CAS: 779-02-2; 9-Methylanthracene

该化合物是炭疽的一种多环芳烃衍生物,其特点是在9位置上替代一个甲基组,这一修改增强了其光物理特性,使其在有机合成和材料科学中具有价值;该化合物表现出强荧光,经常被用作先进的有机半导体,染料和光电子材料的构件;其硬性,平板结构有助于高热稳定性和高效的-同质化,这对于光排放二极管和光伏装置的应用至关重要. 9-Me乙烷还被用作研究光化学反应和能源转移过程的示范系统.

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相似化合物

781-43-1 13752-40-4 7072-00-6

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CAS号17239-99-5 9-methyl-9,10-d... | CAS号13061-96-6 甲基硼酸 | CAS号716-53-0 9-氯蒽 | CAS号80716-31-0 9,9a-dihydro-9a... | CAS号61608-94-4 1-(2-benzylphen... | CAS号24463-19-2 9-氯甲基蒽 | CAS号2584-79-4 9-(methoxymethy... | CAS号132884-19-6 1-benzyl-2-ethe... | CAS号108-88-3 甲苯 | CAS号42332-94-5 10,10-二甲基蒽 | CAS号613-31-0 9,10-二氢蒽 | CAS号120-12-7 蒽 | CAS号610-48-0 1-甲基蒽 | CAS号613-12-7 2-甲基蒽 | CAS号25148-26-9 9-Methyl-10-(ch... | CAS号2476-68-8 蒽-9-基甲胺 | CAS号2606-52-2 9-bromo-10-(bro... | CAS号23674-17-1 RARECHEM AQ BD AN06

合成工艺路线路线简述

    📜2-氯二苯基甲烷置于氢溴酸,溶剂黄146,苯体系中,化学反应生成 9-甲基蒽
    参考文献:A New Route To 9-Alkyl-And 9-Arylanthracenes
    标题:A New Route To 9-Alkyl-And 9-Arylanthracenes
    摘要:
    DOI:10.1021/ja01860A006

    海关参考信息

    专利信息


    专利号:US-2012215002-A1
    优先权日:2009-10-09
    标 题:Synthesis of optically active intermediate for the preparation of montelukast
    发明人:LEFORT LAURENT
    权利人:LEFORT LAURENT
    摘要:The present invention relates to the synthesis of optically active alcohols by means of enantioselective hydrogenation of ketones in biphasic systems. In particular the present invention relates to the synthesis of an optically active alcohol of general formula (1).

    专利号:US-9056868-B1
    优先权日:2012-09-13
    标题 :Three-step synthesis of CL-20
    发明人:WRIGHT MICHAEL E
    权利人:US NAVY
    摘要:Embodiments of the invention relate to the synthesis of CL-20 using only a three step synthesis and because of increased catalyst activity and lifetimes, a continuous flow process can be used with a tremendous reduction in total cost of producing CL-20.

    专利号:US-2003162992-A1
    优先权日:2001-12-14
    标 题 :Preparation of intermediates useful in the synthesis of antiviral nucleosides
    发明人:WATANABE KYOICHI A; DU JINFA
    摘要:The present invention is an efficient process for the manufacture of α-acyloxyacetaldehyde, a key intermediate in the synthesis of 1,3-oxathiolane and 1,3-dioxolane nucleosides.

    专利号:US-11999757-B2
    优先权日:2017-11-01
    标 题:Synthesis of boronate ester derivatives and uses thereof
    发明人:BOYER SERGE HENRI; HECKER SCOTT J; VERZIJL GERARDUS K M; HERMSEN PETRUS J
    权利人:MELINTA SUBSIDIARY CORP
    摘要:Disclosed herein are methods for the preparation of boronate derivatives in the synthesis of antimicrobial compounds and uses thereof. Disclosed herein includes method of making a compound of Formula (B) by reducing the ketone group of the keto-ester compound of Formula (A), and the reduction can be performed using a Ruthenium based catalyst system or using an alcohol dehydrogenase bioreduction system.

