N-乙基甲基胺,氯化铪置于正丁基锂体系中,用 乙二醇二甲醚,甲苯,Hexanes 用作溶剂,以85.8%的收率获得四(二乙基氨基)铪(Iv) 参考文献: Processes For Producing Transition Metal Amido And Imido Compounds[fr] Procédés De Production De Composés Amido Et Imido De Métaux De Transition 标题: Processes For Producing Transition Metal Amido And Imido Compounds[fr] Procédés De Production De Composés Amido Et Imido De Métaux De Transition
专利号:US-8859785-B2 优先权日:2009-05-29 标 题 :Volatile group 2 metal precursors 发明人:NORMAN JOHN ANTHONY THOMAS 权利人:NORMAN JOHN ANTHONY THOMAS; AIR PROD & CHEM 摘要:A compound comprising one or more polyfunctionalized pyrrolyl anions coordinated to a metal selected from the group consisting of barium, strontium, magnesium, radium or calcium or mixtures thereof. Alternatively, one anion can be substituted with and a second non-pyrrolyl anion. n Synthesis of the novel compounds and their use to form BST films is also contemplated.
专利号:US-12043893-B2 优先权日:2017-08-24 标题:Manufacturing processes to synthesize, functionalize, surface treat and/or encapsulate powders, and applications thereof 发明人:KING DAVID; DAMERON ARRELAINE; TREVEY JAMES; LICHTY PAUL; ARGO ANDREW; BOURGOIS KYLE; RAGONESI JAMES; INGHAM KYLE; JACKSON DAVID; TRACY RYON; NGUYEN NGHI; LYON ADAM; VILLAGOMEZ JOSE; CURRY GARRETT 权利人:FORGE NANO INC 摘要:A system, apparatus and method are provided for processing articles. The system includes subsystems for synthesizing, pre-treating, conducting a vapor phase coating process and post-treating articles in the form of powders and solid or porous workpieces. The apparatus permits vapor phase synthesis, treatment and deposition processes to be performed with high efficiency and at high overall throughput. The methods include converting solids, liquids or gases into gaseous and solid streams that can be separated or exchanged with or without treatment and/or coating steps, and produce optimized composite articles for specific applications.
专利号:CN-111279015-B 优先权日:2017-08-24 标 题 :Manufacturing processes for synthesis, functionalization, surface treatment and/or encapsulation of powders and their applications
参考文献:10.1134/s0022476623030083 摘要:Petukhova DE, Vikulova ES, Korolkov IV, Khmel SY, Lebedev MS. Growth Features and Phase Composition of Hf–Sc–O thin Films Synthesized by Atomic Layer Deposition. J Struct Chem. 2023 Mar;64(3):424–36. doi: 10.1134/s0022476623030083. 参考文献:10.1007/s11664-025-11865-z 摘要:Atuchin VV, Lebedev MS, Gromilov SA, Korolkov IV, Perevalov TV, Prosvirin IP. Growth and Characterization of Mixed Oxide Hf1−xScxOy (0 ≤ x ≤ 1) Films Prepared by the Atomic Layer Deposition Method. J. Electron. Mater. 2025 Mar 12;54(6):4832–45. doi: 10.1007/s11664-025-11865-z.