CAS: 1459-93-4; Dimethyl Isophthalate

该化合物是一种有机化合物,被归类为芳香死炉,具体地说是一种异硫酸二甲基酯,其特点是无色至黄色液体色状,有略微甜味;DMI溶于乙醇和丙酮等有机溶剂,但在水中溶解性有限;该化合物主要用作聚酯和树脂生产的中间体,在塑料,涂料和纤维的制造中具有价值;其化学结构具有与异硫酸脊椎相连的两个甲基酯组的特点,有助于其再活性和在聚合化学中的效用;DMI因其热稳定性和对水解的耐性而闻名,适合各种工业用途;此外,必须谨慎处理DMI,因为它可能给接触健康带来风险,因此有必要在其使用和储存中采取适当的安全措施.

结构式图片

相似化合物

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欧盟法规

REACH注册ECHA物质ECHA物质C&L通报REACH预注册

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合成工艺路线路线简述

  • 合成目标产物 Dimethyl Isophthalate 主要起始原料 Methanol And Isophthalic Acid
  • (文献来源)合成步骤主要原料 Methanol 和 Isophthalic Acid
间甲基苯腈置于盐酸,铬酸体系中,化学反应生成间苯二甲酸二甲酯
参考文献:Weith; Landolt,Chemische Berichte,1875,Vol. 8,P. 716
标题:Weith; Landolt,Chemische Berichte,1875,Vol. 8,P. 716

海关参考信息

专利信息


专利号:US-4835247-A
优先权日:1988-08-08
标 题:Process for the synthesis of a copolyester adhesive resin
发明人:WILSON JOHN R; ROUSEK MARIAN M; MASSEY FRED L
权利人:GOODYEAR TIRE & RUBBER
摘要:Isophthalic acid is commonly utilized as a comonomer in the preparation of copolyester resins which are utilized as solution adhesives. Unfortunately, solutions of such resins frequently become hazy due to the presence of cyclic oligomers. This invention is based upon the unexpected discovery that the presence of protonic acids during the synthesis of the copolyester resins containing isophthalic acid utilizing conventional metallic catalysts results in solutions of the resins in organic solvents being virtually haze free. The subject invention more specifically reveals a process for synthesizing a polyethylene terephthalate/isophthalate/azelate copolyester resin which is particularly useful as a solution adhesive resin, comprising reacting ethylene glycol with a diacid component which is comprised of (a) from about 25 to about 45 mole percent terephthalic acid, (b) from about 10 to about 30 to about 55 mole percent azelaic acid based upon the diacid component; in the presence of at least one metallic catalyst selected from the group consisting of antimony compounds, titanium compounds; manganese compounds, and germanium compounds and in the presence of at least one protonic acid having a pKa of less than about 2.5; wherein the amount of metallic catalyst present is within the rang eof about 130 ppm to about 1500 ppm and wherein the amount of protonic acid present is within the range of about 50 ppm to about 500 ppm, with said amounts being based upon the weight of the copolyester resin produced.

专利号:US-4921929-A
优先权日:1988-08-08
标 题:Process for the synthesis of a copolyester adhesive resin
发明人:WILSON JOHN R; ROUSEK MARIAN M; MASSEY FRED L
权利人:GOODYEAR TIRE & RUBBER
摘要:Isophthalic acid is commonly utilized as a comonomer in the preparation of copolyester resins which are utilized as solution adhesives. Unfortunately, solutions of such resins frequently become hazy due to the presence of cyclic oligomers. This invention is based upon the unexpected discovery that the presence of protonic acids during the synthesis of the copolyester resins containing isophthalic acid utilizing conventional metallic catalysts results in solutions of the resins in organic solvents being virtually haze free. The subject invention more specifically reveals a process for synthesizing a polyethylene terephthalate/isophthalate/azelate copolyester resin which is particularly useful as a solution adhesive resin, comprising reacting ethylene glycol with a diacid component which is comprised of (a) from about 25 to about 45 mole percent terephthalic acid, (b) from about 10 to about 30 mole percent isophthalic acid, and (c) from about 30 to about 55 mole percent azelaic acid based upon the diacid component; in the presence of at least one metallic catalyst selected from the group consisting of antimony compounds, titanium compounds; manganese compounds, and germanium compounds and in the presence of at least one protonic acid having a pKa of less than about 2.5; wherein the amount of metallic catalyst present is within the range of about 130 ppm to about 1500 ppm and wherein the amount of protonic acid present is within the range of about 50 ppm to about 500 ppm, with said amounts being based upon the weight of the copolyester resin produced.

