对硝基乙酰苯胺置于iron(III)-Acetylacetonate,一水合肼体系中,用 甲醇 用作溶剂,以99%的收率获得间氨基乙酰苯胺 参考文献:原位生成的氧化铁纳米晶体作为连续流法还原硝基芳烃的高效选择性催化剂 标题:原位生成的氧化铁纳米晶体作为连续流法还原硝基芳烃的高效选择性催化剂 摘要:两全其美:结合了均相和非均相纳米催化的优点,从而可以在溶液中原位生成高反应性的胶态fe 3 O 4纳米晶体,并在溶液中保留足够长的时间,从而可以将硝基芳烃有效地,选择性地还原为连续流动的苯胺.模式(请参阅方案).反应完成后,纳米颗粒聚集并且可以通过磁体回收. Doi:10.1002/anie.201205792
专利信息
专利号:WO-9410327-A1 优先权日:1992-10-28 标 题 :Enzymatic synthesis of polyaniline 发明人:ZEMEL HAYA; QUINN JOHN F 权利人:ALLIED SIGNAL INC 摘要:This invention relates to a process for the enzymatic synthesis of electrically conductive substituted and unsubstituted polyanilines. Aniline monomer(s), an oxidizing agent, which comprises an enzyme and an electron acceptor, and an acidifying agent are reacted together to form polyanilines.
专利号:US-5420237-A 优先权日:1991-08-29 标 题:Enzymatic synthesis of polyaniline 发明人:ZEMEL HAYA; QUINN JOHN F 权利人:ALLIED SIGNAL INC 摘要:This invention relates to a process for the enzymatic synthesis of electrically conductive substituted and unsubstituted polyanilines. Aniline monomer(s), an oxidizing agent, which comprises an enzyme and an electron acceptor, and an acidifying agent are reacted together to form polyanilines.
专利号:US-10557210-B2 优先权日:2014-02-24 标题 :Direct electrochemical synthesis of doped conductive polymers on metal alloys 发明人:KINLEN PATRICK JOHN; LAWLESS LAWRENCE MICHAEL 权利人:BOEING CO 摘要:This disclosure relates generally to the discovery of improved methods of reducing corrosion on metals and metal alloys without using hexavalent chromium reagents. More particularly, the disclosure relates to preparing corrosion resistant metals using doped conducting polymers such as polyaniline (PANI) on metal alloys such as aluminum alloys.
专利号:US-4719053-A 优先权日:1980-08-01 标题 :Beta-chloroethylsulfonylmethyl-benzoic halides as intermediates 发明人:SCHLAEFER LUDWIG; HAEHNLE REINHARD 权利人:HOECHST AG 摘要:New beta -chloroethylsuflonylmethyl-benzoic acid halides which can serve as fibre-reactive anchors for thesynthesis of novel organic, water-soluble compounds, preferably dyestuffs, having fibre-reactive and fibre-finishing properties, such as preferably dyestuff properties, and containing, as a fibre-reactive group, one or two beta -chloroethylsufonylmethylbenzoic acid amide groups. For the synthesis of these novel fibre-finishing compounds, said new beta -chloroethylsulfonylmethyl-benzoic acid halide compounds are reacted with an organic, water-soluble compound having fibre-finishing properties and continuing one or two amino groups. Also precursors of the fibre-finishing, fibre-reactive compounds, containing said beta -chloroethylsulfonylmethyl-benzxoic acid amid grouping, can be employed for their synthesis. The novel fibre-finishing compounds can be applied onto suitable fibre materials, such as especially cellulose fibre material and natural or synthetic polyamide fibre materials, and fixed on these fibre materials in a manner similar to application and fixation methods usual in the technique for fibre-reactive compounds. The fibre-finished material, such as dyed material, shows very good wet fastnesses.
专利号:US-4257942-A 优先权日:1977-10-06 标题:New water-insoluble azo dyes 发明人:DEFEO FRANCESCO; CIPOLLI ROBERTO 权利人:ACNA 摘要:The present invention relates to the synthesis of new dyes having the following general formula: wherein: D is the residue of a diazotizable component of the carbocyclic or heterocyclic series X is an ethylene group, optionally substituted by halogen-methyl, alkyl C1-C4, aryl, aralkyl or CH2OCO(HN)nR (wherein R and n have the meanings hereinafter defined); R is alkyl C1-C8 optionally substituted by halogen, CN,COOH; aryl optionally substituted by one or more atoms of halogen, alkyl C1-C4, alkoxyl C1-C4; alkoxyl C1-C4; alkoxyl C1-C8; Aryloxy; aralkoxy; cycloalkoxy; aralkyl; naphthyl optionally substituted by halogen; alkenyl C2-C8, optionally substituted by halogen, CN, COOH; R1 and R2, either like or unlike each other, may be alkyl C1-C4 optionally substituted by halogen or CN groups; aralkyl; R3 is H; halogen, alkyl C1-C4; alkoxyl C1-C4, optionally substituted. n is 0 or 1.
专利号:JP-6856608-B2 优先权日:2014-02-24 标 题:Direct electrochemical synthesis of dope conductive polymer on metal alloy
摘要:Guram, A. S.; Milne, J. E.; Tedrow, J. S.; Walker, S. D., Science of Synthesis: Cross Coupling and Heck-Type Reactions, (2012) 1, 105. 摘要:U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals., NX#02899