CAS: 69335-91-7; Fluazifop

该化合物是一种选择性的系统性除草剂,主要用于控制各种作物,包括大豆和棉花的草杂草,属于除草剂的丙氧基丙烯丙烯丙烯类,其作用是抑制对植物中脂肪酸合成至关重要的酶乙酰氨-CoA carboxylase,其特点是它对哺乳动物和鸟类的毒性相对较低,因此在农业应用中成为首选.它通常是在出现后应用,针对积极生长的草,同时保留宽叶麻作物.该化合物一般是作为酯或酸制剂配制成的,以提高其效力和植物组织中的吸收程度.氟氮磷还因其在环境中的中度而闻名,需要谨慎管理,以防止对非目标物种和生态系统的潜在影响.同所有杀草剂一样,遵守安全准则和条例对于尽量减少其使用的风险至关重要.

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CAS号69045-85-8 4-{[5-(TRIFLUOR... | CAS号598-78-7 2-氯丙酸 | CAS号69335-90-6 甲基吡氟禾草灵

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    📜吡氟禾草灵-甲基置于lithium Hydroxide Monohydrate体系中,用 甲醇 作为反应溶剂,以84.9 %的收率获得产物吡氟禾草灵
    参考文献:一种天然萘醌衍生物及其制备方法与应用
    标题:一种天然萘醌衍生物及其制备方法与应用
    摘要:本发明涉及化合物合成技术和农药技术领域,具体涉及天然萘醌衍生物及其制备方法与应用,所述天然萘醌衍生物为含芳基羧酸的天然萘醌衍生物或含二苯醚单元的天然萘醌衍生物;本发明天然萘醌芳基羧酸类衍生物,天然萘醌二苯醚类衍生物,部分化合物在300A.I.G/ha剂量下对六种杂草(稗草,马唐,狗尾草,苘麻,反枝苋,马齿苋等)具有100%防除效果;该类化合物在低剂量下就可以获得较好的除草效果,且对玉米,小麦,花生,大豆,棉花等作物具有相对较好的安全性,在农业上可作为选择性除草剂用作作物,本发明所述化合物可作为潜在的psⅱ类抑制剂及阔叶杂草苗后除草剂开发使用,该衍生物的结构和制备工艺简单,生产成本低,应用前景广阔.

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    专利信息


    专利号:WO-2024256370-A1
    优先权日:2023-06-13
    标 题 :Synthesis of glufosinate using an amidase-based process
    发明人:ZIMMERMANN GUNTHER; POTT MORITZ STEFAN
    权利人:BASF SE
    摘要:The present invention relates to a method of preparing glufosinate, comprising the steps of hydrolysing an N-carbamoyl glufosinate amide with an Amidase enzyme to form an N- carbamoyl amino acid compound followed by cleaving off the carbamoyl moiety of said N- carbamoyl amino acid compound.

    专利号:US-2025120400-A1
    优先权日:2021-12-10
    标题:Synthesis of glufosinate using a hydantoinase-based process
    发明人:DITRICH KLAUS; BREUER MICHAEL; POTT MORITZ STEFAN; ZIMMERMANN GUNTHER; SEEMAYER STEFAN
    权利人:BASF SE
    摘要:The present invention relates to a method of manufacturing glufosinate, comprising the steps of hydrolysing a hydantoin with a Hydantoinase enzyme to form a N-carbamoyl amino acid compound followed by cleaving off the carbamoyl moiety of said N-carbamoyl amino acid compound.

    专利号:US-5614551-A
    优先权日:1994-01-24
    标题:Inhibitors of fatty acid synthesis as antimicrobial agents
    发明人:DICK JAMES D; KUHAJDA FRANCIS P
    权利人:UNIV JOHNS HOPKINS
    摘要:Fatty acid synthase (FAS) is overexpressed by certain infectious organisms that are resistant to most currently available antibiotics. Contrarywise, little FAS expression is identified in patient tissues. Inhibition of fatty acid synthesis is thus selectively toxic to invasive cells, while patient cells with low FAS activity are resistant. This invention provides a method of treating septic patients where fatty acid synthesis by invading cells is inhibited with resultant interruption of the disease process.