专利号:US-4452961-A
优先权日:1982-04-22
标题:Process for the synthesis of heat-curable silicone resins
发明人:KOERNER GOETZ; PRIESCH MANFRED; RAU HARALD; SCHAMBERG ECKEHARD
权利人:GOLDSCHMIDT AG TH
摘要:The invention relates to a process for heat-curable silicone resins and their synthesis by reacting a low molecular weight alkoxysilane with a low molecular weight polyol with 2 to 6 hydroxyl groups in the molecule. The reaction products have a very low viscosity, which is suitable for processing when about 20% of solvent, based on the non-volatile resin, are added.

专利号:US-2010055750-A1
优先权日:2008-09-03
标 题:Polyester synthesis
发明人:WOSNICK JORDAN H
权利人:XEROX CORP
摘要:The present disclosure provides for enzymatic polymerization to produce polyester resins suitable for use in manufacturing toners. In embodiments, crystalline copolymers, which are polyesters, may be synthesized from lactones, cyclic anhydrides, cyclic carbonates, and combinations thereof. These crystalline copolymers, in turn, may be utilized in the synthesis of toner particles.

专利号:US-6828466-B2
优先权日:2002-07-19
标题:Process for the synthesis of phenols from arenes
发明人:MALECZKA JR ROBERT E; SMITH III MILTON R; HOLMES DANIEL; SHI FENG
权利人:UNIV MICHIGAN STATE
摘要:A process to synthesize substituted phenols such as those of the general formula RR'R''Ar(OH) wherein R, R', and R'' are each independently hydrogen or any group which does not interfere in the process for synthesizing the substituted phenol including, but not limited to, halo, alkyl, alkoxy, carboxylic ester, amine, amide; and Ar is any variety of aryl or hetroaryl by means of oxidation of substituted arylboronic esters is described. In particular, a metal-catalyzed C-H activation/borylation reaction is described, which when followed by direct oxidation in a single or separate reaction vessel affords phenols without the need for any intermediate manipulations. More particularly, a process wherein Ir-catalyzed borylation of arenes using pinacolborane (HBPin) followed by oxidation of the intermediate arylboronic ester by OXONE is described.

专利号:US-2023348752-A1
优先权日:2019-10-08
标题:A water-soluble co-polyester polymer; a process of synthesis and a coating composition thereof
发明人:MAIKAP AKSHAY NARAYAN; 2 MAIKAP TANUSHREE
权利人:MAIKAP AKSHAY NARAYAN; 2 MAIKAP TANUSHREE
摘要:The present invention relates to a water-soluble co-polyester polymer. The polymer of the present invention is used for inline coating of BOPET film manufacturing, coating of BOPET film used as primer for vacuum metallization and surface coating of Aluminum sheets. The polymer of the present invention provides wide range of printability performances and high metal to film bond strength with minimum gain in weight. The disclosed polymer also provides Tape Test resistant printing and retort resistant layered/composite film. The present invention also discloses a coating composition for preparing peelable sealable biaxially oriented films with desired peel strength, minimum/negligible hazing and negligible anti-fog properties.
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主要参考文献

参考标题:Regioselective Conversion Of Arenes ToN-Aryl-1,2,3-Triazoles Using Ch Borylation
作者:Rajavel Srinivasan,Anthony G. Coyne,Chris Abell |发布日期:2014.9.8
摘要:A One‐pot Protocol For The Synthesis Of N‐aryl 1,2,3‐triazoles From Arenes By An Iridium‐catalyzed Ch Borylation/copper Catalyzed Azidation/click Sequence Is Described. 1 Mol % Of Cu(Otf)2 Was Found To Efficiently Catalyze Both The Azidation And The Click Reaction. The Applicability Of This Method Is Demonstrated By The Late‐stage Chemoselective Installation Of 1,2,3‐triazole Moiety Into Unactivated

合成参考文献


摘要:Muralirajan, K.; Rueping, M., Science of Synthesis, (2019) , 366.
摘要:Ouyang, Y.; Shou, J.-Y.; Qing, F.-L., Science of Synthesis: Special Topics, (2022) 1, 284.
摘要:Taira M et al; Mukogawa Joshi Daigaky Kiyo, Shokumotsu-Hen 25: 2 (1977)
摘要:Lyman WJ et al; Handbook of Chemical Property Estimation Methods. Washington, DC: Amer Chem Soc pp. 7-4, 7-5, 8-12 (1990)
摘要:Franke C et al; Chemosphere 29: 1501-14 (1994)
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