CAS: 76-87-9; Fentin Hydroxide

该化合物其结构特征为有机锡化合物,由三联苯组和氢氧化物组成,该化合物作为白色至白外固体的白色化合物,以其在水中的溶解性较低而著称,但在有机溶剂中可溶性相对较低.三联苯基氢氧化物具有杀菌和生物杀菌特性,因此在农业应用中有用,特别是作为杀虫剂和杀菌剂.它还用于各种工业工艺,包括生产塑料和作为聚氯乙烯配方的稳定剂.然而,由于其潜在的毒性和环境持久性,该化合物的使用受到监管审查.该化合物可能会对人类健康和水生生物构成危险,需要小心处理和遵守安全准则.

结构式图片

欧盟法规

《欧盟PIC法规》统一分类与标签压力设备指令-第1组危险流体ECHA物质食品接触材料-禁用CMR物质OtherC&L通报REACH预注册废弃物危险特性清单"欧盟管控危险化学品"工作场所安全标识要求ECHA物质化妆品禁用物质清单

上下游产品

CAS号23604-56-0 2-triphenylstan... | CAS号639-58-7 三苯基氯化锡 | CAS号108-86-1 溴苯 | CAS号595-90-4 四苯基锡 | CAS号1078-58-6 二苯锌 | CAS号1247-08-1 Stannane,triphe... | CAS号1249-25-8 1H-inden-1-yl(t... | CAS号892-20-6 三苯基锡化氢 | CAS号4104-91-0 Triphenyl-butad... | CAS号894-09-7 Stannane,iodotr... | CAS号1954-39-8 is°Cyanato(trip... | CAS号595-90-4 四苯基锡 | CAS号1064-10-4 六苯基二锡 | CAS号24379-26-8 triphenylstanny... | CAS号252228-35-6 Boroxin,tris[(t... | CAS号20795-53-3 3-苯基环己酮 | CAS号892-20-6 三苯基锡化氢 | CAS号98-80-6 苯硼酸 | CAS号1262-21-1 双(三苯基锡)氧化物

合成工艺路线路线简述

    三苯基氢化锡置于ch3Oh体系中,用 Neat (No Solvent) 作为反应溶剂,化学反应生成 三苯基氢氧化锡
    参考文献:Gmelin Handbuch Der Anorganischen Chemie,Gmelin Handbook: Sn: Org.Verb.2,1.1.2.15.2,Page 359-384
    标题:Gmelin Handbuch Der Anorganischen Chemie,Gmelin Handbook: Sn: Org.Verb.2,1.1.2.15.2,Page 359-384

    海关参考信息

    专利信息


    专利号:US-7351781-B2
    优先权日:2001-04-24
    标题 :Synthesis of vinyl polymers by controlled radical polymerization
    发明人:WHITE DANIELA; O'DWYER JAMES B
    权利人:PPG IND OHIO INC
    摘要:A controlled free radical polymerization process, which includes the steps of: adding a monofunctional iniferter compound to an oxygen-free solvent; heating the solution to a temperature sufficient to allow the iniferter compound to form two carbon centered radical residues; adding a first monomer composition comprising one or more monomers to the solution containing the radical containing residues; polymerizing the first monomer composition to form a quasi-living polymer; and optionally polymerizing a second monomer composition comprising one or more monomers, which are different than the first monomer composition. The resulting non-random copolymer having the general formula:n nφ-[-A p -B s -] t -φn nwhere A and B are different compositions of ethylenically unsaturated monomers; p is an integer from 1 to 1,000; s is an integer from 0 to 1,000; t is an integer from 1 to 100; and φ is a residue from the iniferter.

    专利号:WO-2025056767-A1
    优先权日:2023-09-15
    标题 :Process for the preparation of enantiomerically enriched aliphatic amines
    发明人:BOU HAMDAN FARHAN; GODINEAU EDOUARD; SMEJKAL TOMAS; DUMEUNIER RAPHAEL; BOUSSEMGHOUNE MOHAMED ABDELOUAHAB; BLUM MATHIAS
    权利人:SYNGENTA CROP PROTECTION AG
    摘要:The present invention relates to a process for the preparation of enantiomerically enriched cyclobutylamines of formula (I) from α-tertiary cyclobutanones and reacting said enantiomerically enriched cyclobutylamines to enantiomerically enriched cyclobutylamides. Such compounds are useful intermediates in the synthesis of microbiocidal thiazole compounds.

