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CAS号18209-60-4 二甲基二甲氨基氯硅烷 | CAS号2449-49-2 N,N-二甲基-1-苯乙胺 | CAS号103-83-3 N,N-二甲基苄胺 | CAS号1199-99-1 1-dimethylamino... | CAS号15184-96-0 N,N-二甲基-4-硝基苄胺 | CAS号4052-88-4 BENZENEMETHANAM...📜二甲基二甲氨基氯硅烷置于锂硼氢体系中,化学反应生成二甲硅基二甲胺
参考文献:Noeth,H.,Zeitschrift Fur Naturforschung. Teil B: Chemie,Biochemie,Biophysik,Biologie,1961,Vol. 16,P. 618-620
标题:Noeth,H.,Zeitschrift Fur Naturforschung. Teil B: Chemie,Biochemie,Biophysik,Biologie,1961,Vol. 16,P. 618-620
专利信息
专利号:US-4730074-A
优先权日:1986-12-31
标 题 :Vapor phase alcoholysis of aminosilanes and carbamatosilanes
发明人:LEWIS KENRICK M; MENDICINO FRANK D; CHU NAN S
权利人:UNION CARBIDE CORP
摘要:A vapor phase process for the synthesis of alkoxysilanes of the general formula HSi(OR'') x (R') 3-x which comprises reacting n (a) a silane of the general formula n n HSi(NRR').sub.x (R').sub.3-x n n wherein R, R' and R' are individually hydrogen or an aryl or alkyl group optionally containing unsaturation, each having from one to eight carbon atoms inclusive, and where R' may also be an alkoxy or carbamato group and where x has a value of from one to three; with n (b) an alcohol of the general formula n n R''OH n n wherein R'' is an aryl group, or an alkyl group optionally containing unsaturation, each having from one to twenty carbon atoms inclusive and optionally substituted said reaction taking place in the presence of n (c) a catalyst n in which both the silane and the alcohol are present in gaseous form in a stoichiometric ratio of 0.4 to 1.05 moles of alcohol per mole of silicon-nitrogen bonds and where said catalyst is present in an amount from 0.01 to 10 mole percent of the silicon-nitrogen bonds.
专利号:US-4668812-A
优先权日:1985-12-31
标 题 :Process for the preparation of olefinic silanes and siloxanes
发明人:QUIRK JENNIFER M; KANNER BERNARD
权利人:UNION CARBIDE CORP
摘要:A novel synthesis for silanes and siloxanes containing olefinic bonds wherein an aminosilane, siloxane alkoxysilane or alkylalkoxysilane and an olefin undergo a dehydrocondensation in the presence of a rhodium or ruthenium catalyst.
专利号:EP-0488681-A1
优先权日:1990-11-27
标题:N, N-dialkylaminoalkyl-N', N'-dialkylaminodimethylsilane
发明人:SHINOHARA TOSHIO; KUDO MUNEO; MATSUMURA KAZUYUKI
权利人:SHINETSU CHEMICAL CO
摘要:A novel silylation agent for organic synthesis, which is also effective in improving the performance of adhesives for binding an inorganic material with an organic material, namely N,N-dialkylaminoalkyl-N′,N′-dialkylaminodimethylsilane represented by the following formula:n n wherein R¹, R², R³ and Râ?´ independently represent alkyls, and n is 1, 2 or 3.