Herter, S.; Turner, N. J., Science of Synthesis: Biocatalysis in Organic Synthesis, (2015) 3, 141.
摘要:M. E. Taylor and R. J. Robinson, Talanta 8, 518 (1961).
参考文献:10.1074/jbc.m202682200
摘要:Pelletier B, Beaudoin J, Mukai Y, Labbé S. Fep1, an Iron Sensor Regulating Iron Transporter Gene Expression in Schizosaccharomyces pombe. Journal of Biological Chemistry. 2002 Jun;277(25):22950–8. doi: 10.1074/jbc.m202682200.
参考文献:10.1007/s12010-007-8100-4
摘要:Cambria MT, Minniti Z, Librando V, Cambria A. Degradation of Polycyclic Aromatic Hydrocarbons by Rigidoporus lignosus and its Laccase in the Presence of Redox Mediators. Applied Biochemistry and Biotechnology. 2008 Feb 14;149(1):1–8. doi: 10.1007/s12010-007-8100-4.
参考文献:10.1007/s12010-008-8138-y
摘要:Oudia A, Queiroz J, Simões R. The Influence of Operating Parameters on the Biodelignification of Eucalyptus globulus Kraft Pulps in a Laccase–Violuric Acid System. Applied Biochemistry and Biotechnology. 2008 Feb 20;149(1):23–32. doi: 10.1007/s12010-008-8138-y.
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