CAS: 1679-51-2; Cyclohex-3-En-1-Ylmethanol

相似化合物

4771-80-6 6493-77-2 5708-19-0

上下游产品

2-(2-丙烯基)己-5-烯-1-醇 2-(2-Propenyl)Hex-5-En-1-Ol 151259-42-6
3-环己烯-1-甲酸 1,2,5,6-Tetrahydrobenzoic Acid 4771-80-6

3-环己烯甲醛置于[fe(Pnpme-Ipr)(Co)(H)(Br)],氢气,1,8-二氮杂双环[5.4.0]十一碳-7-烯体系中,用 乙醇 用作溶剂,40.0 °C,3.0 Mpa 条件下,反应 16.0H,以98%的收率获得3-环己烯-1-甲醇
参考文献:醛的高效选择性加氢:结构明确的 Fe(II) 催化剂具有贵金属活性
标题:醛的高效选择性加氢:结构明确的 Fe(II) 催化剂具有贵金属活性
摘要:[fe(Pnp Me-I Pr)(Co)(H)(Br)]和[fe(Pnp Me-I Pr)(H) 2 (Co)]的合成及醛类均相加氢催化剂的应用被描述.这些系统被发现是迄今为止报道的该过程最有效的催化剂之一,并且构成了催化过程的罕见例子,该催化过程允许在酮和其他可还原官能团存在的情况下选择性还原醛.在某些情况下,Ton 和 Tof 分别达到 80000 和 20000 H-1 .在化学计量实验和计算研究的基础上,提出了一种通过反式二氢化物中间体进行的机制.氢化物配合物的结构也通过x射线晶体学得到证实.
Doi:10.1021/acscatal.6B00436

专利信息

专利号:US-11583842-B2
优先权日:2019-07-24
标题 :Zwitterionic catalysts for (trans)esterification: application in fluoroindole-derivatives and biodiesel synthesis
发明人：YEUNG YING-YEUNG; LAM YING-PONG; KE ZHIHAI; WANG XINYAN; TAN FEI; NG WING-HIN; TSE YING-LUNG STEVE
权利人:UNIV HONG KONG CHINESE
摘要:An amide/iminium zwitterion catalyst has a catalyst pocket size that promotes transesterification and dehydrative esterification. The amide/iminium zwitterions are easily prepared by reacting aziridines with aminopyridines. The reaction can be applied a wide variety of esterification processes including the large-scale synthesis of biodiesel. The amide/iminium zwitterions allow the avoidance of strongly basic or acidic condition and avoidance of metal contamination in the products. Reactions are carried out at ambient or only modestly elevated temperatures. The amide/iminium zwitterion catalyst is easily recycled and reactions proceed in high to quantitative yields.

专利号:US-5637757-A
优先权日:1995-04-11
标 题 :One-pot synthesis of ring-brominated benzoate compounds
发明人：HILL JOHN E; FAVSTRITSKY NICOLAI A; MAMUZIC RASTKO I; BHATTACHARYA BHABATOSH
权利人:GREAT LAKES CHEMICAL CORP
摘要:A method of preparing tetrabromobenzoate compounds from tetrabromophthalic anhydride by reacting tetrabromophthalic anhydride with alcohol in the presence of a decarboxylation catalyst. The reaction may be carried out in an excess of alcohol, or with a near stoichiometric amount of alcohol by performing the reaction in an inert solvent.

专利号:US-2004053999-A1
优先权日:1997-09-17
标题 :Novel compounds and methods for synthesis and therapy
发明人：BISCHOFBERGER NORBERT W; DAHL TERRENCE C; HITCHCOCK MICHAEL J M; KIM CHOUNG U; LEW WILLARD; LIU HONGTAO; MILLS ROGER G; WILLIAMS MATTHEW A
摘要:Novel compounds are described. The compounds generally comprise an acidic group, a basic group, a substituted amino or N-acyl and a group having an optionally hydroxylated alkane moiety. Pharmaceutical compositions comprising the inhibitors of the invention are also described. Methods of inhibiting neuraminidase in samples suspected of containing neuraminidase are also described. Antigenic materials, polymers, antibodies, conjugates of the compounds of the invention with labels, and assay methods for detecting neuraminidase activity are also described.

专利号:US-6225341-B1
优先权日:1995-02-27
标 题:Compounds and methods for synthesis and therapy
发明人：BISCHOFBERGER NORBERT W; KIM CHOUNG U; LEW WILLARD; LIU HONGTAO; WILLIAMS MATTHEW A
权利人:GILEAD SCIENCES INC
摘要:Novel compounds are described. The compounds generally comprise an acidic group, a basic group, a substituted amino or N-acyl and a group having an optionally hydroxylated alkane moiety. Pharmaceutical compositions comprising the inhibitors of the invention are also described. Methods of inhibiting neuraminidase in samples suspected of containing neuraminidase are also described. Antigenic materials, polymers, antibodies, conjugates of the compounds of the invention with labels, and assay methods for detecting neuraminidase activity are also described.

专利号:WO-9632368-A1
优先权日:1995-04-11
标题:One-pot synthesis of ring-brominated benzoate compounds

专利号:EP-0825974-A1
优先权日:1995-04-11
标 题 :One-pot synthesis of ring-brominated benzoate compounds