专利号:US-8975358-B2 优先权日:2010-07-23 标题 :Compositions and methods for synthesis of organic-silica hybrid materials 发明人:SHEA KENNETH J; HU LI-CHIH 权利人:SHEA KENNETH J; HU LI-CHIH; UNIV CALIFORNIA 摘要:The present invention relates to compositions and methods for synthesis of organic-silica hybrid microparticles and nanoparticles. In particular, the present invention provides compositions and methods for particle size control during synthesis of organic-silica hybrid microparticles and nanoparticles.
专利号:US-6916982-B2 优先权日:2000-07-21 标题:Synthesis of perylene-porphyrin building blocks and polymers thereof for the production of light-harvesting arrays 发明人:LOEWE ROBERT S; TOMIZAKI KIN-YA; LINDSEY JONATHAN S 权利人:UNIV NORTH CAROLINA STATE 摘要:The present invention provides methods, compounds, and compositions for the synthesis of light harvesting arrays, such arrays comprising: (a) a first substrate comprising a first electrode; and (b) a layer of light harvesting rods electrically coupled to said first electrode, each of said light harvesting rods comprising a polymer of Formula I:n nX 1 X m+1 ) m   (I)n nwherein m is at least 1; X 1 is a charge separation group, and X 2 through X m+1 are chromophores. At least one of X 2 through X m+1 has at least one perylene group coupled thereto.
专利号:US-6162882-A 优先权日:1996-07-10 标 题:Preparation of novel homo- and copolymers using atom transfer radical polymerization 发明人:MATYJASZEWSKI KRZYSZTOF; COCA SIMION; GAYNOR SCOTT G; NAKAGAWA YOSHIKI; JO SEONG MU 权利人:UNIV CARNEGIE MELLON 摘要:The present invention is directed to a process of atom (or group) transfer radical polymerization for the synthesis of novel homopolymer or a block or graft copolymer, optionally containing at least one polar group, with well defined molecular architecture and narrow polydipersity index, in the presence of an initiating system comprising (i) an initiator having a radically transferrable atom or group, (ii) a transition metal compound, and (iii) a ligand, the present invention is also directed to the synthesis of a macromolecule having at least two halogen groups which can be used as a macroinitiator component (i) to subsequently form a block or graft copolymer by an atom or group transfer radical polymerization process; the present invention is also directed to a process of atom or group transfer radical polymerization for the synthesis of a branched or hyperbranched polymer; in addition, the present invention is directed to a process of atom or group transfer radical polymerization for the synthesis of a macroinitiator which can subsequently be used to produce a block or graft copolymer.
专利号:US-7271231-B2 优先权日:1995-01-24 标 题 :Polymerization of olefins 发明人:BROOKHART MAURICE S; JOHNSON LYNDA KAYE; KILLIAN CHRISTOPHER MOORE 权利人:DU PONT 摘要:Disclosed herein are processes for polymerizing ethylene, acyclic olefins, and/or selected cyclic olefins, and optionally selected olefinic esters or carboxylic acids, and other monomers. The polymerizations are catalyzed by selected transition metal compounds, and sometimes other co-catalysts. Since some of the polymerizations exhibit some characteristics of living polymerizations, block copolymers can be readily made. Many of the polymers produced are often novel, particularly in regard to their microstructure, which gives some of them unusual properties. Numerous novel catalysts are disclosed, as well as some novel processes for making them. The polymers made are useful as elastomers, molding resins, in adhesives, etc. Also described herein is the synthesis of linear α-olefins by the oligomerization of ethylene using as a catalyst system a combination a nickel compound having a selected α-diimine ligand and a selected Lewis or Bronsted acid, or by contacting selected α-diimine nickel complexes with ethylene.
专利号:US-9932423-B2 优先权日:2015-09-24 标题:Hydrogenation of annulated cyclopentadienyl metal complexes and metallocene catalysts comprising such 发明人:MCCULLOUGH LAUGHLIN G 权利人:EXXONMOBIL CHEMICAL PATENTS INC 摘要:Disclosed are methods for making partially hydrogenated annulated cyclopentadienyl complexes which can provide efficient synthesis of metallocene catalysts desired for olefin polymerization.
专利号:US-5292880-A 优先权日:1992-05-11 标题:Synthesis of caprolactam using catalysts 发明人:APELIAN MINAS R; BELL WELDON K; FUNG ANTHONY S; HAAG WERNER O; VENKAT CHAYA 权利人:MOBIL OIL CORP 摘要:A process for catalytically converting cyclohexanone oxime to epsilon caprolactam. The conversion catalyst is a crystalline aluminosilicate zeolite having a Constraint Index greater than 1 and a reduced surface acidity. The surface acidity is reduced by selective surface dealumination of the crystalline aluminosilicate zeolite by contacting the zeolite with dicarboxylic acid, such as oxalic acid.