    专利号:US-2021386068-A1
    优先权日:2018-11-07
    标题 :Compositions comprising pyridine carboxylate herbicides and very long chain fatty acid (vlcfa) synthesis inhibitor herbicides
    发明人:KISTER JEREMY; SATCHIVI NORBERT M
    权利人:CORTEVA AGRISCIENCE LLC
    摘要:Disclosed herein are compositions comprising (a) a pyridine carboxylate herbicide or an agriculturally acceptable N-oxide, salt, or ester thereof and (b) a VLCFA synthesis inhibitor herbicide. Also disclosed herein are methods of controlling undesirable vegetation, comprising applying to vegetation or an area adjacent the vegetation or applying in soil or water to control the emergence or growth of vegetation (a) a pyridine carboxylate herbicide or an agriculturally acceptable N-oxide, salt, or ester thereof, and (b) a VLCFA synthesis inhibitor herbicide.

    专利号:US-2021352899-A1
    优先权日:2018-11-07
    标题 :Compositions comprising pyridine carboxylate herbicides and fatty acid and lipid synthesis inhibitor herbicides
    发明人:KISTER JEREMY; SATCHIVI NORBERT M
    权利人:CORTEVA AGRISCIENCE LLC
    摘要:Disclosed herein are compositions comprising (a) a pyridine carboxylate herbicide or an agriculturally acceptable N-oxide, salt, or ester thereof and (b) a fatty acid and lipid synthesis inhibitor (FA/LSI) herbicide, an agriculturally acceptable salt or ester thereof, or mixtures thereof. Also disclosed herein are methods of controlling undesirable vegetation, comprising applying to vegetation or an area adjacent the vegetation or applying in soil or water to control the emergence or growth of vegetation (a) a pyridine carboxylate herbicide or an agriculturally acceptable N-oxide, salt, or ester thereof and (b) a fatty acid and lipid synthesis inhibitor (FA/LSI) herbicide, an agriculturally acceptable salt or ester thereof, or mixtures thereof.

    专利号:ES-2717283-T3
    优先权日:2012-07-24
    标 题:Herbicidal compositions comprising 4-amino-3-chloro-5-fluoro-6- (4-chloro-2-fluoro-3-methoxyphenyl) pyridine-2-carboxylic acid or a derivative thereof and herbicides inhibitors of VLCFA synthesis and synthesis of fatty acids / lipids

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    ✅ COA系统入驻 | 共享模式

    主要参考文献


    1: Liu Z, Li P, Sun X, Zhou F, Yang C, Li L, Matsumoto H, Luo X. Fluazifop-P- butyl induced ROS generation with IAA (indole-3-acetic acid) oxidation in Acanthospermum hispidum D.C. Pestic Biochem Physiol. 2017 Nov;143:312-318. doi: 10.1016/j.pestbp.2017.10.005. Epub 2017 Oct 26.
    221:1120-1127. doi: 10.1016/j.foodchem.2016.11.048. Epub 2016 Nov 10.
    146:315-22. doi: 10.1016/j.chemosphere.2015.12.040. Epub 2015 Dec 28. 10(1):39-43. doi: 10.1177/096032719101000107. 11(4):247-54. doi: 10.1177/096032719201100402. 68(3):412-21. doi: 10.1002/ps.2282. Epub 2011 Oct 3. 16(19):3600. doi: 10.3390/ijerph16193600.

    合成参考文献


    参考文献:10.1016/j.pestbp.2014.04.011
    摘要:Cha TS, Najihah MG, Sahid IB, Chuah TS. Molecular basis for resistance to ACCase-inhibiting fluazifop in Eleusine indica from Malaysia. Pestic Biochem Physiol. 2014 May;111():7–13. doi: 10.1016/j.pestbp.2014.04.011.
    参考文献:10.1073/pnas.96.23.13387
    摘要:Zuther E, Johnson JJ, Haselkorn R, McLeod R, Gornicki P. Growth ofToxoplasma gondiiis inhibited by aryloxyphenoxypropionate herbicides targeting acetyl-CoA carboxylase. Proc. Natl. Acad. Sci. U.S.A. 1999 Nov 09;96(23):13387–92. doi: 10.1073/pnas.96.23.13387.
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