CAS: 58473-78-2; 4,4-(Cyclohexane-1,1-Diyl)Bis(N,N-Di-P-Tolylaniline)

上下游产品

4-tolyl iodide 1,1-bis-(4-aminophenyl)cyclohexane

4-碘甲苯,1,1-双(4-氨基苯基)环己烷置于18-冠醚-6,Potassium Carbonate体系中,用 邻二氯苯 作为反应溶剂,化学反应 48.0H,以54%的收率获得产物4,4'-环己基二[n,N-二(4-甲基苯基)苯胺]
参考文献:Tuning The Energy Level Of Tapc: Crystal Structure And Photophysical And Electrochemical Properties Of 4,4'-(Cyclohexane-1,1-Diyl)Bis[n,N-Bis(4-Methoxyphenyl)Aniline]
标题:Tuning The Energy Level Of Tapc: Crystal Structure And Photophysical And Electrochemical Properties Of 4,4'-(Cyclohexane-1,1-Diyl)Bis[n,N-Bis(4-Methoxyphenyl)Aniline]
摘要:在有机发光二极管(oled)和过氧化物太阳能电池(psc)等有机电子器件中,空穴传输材料(htm)的能级对器件效率非常重要.在这方面,我们制备了 4,4'-(环己烷-1,1-二基)双[n,N-双(4-甲氧基苯基)苯胺] (Tapc-Ome),C46H46N2O4,以调节 4,4'-(环己烷-1,1-二基)苯胺的能级,4'-(环己烷-1,1-二基)双[n,N-双(4-甲基苯基)苯胺](tapc)的能级.研究人员对 Tapc-Ome 进行了系统表征,包括 1H 和 13C NMR,元素分析,紫外-可见吸收,荧光发射,密度泛函理论(dft)计算和单晶 X 射线衍射.tapc-Ome 在三菱空间群 P\overline{1} 中结晶,不对称单元中有两个分子.由于中央环己基环的立体阻碍,中央胺三角形平面与苯基平面之间的二面角从 26.56 (9) ° 到 60.34 (8) ° 不等.这种排列可能是由扩展结构中的弱氢键和 C-H...π(Ph)相互作用引起的.与 Tapc 相比,Tapc-Ome 的发射最大值出现了明显的浴原子偏移.通过将氧化电位与已知的哈米特参数(σ)进行比较,证实了氧化电位与取代基电子供能性质的密切关系.
DOI:10.1107/s2053229619007101

专利信息

专利号:US-2007287821-A1
优先权日:2004-09-06
标 题:Synthesis of Polynaphthalenes and Their Use
发明人：DOETZ FLORIAN; NORD SIMON; WEISS HORST; ROSCH JOACHIM
权利人:BASF AG
摘要:The present invention relates to a process for preparing polynaphthalene derivatives comprising repeating units of the general formula Ia and/or Ib n n nwhere R 1 , R 2 , R 1′ , R 2′ are as defined in the description. The present invention further relates to polynaphthalene derivatives which can be prepared by the process of the invention, films comprising or consisting of at least one polynaphthalene derivative according to the invention, organic light-emitting diodes (OLEDs) comprising at least one polynaphthalene derivative according to the invention, a light-emitting layer comprising or consisting of at least one polynaphthalene derivative according to the invention, an OLED comprising the light-emitting layer of the invention, devices comprising an OLED according to the invention and the use of the polynaphthalene derivatives of the invention as emitter substances in OLEDs.

专利号:US-8137822-B2
优先权日:2005-04-28
标题 :Synthesis of phenyl-substituted polyfluoroanthenes and the use thereof
发明人：DOETZ FLORIAN; NORD SIMON; WEISS HORST; ROESCH JOACHIM
权利人:DOETZ FLORIAN; NORD SIMON; WEISS HORST; ROESCH JOACHIM; BASF AG
摘要:The invention relates to a method for producing polyfluoroanthenes containing repeat units of general formula (I), said method consisting of the following steps: a) a monomer fluoroanthene derivative of formula IIa is produced; b) optionally the monomer fluoroanthene derivative of formula IIa is converted into another monomer fluoroanthene derivative of formula IIb; and c) the monomer fluoroanthene derivative of formula IIa or IIb is polymerised, optionally together with at least one other comonomer. The invention also relates to polyfluoroanthenes that can be produced according to the inventive method, films, a light-emitting layer containing or consisting of at least one inventive polyfluoroanthene, OLEDs containing at least one inventive polyfluoroanthene, OLEDs containing an inventive light-emitting layer, a device containing an inventive OLED, and the use of the inventive polyfluoroanthene emitter substances in OLEDs.

专利号:US-2024215280-A1
优先权日:2022-10-31
标 题:In situ core/shell perovskite nanocrystal material, method of preparation thereof, and light emitting device comprising the same
发明人：LEE TAE-WOO; KIM JOO SUNG
权利人:SEOUL NAT UNIV R&DB FOUNDATION; PEROLED CO LTD
摘要:The present inventive concept relates to an in situ core/shell perovskite nanocrystal film formed by an in situ nanocrystal synthesis process, a method for producing the same, and a light emitting device comprising the same as a light-emitting layer. The in situ core/shell perovskite nanocrystal film formed by the in situ nanocrystal synthesis process according to the present inventive concept exhibits a strong charge confinement effect by nanocrystal formation, and can simultaneously greatly improve the luminescence efficiency and lifetime by maintaining the fast charge transport capability of polycrystalline perovskite.

专利号:US-2017246690-A1
优先权日:2014-06-20
标 题:Stabilizing agent-free metal nanoparticle synthesis and uses of metal nanoparticles synthesized therefrom
发明人：MURPHY RYAN J; DREYFUS REMI; HOUGH LAWRENCE ALAN; MALASSIS LUDIVINE; MURRAY CHRISTOPHER; DONNIO BERTRAND
权利人:RHODIA OPERATIONS; CENTRE NAT RECH SCIENT; UNIV PENNSYLVANIA
摘要:Described herein are methods of synthesizing metal nanoparticles and the metal nanoparticles synthesized therefrom. Further described in the present disclosure are methods of modifying the surfaces of metal nanoparticles and the metal nanoparticles modified thereby. Also described herein are uses of such metal nanoparticles.

专利号:US-2008213623-A1
优先权日:2005-04-28
标题:Synthesis Of Phenyl-Substituted Polyfluoroanthenes and the Use Thereof

专利号:WO-2024264000-A2
优先权日:2023-06-21
标题:De novo stepwise template-independent synthesis of long polynucleotides