    专利号:US-2016073631-A1
    优先权日:2013-03-04
    标 题 :Process for the preparation of dihydropyrrole derivatives
    发明人:EL QACEMI MYRIEM; SMITS HELMARS; CASSAYRE JEROME YVES; MULHOLLAND NICHOLAS PHILLIP; RENOLD PETER; GODINEAU EDOUARD; PITTERNA THOMAS
    权利人:SYNGENTA PARTICIPATIONS AG; SYNGENTA LTD
    摘要:The present invention provides stereoselective processes for the preparation of compounds of formula (I) n n n n n n n n n n n n wherein n P is phenyl, naphthyl, a 6-membered heteroaryl group containing one or two nitrogen atoms as ring members, or a 10-membered bicyclic heteroaryl group containing one or two nitrogen atoms as ring members, and wherein the phenyl, naphthyl and heteroaryl groups are optionally substituted; n R 1 is chlorodifluoromethyl or trifluoromethyl; n R 2 is optionally substituted aryl or optionally substituted heteroaryl; n n is 0 or 1; n including the process comprising n (a-i) reacting a compound of formula II n n n n n n n n n n n n n n n n wherein P, R 1 and R 2 are as defined for the compound of formula I; n with nitromethane in the presence a chiral catalyst to give a compound of formula III n n n n n n n n n n n n n n n n wherein P, R 1 and R 2 are as defined for the compound of formula I; and n (a-ii) reductively cyclising the compound of formula III to give the compound of formula I. n n n n n The invention also provides intermediates useful for processes for the synthesis of compounds of formula (I).

    专利号:US-9233920-B2
    优先权日:2010-06-11
    标题 :Process for the preparation of dihydropyrrole derivatives
    发明人:EL QACEMI MYRIEM; SMITS HELMARS; CASSAYRE JEROME YVES; MULHOLLAND NICHOLAS PHILLIP; RENOLD PETER; GODINEAU EDOUARD; PITTERNA THOMAS
    权利人:EL QACEMI MYRIEM; SMITS HELMARS; CASSAYRE JEROME YVES; MULHOLLAND NICHOLAS PHILLIP; RENOLD PETER; GODINEAU EDOUARD; PITTERNA THOMAS; SYNGENTA PARTICIPATIONS AG; SYNGENTA LTD
    摘要:The present invention provides stereoselective processes for the preparation of compounds of formula (I) wherein P is phenyl, naphthyl, a 6-membered heteroaryl group containing one or two nitrogen atoms as ring members, or a 10-membered bicyclic heteroaryl group containing one or two nitrogen atoms as ring members, and wherein the phenyl, naphthyl and heteroaryl groups are optionally substituted; R 1 is chlorodifluoromethyl or trifluoromethyl; R 2 is optionally substituted aryl or optionally substituted heteroaryl; n is 0 or 1; including the process comprising (a-i) reacting a compound of formula II wherein P, R 1 and R 2 are as defined for the compound of formula I; with nitromethane in the presence a chiral catalyst to give a compound of formula III Wherein P, R 1 and R 2 are as defined for the compound of formula I; and (a-ii) reductively cyclizing the compound of formula III to give the compound of formula I. The invention also provides intermediates useful for processes for the synthesis of compounds of formula (I).

    专利号:US-9968097-B2
    优先权日:2012-05-30
    标题:Composition comprising a biological control agent and a fungicide selected from inhibitors of the lipid membrane synthesis, the melanine biosynthesis, the nucleic acid synthesis or the signal transduction
    发明人:WACHENDORFF-NEUMANN ULRIKE; ANDERSCH WOLFRAM; STENZEL KLAUS; SPRINGER BERND
    权利人:BAYER CROPSCIENCE AG
    摘要:The present invention relates to a composition comprising at least one biological control agent. Furthermore, the present invention relates to the use of this composition as well as a method for reducing overall damage of plants and plant parts.

    专利号:US-2007232495-A1
    优先权日:2006-03-24
    标题:Compositions and methods to add value to plant products, increasing the commercial quality, resistance to external factors and polyphenol content thereof
    发明人:NAPPA ALVARO O; LORENZINI FELIPE C; SANHUEZA ANDRES L
    权利人:NAPPA ALVARO O; LORENZINI FELIPE C; SANHUEZA ANDRES L
    摘要:The invention is related to compositions and methods that naturally protect plant tissues against ultraviolet radiation and temperature, thus giving protection against sunburn to plants, plant parts, fruits and/or flowers during their development. The invention is also related to compositions and methods to naturally improve the color of plants, plant parts, fruits and/or flowers by inducing the natural synthesis of flavonoids and anthocyanins present in plants. Likewise, the present invention is directed to improving the nutritional value of plants, plant parts, fruits and/or flowers by increasing the normal levels of polyphenolic compounds, especially flavonoids, present therein. Additionally, the present invention is related to compositions and methods that give more resistance to plants, plant parts, fruits and/or flowers against pathogens as bacteria and fungi. Finally, the present invention is related to plants, plant parts, fruits, flowers and/or propagating material treated with the compositions described in the present document.
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    合成参考文献


    摘要:Snaith, J. S., Science of Synthesis Knowledge Updates, (2011) 2, 199.
    摘要:National Academy of Sciences, National Research Council, Chemical-Biological Coordination Center, Review., 5(46), 1953
    摘要:Yakkyoku. Pharmacy., 30(505), 1979
    摘要:Agrochemicals Handbook, with updates, Hartley, D., and H. Kidd, eds., Nottingham, Royal Soc of Chemistry, 1983-86, A205(1984)
    参考文献:10.1007/s002040050603
    摘要:Ema M, Miyawaki E, Kawashima K. Suppression of uterine decidualization as a cause of implantation failure induced by triphenyltin chloride in rats. Arch Toxicol. 1999 Apr;73(3):175–9. doi: 10.1007/s002040050603.
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