CAS: 54835-70-0; (S)-4-Hydroxy-3,5,5-Trimethyl-4-((R,E)-3-(((2R,3R,4S,5S,6R)-3,4,5-Trihydroxy-6-(Hydroxymethyl)Tetrahydro-2H-Pyran-2-yl)Oxy)But-1-En-1-yl)Cyclohex-2-En-1-One
该化合物是一个复杂的有机化合物,其独特的结构特征包括环己烷环和丙基甲基甲酰胺基.该化合物展示了一系列功能组,包括一个氯酮,氢氧基和醚,有助于其再活动及潜在的生物活动.该化合物的存在表明,该化合物可能具有晶体特性,可能影响其溶性及其与生物系统的互动.1,3R)和(4S)的命名表明,其立体化学化学化学学意味着具体的空间安排,这可能会对化合物在化学反应中的特性和行为产生重大影响.此外,三甲基组会增强其水隐特性,有可能影响其与其他分子的相互作用.
- 英文名称(S)-4-Hydroxy-3,5,5-Trimethyl-4-((R,E)-3-(((2R,3R,4S,5S,6R)-3,4,5-Trihydroxy-6-(Hydroxymethyl)Tetrahydro-2H-Pyran-2-yl)Oxy)But-1-En-1-yl)Cyclohex-2-En-1-One
- 中文名称长寿花糖甙
- IUPAC名称(S)-4-hydroxy-3,5,5-trimethyl-4-((R,E)-3-(((2R,3R,4S,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)tetrahydro-2H-pyran-2-yl)oxy)but-1-en-1-yl)cyclohex-2-en-1-one
- 其它别名-Dglucopyranosyloxy)- 1-Butenyl]-4-Hydroxy-3,5,- 5-Trimethyl-,(4S)-; 2-Cyclohexen-1-One,4-[(1E,3R)-3-(Aroseoside A; Vomifoliol 9-Glucoside; Roseoside; (4S)-3-Methyl-4-Hydroxy-4-[(1E,3R)-3-(β-D-Glucopyranosyloxy)-1-Butenyl]-5,5-Dimethyl-2-Cyclohexene-1-One; (S)-4-[(R,E)-3-(β-D-Glucopyranosyloxy)-1-Butenyl]-4-Hydroxy-3,5,5-Trimethyl-2-Cyclohexen-1-One; [(1R,2E)-1-Methyl-3-[(1S)-1-Hydroxy-2,6,6-Trimethyl-4-Oxo-2-Cyclohexenyl]-2-Propenyl]β-D-Glucopyranoside
- CAS编号54835-70-0
- MFCD编号:MFCD17214862
- FDA UNII编号:BOE4GN3B64
- 分子式:C19H30O8分子量:386.44
- 产品CID: 2512476
- 产品分类天然产物 → 倍半萜
- 相似结构搜索
- 产品信息参考
;;;; - InChIKey: SWYRVCGNMNAFEK-MHXFFUGFSA-N
- SWYRVCGNMNAFEK-KDCLJAHCNA-N
- 计算化学: 氢键受体数8.0氢键供体数5.0可旋转键数5.0
物理性质
MSDS等安全信息
上下游产品
2,2-Dimethyl-propionic acid (2R,3R,4S,5R,6R)-4,5-bis-(2,2-dimethyl-propionyloxy)-6-(2,2-dimethyl-propionyloxymethyl)-2-[(E)-(R)-3-((R)-1-hydroxy-2,6,6-trimethyl-4-oxo-cyclohex-2-enyl)-1-methyl-allyloxy]-tetrahydro-pyran-3-yl ester (6R,9R)-vomifoliol Acetic acid (E)-(R)-3-((R)-1-hydroxy-2,6,6-trimethyl-4-oxo-cyclohex-2-enyl)-1-methyl-allyl ester Acetic acid (E)-(R)-3-((1R,4S,6S)-4-hydroxy-2,2,6-trimethyl-7-oxa-bicyclo[4.1.0]hept-1-yl)-1-methyl-allyl ester(6S,9S)-6,9-dihydroxymegastiman-4-megastigmen-3-one-9-O-β-D-glucopyranoside D-glucose blumenol A 6,9-dihydroxymegastigma-4,7-dien-3-one合成工艺路线路线简述
📜(E,2R)-4-[(4R)-4-[tert-Butyl(Dimethyl)Silyl]Oxy-2,6,6-Trimethylcyclohexen-1-Yl]But-3-En-2-Ol置于吡啶,甲醇,Lithium Hydroxide,Sodium Methylate,Silver Trifluoromethanesulfonate,戴斯-马丁氧化剂,对甲苯磺酸,氟化氢吡啶,间氯过氧苯甲酸,1,1,3,3-四甲基脲体系中,用 四氢呋喃,二氯甲烷,苯 作为反应溶剂,化学反应 50.08H,反应生成 长寿花糖甙
参考文献:Synthesis Of Optically Active Vomifoliol And Roseoside Stereoisomers
标题:Synthesis Of Optically Active Vomifoliol And Roseoside Stereoisomers
摘要:通过α-炔醇11A或11B有效地制备的α,β-炔酮10进行不对称转移氢化反应,成功合成了光学活性的vomifoliol立体异构体1-4及其葡萄糖苷,玫瑰苷立体异构体5-8.同时,还进行了这些立体异构体的HPLC分离.
DOI:10.1248/cpb.53.541
海关参考信息
- 2901210000-乙烯
2901220000-丙烯
2905122000-异丙醇
2905143000-叔丁醇 - 💡 提示：海关信息按照顺序优先匹配，如需确认的海关信息，请参考相关资料。
- 详情请参考：📖 海关编码查询和海关进出口税则
供应商参考报价(招募中)
品牌试剂参考报价(招募中)
📌 第三方产品分析报告
合成参考文献
参考文献:10.1021/jf034954v
摘要:Kikuzaki H, Kayano S, Fukutsuka N, Aoki A, Kasamatsu K, Yamasaki Y, Mitani T, Nakatani N. Abscisic acid related compounds and lignans in prunes (Prunus domestica L.) and their oxygen radical absorbance capacity (ORAC). J Agric Food Chem. 2004 Jan 28;52(2):344–9. doi: 10.1021/jf034954v.
参考文献:10.1248/cpb.52.980
摘要:Kanchanapoom T, Ruchirawat S, Kasai R, Otsuka H. Aliphatic alcohol and iridoid glycosides from Asystasia intrusa. Chem Pharm Bull (Tokyo). 2004 Aug;52(8):980–2. doi: 10.1248/cpb.52.980.
参考文献:10.1055/s-0029-1240868
摘要:Frankish N, de Sousa Menezes F, Mills C, Sheridan H. Enhancement of insulin release from the beta-cell line INS-1 by an ethanolic extract of Bauhinia variegata and its major constituent roseoside. Planta Med. 2010 Jul;76(10):995–7. doi: 10.1055/s-0029-1240868.
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