1,2-环氧-4-乙烯基环己烷,甲基二乙氧基硅烷置于氯铂酸,溶剂黄146体系中,用 乙醇 作为反应溶剂,化学反应 1.0H,以84%的收率获得产物3-[2-(二甲氧基甲基硅烷基)乙基]-7-氧杂双环[4.1.0]庚烷
参考文献:Unexpected Silicon Group Transfer In Difunctional Alkoxy Silanes
标题:Unexpected Silicon Group Transfer In Difunctional Alkoxy Silanes
摘要:During The Hydrosilylation Reaction Of A Difunctional Silane With Allyl Glycidyl Ether (Age),Two Scrambled Hydrosilylation Products Were Produced In Significant Amounts. This Scrambling Is Reaction Condition Dependent And Has Been Observed In A Few Other Examples. It Appears To Be The First Such Alkoxysilane Transformation To occur Under These Conditions,Although Similar Siloxane Transformations Have Been Documented. This Also Introduces A Method Of Preparing Certain Organofunctional Alkyldialkoxysilanes In High Purities Via Hydrosilylation,Where The Close Boiling Rearrangement By-Products Are Minimized.
DOI:10.1021/op010220C