CAS: 14708-14-6; Nickel(Ii) Tetrafluoroborate

该化合物是一种无机化合物,配有公式Ni(BF4)2.它具有协调性,镍通常处于+2氧化状态,由四氟乙酸阴离子(BF4-)协调.该化合物经常遇到晶状固体,由于镍的存在而呈现绿色色彩.镍四氟乙酸盐在水和酒精等极地溶剂中溶解,有利于其在各种化学应用中使用,包括电化学和催化.它还被用于制作含镍材料,并作为镍基催化剂合成的前体.在处理该化合物时,安全考虑十分重要,因为它可能有毒,并可能对环境造成危害.在冷,干燥的地方适当储存并遵守安全协议对于减少其使用的风险至关重要.

结构式图片

欧盟法规

统一分类与标签ECHA物质工作场所安全标识要求食品接触材料-禁用CMR物质化妆品禁用物质清单C&L通报ECHA物质REACH预注册废弃物危险特性清单

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    专利信息


    专利号:US-7615169-B2
    优先权日:2004-09-20
    标题 :Method for synthesis of colloidal nanoparticles
    发明人:STROUSE GEOFFREY FIELDING; GERBEC JEFFREY A; MAGANA DONNY
    权利人:UNIV CALIFORNIA
    摘要:A method for synthesis of high quality colloidal nanoparticles using comprises a high heating rate process. Irradiation of single mode, high power, microwave is a particularly well suited technique to realize high quality semiconductor nanoparticles. The use of microwave radiation effectively automates the synthesis, and more importantly, permits the use of a continuous flow microwave reactor for commercial preparation of the high quality colloidal nanoparticles.

    专利号:US-7927516-B2
    优先权日:2004-09-20
    标题 :Method for synthesis of colloidal nanoparticles
    发明人:STROUSE GEOFFREY F; GERBEC JEFFREY A; MAGANA DONNY
    权利人:UNIV CALIFORNIA
    摘要:A method for synthesis of high quality colloidal nanoparticles using comprises a high heating rate process. Irradiation of single mode, high power, microwave is a particularly well suited technique to realize high quality semiconductor nanoparticles. The use of microwave radiation effectively automates the synthesis, and more importantly, permits the use of a continuous flow microwave reactor for commercial preparation of the high quality colloidal nanoparticles.

    专利号:US-5013412-A
    优先权日:1989-04-28
    标题:Process for the electrosynthesis of a beta,gamma-unsaturated ester
    发明人:CONAN ANNIE; D INCAN ESTHER; PERICHON JACQUES; SIBILLE SOLINE
    权利人:POUDRES ET EXPLOSIES SNPE SOC
    摘要:The invention relates to a process for the electrosynthesis of a beta,gamma-unsaturated ester by electrolysis, in a cell having only a single compartment, of a mixture of an alpha,beta-unsaturated halide and an alpha-halogenated ester in the presence of an amount which is less than the stoichiometric amount for the reaction between the halide and the ester of a catalyst based on nickel complexed with a binitrogenous bidentate organic ligand. The anode, which is consumed by the electrochemical reaction of which it is the center, is made of a metal chosen from the group comprising the reducing metals and their alloys and is preferably made of zinc, aluminum or magnesium. This process, which is simple and economical, in particular permits the synthesis of arylacetates and arylpropionates, which are intermediates in the synthesis of pharmaceutical or plant protection products.

    专利号:US-2007264834-A1
    优先权日:2004-09-20
    标题:Method for Synthesis of Colloidal Nanoparticles

    专利号:US-2006061017-A1
    优先权日:2004-09-20
    标题 :Method for synthesis of colloidal nanoparticles

    专利号:US-2006060998-A1
    优先权日:2004-09-20
    标 题:Method for synthesis of colloidal nanoparticles
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    合成参考文献


    摘要:Vashchenko, B. V.; Grygorenko, O. O., Science of Synthesis Knowledge Updates, (2021) 3, 368.
    摘要:Terada, M., Science of Synthesis: Stereoselective Synthesis, (2011) 3, 321.
    摘要:Zhang, L., Science of Synthesis: Metal-Catalyzed Cyclization Reactions, (2016) 1, 266.
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