CAS: 4385-76-6; 4-Pyridin-4-Yl-Benzoic Acid

该化合物是一种有机化合物,其特点是芳香结构,包括苯并二酸和环,该化合物一般是白色至白外晶状固体,在水和乙醇等极地溶剂中溶解,但其溶性可能因溶液pH而异,但因碳oxylic酸功能组的存在而异.化合物既具有酸性,又具有基本特性,允许其参与各种化学反应,包括酯化和恐吓.其环具有作为协调化学中的悬浮和核化的潜力,在金属综合体中有用.此外,4-(4-Pyridyl)苯甲酸在材料科学中具有应用性,特别是在有机半导体的研制中,并作为合成更复杂的有机分子的建筑块.其独特的结构特征也使其对可能的生物活动具有医学化学意义.

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合成工艺路线路线简述

    📜吡啶 4-(4-甲基苯基)-置于manganese(II) Acetate 硫酸,臭氧,溶剂黄146体系中,化学反应 1.0H,以94%的收率获得产物4-吡啶-4-基苯甲酸
    参考文献:Preparation Of Aromatic And Heteroaromatic Carboxylic Acids By Catalytic Ozonolysis
    标题:Preparation Of Aromatic And Heteroaromatic Carboxylic Acids By Catalytic Ozonolysis
    摘要:将式(I)中的烷基芳香化合物催化氧化为相应的芳香或杂芳羧酸的过程是在溶剂中,在存在过渡金属催化剂和可选地存在酸的情况下,利用臭氧将式(I)中的化合物氧化为相应的芳香或杂芳羧酸的过程.其中,式(I)中ar为可选地取代的芳香或杂芳5-或6-成员环或具有多达20个碳原子的环系统,其中ar可选地与一个c1-C6-烷基基团融合,其中最多有2个碳原子可被杂原子取代;r为氢,苯基,苄基或杂芳基,其中苯基,苄基或杂芳基基团也可以通过桥连接到ar,或r与ar一起形成一个可选地取代的环系统,该环系统可以含有一个或多个可选地取代的杂原子,反应温度在-70oc至110oc之间.

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    专利信息


    专利号:WO-2013063779-A1
    优先权日:2011-11-03
    标题:Conductive polymer material and synthesis process and use thereof
    发明人:ZHANG CHUNYANG; WANG QIANGXIN
    权利人:SHENZHEN INST OF ADV TECH CAS; ZHANG CHUNYANG; WANG QIANGXIN
    摘要:Disclosed is a conductive polymer material, which is a nano polypyrrole molecular wire having a one-dimensional molecular chain structure. The nano polypyrrole molecular wire having a one-dimensional molecular chain structure effectively remedies the defect in the structure of a polypyrrole molecule, and increases the degree of delocalization of electric charge in the nano polypyrrole molecular wire, and therefore, the conductive polymer material has relatively high conductivity. In addition, also provided are a process for synthesizing the conductive polymer material and the use thereof.

    专利号:CN-213254372-U
    优先权日:2020-08-17
    标题:A device for the alternate synthesis of metal-organic frameworks based on different reaction conditions

    专利号:US-2025318352-A1
    优先权日:2024-04-03
    标题 :Functionalized aromatic phosphonic acids for display and solar cell applications
    发明人:SELLINGER ALAN; KUVAYSKAYA ANASTASIA ALEKSEYEVNA; HUANG JINSONG; FEI CHENGBIN
    权利人:SELLINGER ALAN; KUVAYSKAYA ANASTASIA ALEKSEYEVNA; HUANG JINSONG; FEI CHENGBIN
    摘要:The present disclosure describes the synthesis, characterization, and purification of functionalized aromatic phosphonic acids (FAPAs) for use as hole extraction materials in perovskite solar cells and display devices. Embodiments of the present disclosure provide a method to prepare FAPAs with varying dipoles that can significantly improve the electronic properties of electrode materials used in displays and photovoltaic devices. The FAPA may be tuned for specific active layers. Aspects of the disclosure include phosphonic acid molecules that enhance bonding at the perovskite/substrate interface to create a strong hole extraction polymer retaining high efficiency and improving ultraviolet stability of perovskite solar cells by suppressing ion migration at the embedded interface.

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    ✅ COA系统入驻 | 共享模式

    合成参考文献


    参考文献:10.1002/chem.201100350
    摘要:Das MC, Xu H, Xiang S, Zhang Z, Arman HD, Qian G, Chen B. A new approach to construct a doubly interpenetrated microporous metal-organic framework of primitive cubic net for highly selective sorption of small hydrocarbon molecules. Chemistry. 2011 Jul 04;17(28):7817–22. doi: 10.1002/chem.201100350.
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