    专利号:US-2008125587-A1
    优先权日:2006-05-25
    标 题 :Synthesis of triazole compounds that modulate HSP90 activity
    发明人:CHIMMANAMADA DINESH U; LEE CHI-WAN; JAMES DAVID; ZHANG SHIJIE; YING WEIWEN; CHAE JUNGHYUN; PRZEWLOKA TERESA
    权利人:CHIMMANAMADA DINESH U; LEE CHI-WAN; JAMES DAVID; ZHANG SHIJIE; YING WEIWEN; CHAE JUNGHYUN; PRZEWLOKA TERESA
    摘要:The present invention provides novel methods of preparing triazole compounds which inhibit the activity of Hsp90. One embodiment of the invention is directed to methods for preparing a triazole compound represented by the following Structural Formula: n n n n n n n n n n or a tautomer, a pharmaceutically acceptable salt, solvate, or clathrate, or a prodrug thereof, comprising the steps of: a) reacting an amide represented by the following Structural Formula: n n n n n n n n n n with a thionation reagent to form a thioamide; b) reacting the thioamide of step a) with hydrazine to form a hydrazonamide; c) reacting the hydrazonamide of step b) with a carbonylation or a thiocarbonylation reagent. n In one embodiment, the present invention is a method of synthesis of a compound of formula (IA) n n n n n n n n n n or a tautomer, a pharmaceutically acceptable salt, solvate, or clathrate, or a prodrug thereof, comprising reacting a compound of formula (IIA) n n n n n n n n n n with an oxidizing agent, thereby producing a compound of formula (IA). n The present invention is also directed to a method of preparing a compound or a tautomer thereof represented by the following Structural Formula: n n n n n n n n n n or a tautomer, a pharmaceutically acceptable salt, solvate, or clathrate, or a prodrug thereof. The method comprises the step of reacting a first starting compound represented by the following Structural Formula: n n n n n n n n n n in the presence of a mercuric salt, with a second starting compound represented by the following Structural Formula:

    专利号:US-10669292-B2
    优先权日:2014-05-05
    标 题 :Synthesis of boronate salts and uses thereof
    发明人:HECKER SCOTT; BOYER SERGE
    权利人:REMPEX PHARMACEUTICALS INC
    摘要:Disclosed herein are boronate intermediates in the synthesis of antimicrobial compounds and the use and preparation thereof. Some embodiments relate to crystalline boronate salt derivatives and their use in the synthesis of therapeutic compounds.

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    品牌试剂参考报价(招募中)

    📌 第三方产品分析报告

    ✅ COA系统入驻 | 共享模式

    主要参考文献

    [参考文献]: A A Toropov, Et Al. Qspr Modeling Of Octanol/water Partition Coefficient For Vitamins By Optimal Descriptors Calculated With Smiles. Eur J Med Chem. 2008 Apr;43(4):714-40.
    [参考文献]: B V Pepich, Et Al. Capillary Gas Chromatography/pulsed Supersonic Jet/fluorescence Excitation Spectroscopy For The Identification Of Methylanthracenes In A Complex Environmental Sample. Anal Chem. 1986 Nov;58(13):2825-30.
    [参考文献]: C E Cerniglia, Et Al. Stereoselective Fungal Metabolism Of Methylated Anthracenes. Appl Environ Microbiol. 1990 Mar;56(3):661-8.
    [参考文献]: K Takegoshi, Et Al. Solid-State Photodimerization Of 9-Methylanthracene As Studied By Solid-State 13C Nmr. Solid State Nucl Magn Reson. 1998 Jun;11(3-4):189-96.
    [参考文献]: Kamlesh Awasthi, Et Al. Synergy Effects Of Electric And Magnetic Fields On Locally Excited-State Fluorescence Of Photoinduced Electron Transfer Systems In A Polymer Film. J Phys Chem A. 2009 Oct 8;113(40):10603-9.

    合成参考文献


    摘要:Toyota, S.; Iwanaga, T., Science of Synthesis, (2010) 45, 795.
    摘要:Toyota, S.; Iwanaga, T., Science of Synthesis, (2010) 45, 815.
    摘要:Molander, G. A.; Ryu, D., Science of Synthesis: C-1 Building Blocks in Organic Synthesis, (2013) 2, 31.
    摘要:Dai, X.; Shi, F., Science of Synthesis: Catalytic Reduction in Organic Synthesis, (2017) 1, 145.
    摘要:Fogel, M. S.; Shellnutt, Z. S.; Koide, K., Science of Synthesis: Dearomatizations, (2026) .
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