3,3,3-三氟丙烯置于dihydrogen Hexachloroplatinate 三氯硅烷体系中,化学反应生成 三氟丙基三氯硅烷 参考文献:Photochemical Chlorination Of Chloro(3,3,3-Trifluoropropyl) Silanes And The Synthesis Of Chloro(3,3,3-Trifluoropropenyl)Silanes 标题:Photochemical Chlorination Of Chloro(3,3,3-Trifluoropropyl) Silanes And The Synthesis Of Chloro(3,3,3-Trifluoropropenyl)Silanes 摘要: DOI:10.1007/bf00846718
专利号:US-8816117-B2 优先权日:2009-09-01 标 题 :Synthesis of fluorocarbofunctional silsesquioxanes 发明人:MARCINIEC BOGDAN; MACIEJEWSKI HIERONIM; DUTKIEWICZ MICHAL 权利人:MARCINIEC BOGDAN; MACIEJEWSKI HIERONIM; DUTKIEWICZ MICHAL; UNIV ADAM MICKIEWICZ 摘要:The subject of the invention is the method of synthesis of fluoracarbofunctional cage silsesquioxanes of the general formula in which•R 1 stands for HCF 2 (CF 2 ) n (CH 2 )mO(CH 2 ) 3 Si(CH 3 ) 2 O or HCF 2 (CF 2 ) n (CH 2 ) m O(CH 2 ) 3 group in which n=1-12, m=1-4;•R 2 , R 3 , R 4 , R 5 , R 6 , R 7 , R 8 can be the same as R 1 or different from it and stand all either for the (C 1 -C 25 ) alkyl group or any aryl group, based on hydrosilylation of fluoroalkyl-allyl ether with an appropriate hydrogen-silsesquioxane in the presence of siloxide rhodium complex [{Rh(OSiMe 3 )(cod)} 2 ] as a catalyst.
专利号:US-5455367-A 优先权日:1993-04-22 标 题:Method for the synthesis of silanes or organosilicon hydrides by the reduction of the corresponding silicon halides or organosilicon halides 发明人:KLEIN KLAUS-DIETER; KNOTT WILFRIED; KOERNER GOETZ 权利人:GOLDSCHMIDT AG TH 摘要:A method for the synthesis of silanes or organosilicon hydrides by the reduction of the corresponding silicon halides or organosilicon halides with a magnesium hydride in a liquid reaction medium is carried out by utilizing the following distinguishing features: n a) the use of non-pyrophoric, preferably autocatalytically produced, storage magnesium hydride as magnesium hydride, n b) the use of conventional ethers as reaction medium, and n c) the continuous removal of the magnesium halide formed being deposited on the surface of the magnesium hydride particles during the reaction by the action of mechanical energy or ultrasound so as to form a fresh surface.
专利号:WO-2011028142-A1 优先权日:2009-09-01 标 题:Synthesis of fluorocarbofunctional silsesquioxanes
专利号:CN-102482422-A 优先权日:2009-09-01 标 题 :Synthesis of Fluorocarbon Functional Silsesquioxanes
专利号:CN-102482422-B 优先权日:2009-09-01 标题 :Synthesis of Fluorocarbon Functional Silsesquioxanes
专利号:US-9416147-B2 优先权日:2014-04-03 标题 :Preparation of silazane compound 发明人:TONOMURA YOICHI; KUBOTA TOHRU 权利人:SHINETSU CHEMICAL CO 摘要:A silazane compound useful as synthesis intermediates for paint additives, polymer modifiers, pharmaceuticals and agricultural chemicals is efficiently prepared by reaction of a halosilane compound with an amino-containing compound in a solvent which is the same silazane compound as the target product.