CAS: 145-39-1; Musk Tibetene
该化合物是一种替代芳香化合物,其特点是苯环上一个异丁基组和三个甲基替代物,以及2和6个位置的两个硝基组.这一结构具有立体障碍和电子效应,在合成化学中作为进一步功能化的中间体或作为特殊化学品开发的先质而发挥作用.三丁基组增强了稳定性,而硝基组则提供了核分裂性替代或减少反应的回活动.其明确界定的分子结构有利于需要受控修改芳香系统的应用,如制药,农用化学或材料科学.
- ⚠️《化妆品禁用原料目录》
- 英文名称Musk Tibetene
- 中文名称西藏麝香
- IUPAC名称1-(tert-butyl)-3,4,5-trimethyl-2,6-dinitrobenzene
- 其它别名1-(1,1-dimethylethyl)-3,4,5-trimethyl-2,6-dinitro-Benzene; 1-(1,1-dimethylethyl)-2,6-dinitro-3,4,5-trimethyl-benzen; 5-tert-butyl-1,2,3-trimethyl-4,6-dinitrobenzene; 1-(1,1-dimethylethyl)-3,4,5-trimethyl-2,6-dinitro-benzen; 1-tert-butyl-2,6-dinitro-3,4,5-trimethyl-benzen; musk tibetine
- CAS编号145-39-1
- MFCD编号:MFCD00024266
- EINECS号:205-651-6
- FDA UNII编号:CMN65165X5
- 分子式:C13H18N2O4分子量:266.3
- 产品CID: 689278
- 产品分类香精与香料 → 合成香料 → 麝香和大环类香料
物理性质
MSDS等安全信息
上下游产品
1,2,3-trimethyl-5-tert-butylbenzene合成工艺路线路线简述
📜5-叔-丁基-1,2,3-三甲基苯置于cupric Nitrate Trihydrate Supported On K 10 Montmorillonite Clay,硝酸,乙酸酐体系中,用 四氯化碳 用作溶剂,化学反应 2.0H,以93%的收率获得西藏麝香
参考文献:Mild And Selective Nitration By Claycop
标题:Mild And Selective Nitration By Claycop
摘要:A One-Pot Nitration Of Aromatic Compounds By ''Claycop'',A Reagent Consisting Of An Acidic Montmorillonite Clay Impregnated With Anhydrous Cupric Nitrate,Is Reported. Simply By Varying The Conditions,It Is Possible To Drive The Reaction At Will Toward Either Mono-Or Polynitration. Both The Yields And Selectivities Are Superior To Those Obtained Under Homogeneous Reaction Conditions.
Doi:10.1021/jo00116A034
海关参考信息
- 2902600000-乙苯
2902700000-异丙基苯 - 💡 提示：海关信息按照顺序优先匹配，如需确认的海关信息，请参考相关资料。
- 详情请参考：📖 海关编码查询和海关进出口税则
供应商参考报价(招募中)
品牌试剂参考报价(招募中)
📌 第三方产品分析报告
主要参考文献
1: Yin J, Wang H, Li J, Wu Y, Shao B. Occurrence of synthetic musks in human breast milk samples from 12 provinces in China. Food Addit Contam Part A Chem Anal Control Expo Risk Assess. 2016 Jul;33(7):1219-27. doi: 10.1080/19440049.2016.1201219. Epub 2016 Jul 4. doi: 10.1016/j.talanta.2013.11.086. Epub 2013 Dec 6.
合成参考文献
摘要:Schafer, E. W., Jr., and W. A. Bowles Jr. 1985. Acute oral toxicity and repellency of 933 chemicals to house and deer mice. Archives of Environmental Contamination and Toxicology 14:111-129. https://www.aphis.usda.gov/ws/nwrc/chem-effects-db/S_schafer851.pdf
📝 需求与反馈
尽可能描述清楚需求与问题信息
