专利号:US-10266467-B2 优先权日:2017-08-02 标 题:Synthesis of glycols via transfer hydrogenation of alpha-functional esters with alcohols 发明人:CHAKRABORTY SUMIT; HEMBRE ROBERT THOMAS 权利人:EASTMAN CHEM CO 摘要:A transfer hydrogenation process for forming vicinal diols by hydrogenating 1,2-dioxygenated organic compounds using alcohols as the reducing agent instead of the traditional H 2 gas. The transfer hydrogenation is carried out under milder conditions of temperature and pressure than is typical for ester hydrogenation with H 2 . The milder conditions of operation provide benefits, such as lower operating and capital costs for industrial scale production as well as savings in product purification due to the avoidance of by-products from exposure of reaction mixtures and products to high temperatures.
专利号:US-2005209355-A1 优先权日:2004-03-22 标 题:[Novel Reactions and the Products of Such Reactions] 发明人:ROITMAN LIPA L 权利人:ROITMAN LIPA L 摘要:A process for the synthesis of novel compounds is described comprising reacting tetrachloroethylene with substances containing active methylene group in the presence of free radical initiators. Also, a process for grafting tetrachloroethylene is described comprising reacting these compounds with polymers containing active methylene group in the presence of free radical initiators. Furthermore, a method of conducting such reactions to high conversion is described, comprising conducting the reactions in the reflux condensate. The present invention provides a novel and high yield route for heretofore unobtainable materials.
专利号:US-8053161-B2 优先权日:2006-09-25 标 题 :Resist composition, resin for use in the resist composition, compound for use in the synthesis of the resin, and pattern-forming method using the resist composition 发明人:WADA KENJI; SAEGUSA HIROSHI 权利人:FUJIFILM CORP 摘要:A resist composition comprises: (A) a resin capable of increasing its solubility in an alkali developer by action of an acid; (B) a compound capable of generating an acid upon irradiation with actinic ray or radiation; (C) a resin having at least one of a fluorine atom and a silicon atom; and (D) a solvent, wherein the resin (C) has a degree of molecular weight dispersion of 1.3 or less and a weight average molecular weight of 1.0×10 4 or less.
专利号:US-10106487-B2 优先权日:2015-06-10 标 题:Oxidative dehydrogenation of lactate esters to pyruvate esters 发明人:UMBARKAR SHUBHANGI BHALCHANDRA; DONGARE MOHAN KERABA; PANDHARE SWATI LAXMIKANTRAO; KHOMANE SONALI BALASAHEB; DOKE DHANANJAY SHAHAURAJ 权利人:COUNCIL SCIENT IND RES 摘要:The present invention relates to a simple one step oxidative dehydrogenation process for the synthesis of alkyl pyruvate with 100% selectivity towards alkyl pyruvate comprising reacting an alkyl lactate in the presence of catalyst at the temperature ranging from 25-100° C. for the time period ranging from 5 to 40 hours in an organic solvent and hydrogen peroxide to afford alkyl pyruvate.
专利号:US-11725220-B1 优先权日:2020-08-26 标 题:Production of fusel lactates via biocatalysis 发明人:DAVIS RYAN WESLEY; VARMAN ARUL MOHZY; SARNAIK ADITYA PANDHARINATH; JHA AMIT KUMAR 权利人:NAT TECH & ENG SOLUTIONS SANDIA LLC; UNIV ARIZONA STATE 摘要:Microbial enzymes are used for esterification of biomass-derived substrates for production of industrially valuable esters. E. coli was used as an efficient platform for recombinant synthesis of fusel lactates such as the green solvent ethyl lactate.
专利号:US-9709891-B2 优先权日:2005-12-09 标 题:Positive resist composition, resin used for the positive resist composition, compound used for synthesis of the resin and pattern forming method using the positive resist composition 发明人:KANDA HIROMI; KANNA SHINICHI 权利人:FUJIFILM CORP 摘要:A positive resist composition comprises: (A) a resin of which solubility in an alkali developer increases under an action of an acid; (B) a compound capable of generating an acid upon irradiation with actinic rays or radiation; (C) a resin having at least one of a fluorine atom and a silicon atom; and (D) a solvent; and a pattern forming method using the positive resist composition.
[参考文献]: Domenico Pirozzi, Et Al. Lipase-Catalyzed Transformations For The Synthesis Of Butyl Lactate: A Comparison Between Esterification And Transesterification. Biotechnol Prog. 2006 Mar-Apr;22(2):444-8. [参考文献]: J J Clary, Et Al. Safety Assessment Of Lactate Esters. Regul Toxicol Pharmacol. 1998 Apr;27(2):88-97. [参考文献]: Marwa Ahmed Sallam, Et Al. An Insight On Human Skin Penetration Of Diflunisal: Lipogel Versus Hydrogel Microemulsion. Drug Dev Ind Pharm. 2015 Jan;41(1):141-7. [参考文献]: Marwa Ahmed Sallam, Et Al. Optimization, Ex Vivo Permeation, And Stability Study Of Lipid Nanocarrier Loaded Gelatin Capsules For Treatment Of Intermittent Claudication. Int J Nanomedicine. 2015 Jul 13:10:4459-78. [参考文献]: Michele Trotta, Et Al. Preparation Of Griseofulvin Nanoparticles From Water-Dilutable Microemulsions. Int J Pharm. 2003 Mar 26;254(2):235-42.
合成参考文献
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