专利号:US-2021371291-A1 优先权日:2020-05-29 标 题:Hydrophobic zeolites with low silanol densities 发明人:FLAHERTY DAVID WILLIAM; BREGANTE DANIEL 权利人:UNIV ILLINOIS 摘要:A method for the synthesis of siliceous or heteroatom-substituted MFI zeolites (M-MFI; M=Si, Ti, Nb, or Ta) with tunable densities of SiOH that depend simply on the ratio of hydrofluoric acid (HF) to structure-directing agent (SDA; tetrapropylammonium hydroxide) used within the synthesis gel. The equilibrated ion exchange between OH − and F − ions forms tetrapropylammonium fluoride in situ, which does not lead to the formation of SiOH defects within M-MFI. Comparisons of infrared spectra from 15 distinct M-MFI materials show that the densities of SiOH groups within M-MFI decrease linearly with the ratio of HF:SDA, independent of the identity of the heteroatom within the framework.
专利号:US-2005124683-A1 优先权日:2003-09-17 标 题:HIV protease inhibitors, compositions containing the same, their pharmaceutical uses and materials for their synthesis 发明人:ALEGRIA LARRY A; CANAN-KOCH STACIE S; DRESS KLAUS R; HUANG BUWEN; KUMPF ROBERT A; LEWIS KATHLEEN K; MATTHEWS JEAN J; SAKATA SYLVIE K; VIRGIL SCOTT C 权利人:AGOURON PHARMA 摘要:The present invention relates to a series of chemical compounds useful as Human Immunodeficiency Virus (HIV) protease inhibitors and to the use of such compounds as antiviral agents. The invention further relates to pharmaceutical compositions containing such antiviral agents, and their uses and materials for their synthesis
专利号:US-11498041-B2 优先权日:2018-01-04 标题 :Optimized reactor configuration for optimal performance of the aromax catalyst for aromatics synthesis 发明人:MCGAHEE VINCENT D; HASENBERG DANIEL M 权利人:CHEVRON PHILLIPS CHEMICAL CO LP 摘要:A naphtha reforming reactor system comprising a first reactor comprising a first inlet and a first outlet, wherein the first reactor is configured to operate as an adiabatic reactor, and wherein the first reactor comprises a first naphtha reforming catalyst; and a second reactor comprising a second inlet and a second outlet, wherein the second inlet is in fluid communication with the first outlet of the first reactor, wherein the second reactor is configured to operate as an isothermal reactor, and wherein the second reactor comprises a plurality of tubes disposed within a reactor furnace, a heat source configured to heat the interior of the reactor furnace; and a second naphtha reforming catalyst disposed within the plurality of tubes, wherein the first naphtha reforming catalyst and the second naphtha reforming catalyst are the same or different.
专利号:US-11634648-B2 优先权日:2018-01-04 标 题 :Optimized reactor configuration for optimal performance of the aromax catalyst for aromatics synthesis 发明人:MCGAHEE VINCENT D; HASENBERG DANIEL M 权利人:CHEVRON PHILLIPS CHEMICAL CO LP 摘要:A naphtha reforming reactor system comprising a first reactor comprising a first inlet and a first outlet, wherein the first reactor is configured to operate as an adiabatic reactor, and wherein the first reactor comprises a first naphtha reforming catalyst; and a second reactor comprising a second inlet and a second outlet, wherein the second inlet is in fluid communication with the first outlet of the first reactor, wherein the second reactor is configured to operate as an isothermal reactor, and wherein the second reactor comprises a plurality of tubes disposed within a reactor furnace, a heat source configured to heat the interior of the reactor furnace; and a second naphtha reforming catalyst disposed within the plurality of tubes, wherein the first naphtha reforming catalyst and the second naphtha reforming catalyst are the same or different.
专利号:US-2014356279-A1 优先权日:2011-10-31 标 题 :Method for modifying titanium silicon molecular sieves 发明人:GUO HONGCHEN; LIU GUANGHONG; LIU LING; SU JI 权利人:Dalian Unversity of Technology; UNIV DALIAN TECH 摘要:This invention belongs to the technical field of inorganic chemical synthesis, relating to a modification method for titanium-silicalite zeolite (TS-1). The feature of the invention is pretreating on the TS-1, the TS-1 after pretreatment is modified by the mixture of TPAOH and alkali salts, the alkali salts can be the compounds containing lithium, sodium and potassium element, and then the modification is performed at last. The benefit of the invention is universal capable to modify the TS-1 synthesized by any method, specially the TS-1 with low cost one, the modification can enhance the catalytic performance on both gas and liquid phase epoxidation of propylene.
专利号:US-10287225-B2 优先权日:2015-05-13 标 题:Chain multiyne compound, preparation method and application thereof 发明人:XIA HAIPING; ZHUO QINGDE; LIN JIANFENG; ZHOU XIAOXI; CHEN ZHIXIN; SHAO YIFAN; ZHANG HONG; HE XUMIN 权利人:UNIV XIAMEN 摘要:The present invention relates to fields of organic chemistry and organometallic chemistry. The present invention discloses a chain multiyne compound, a preparation method thereof and an application in synthesizing a fused-ring metallacyclic compound. A structure of the chain multiyne compound in the present invention is shown as Formula I below. The present invention also provides a preparation method of the chain multiyne compound and an application thereof in a synthesis of a fused-ring metallacyclic compound. The chain multiyne compound disclosed in the present invention has multiple functional groups and the structure of the chain multiyne compound is adjustable. The chain multiyne compound can also be used to synthesize the fused-ring metallacyclic compound efficiently. The preparation method of the chain multiyne compound disclosed in the present invention is simple, which can be used to prepare the chain multiyne compound rapidly and efficiently.
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