CAS: 106-86-5; 3-Vinyl-7-Oxabicyclo[4.1.0]Heptane

相似化合物

1195-92-2 64630-63-3 36099-51-1

上下游产品

peracetic acid 4-ethenylcyclohexene 1,1,3,3-tetrachloropropanone acetic acid (2-(7-oxabicyclo[4.1.0]heptan-3-yl)ethyl)triethoxysilane 1,3-bis(2(3,4-epoxycyclohexyl)ethyl)-1,1,3,3-tetramethyldisiloxane 3,4-dihydroxy-1-vinylcyclohexane 4-azido-3-hydroxy-1-vinylcyclohexane

4-乙烯基-1-环己烯置于过氧乙酸,[mncl2(2-(3-Pyrazolyl)Pyridine)2].h2O体系中,用 乙腈 用作溶剂,化学反应 3.05H,反应生成1,2-环氧-4-乙烯基环己烷
参考文献:含吡唑基配体的可重复使用的锰化合物,用于烯烃环氧化反应†
标题:含吡唑基配体的可重复使用的锰化合物,用于烯烃环氧化反应†
摘要:我们描述了含有二齿配体2-(3-吡唑基)吡啶,Pypz-H和3(5)-(2-羟苯基)吡唑,Hophpz-H的新锰(II)和锰(III)配合物的合成与式[mnx 2(pypz-H)2 ](x =氯-,1,Cf 3 So 3-,2,Oac-,3或no 3-(4)),的mncl 2(pypz-H)( H 2 O)2 ],5或[mncl(ophpz-H)2 ],6.所有的配合物已通过分析,光谱和电化学技术进行了表征.单一x射线结构分析显示,配合物1-5中有六配位的mn(II)离子,而配合物6中有五配位的mn(III)离子.化合物5是含有cl和h 2 O配体以及二齿氮配体的mn(II)的第一共晶体.配合物的催化活性的1-6已经过测试关于苯乙烯的环氧化,并且在的情况下1,5和6,其他烯烃已经在不同的介质中使用过氧乙酸作为氧化剂进行环氧化,其中甘油是一种从未在使用过氧乙酸作为氧化剂的环氧化
Doi:10.1039/c5Dt02787J

专利信息

专利号:WO-2023152730-A1
优先权日:2022-02-14
标题 :Amine-borane adducts in the synthesis of polyester and its copolymers using cyclic esters and compositions thereof
发明人：FENG XIAOSHUANG; LIU JINGJING; GNANOU YVES
权利人:UNIV KING ABDULLAH SCI & TECH
摘要:Embodiments of the present disclosure provide for the process of synthesis of polyester and its copolymers through (co)polymerization of cyclic esters and with other oxygenated monomers using amine-borane adduct. Embodiments of the present disclosure further describe the controlled anionic ring-opening polymerization of the cyclic compounds. Embodiments of the present disclosure also describe the polymerization of cyclic compounds using the synergistic effect of amines and thioureas. Embodiments of the present disclosure also describe compositions of polymers formed by the said process.

专利号:US-5073643-A
优先权日:1990-08-30
标 题 :High yield synthesis of hydroxyl-containing cationic photoinitiators
发明人：CRIVELLO JAMES V
权利人:POLYSET CORP
摘要:Synthesis use of a new class of diaryliodonium salt photo and thermal polymerization initiators in which the aryl groups are substituted with alkoxy group bearing hydroxy groups. Good to excellent yields are obtained of diaryliodonium salts in which the aryl groups are substituted with long chain alkoxy groups, which alkoxy groups also possess at least one hydroxyl moiety attached at the 2-position of an alkoxy group. The resultant salts have enhanced solubility when compared with their lower molecular weight counterparts. The hydroxyl groups serve as chain transfer agents; and, in cross linking UV-induced cationic polymerizations, the hydroxyl groups effect marked accelertion on polymerization rates. The salts also have excellent compatability with nonpolar monomers such as epoxidized oil and poly(1,2-butadience oxide) and provide further benefits when they are used along with copper cocatalysts in thermally curable polymer systems. In the latter form of cases, the secondary hydroxyl group serves as a reducing agent for the copper (II) complex.

专利号:US-2010280189-A1
优先权日:2005-11-30
标 题 :Synthesis of cycloaliphatic substituted silane monomers and polysiloxanes for photo-curing
发明人：DWORAK DAVID P; SOUCEK MARK D
权利人:UNIV AKRON
摘要:The present invention generally relates to compositions including linear cycloaliphatic siloxane polymers, and the cyclic cycloaliphatic siloxane oligomers from which they are made. The present invention also generally relates to methods for making cycloaliphatic siloxane polymers, and the cyclic cycloaliphatic siloxane oligomers from which they are made. Some embodiments relate to cationic polymerization of methyl, cyclopentyl, and/or cyclohexyl substituted polysiloxanes. In some embodiments the cationic polymerization is a cationic ring-opening polymerization.

专利号:US-3979460-A
优先权日:1974-07-01
标 题 :Process for the preparation of an organomercaptophenol from sulfur, a 2,6-disubstituted phenol, and an activated olefin or an epoxy compound
发明人：HAY ALLAN S
权利人:GEN ELECTRIC
摘要:A process for the preparation of an organomercaptophenol is described which comprises the reaction of sulfur with a 2,6-disubstituted phenol carried out in the presence of (1) a base, (2) an activated olefin or an epoxy compound, (3) and a solvent with a high dielectric constant. The organomercaptophenols produced by this process are useful as monomers in the synthesis of esters, carbonates, ethers, epoxy compounds, among many other chemicals synthesized from monohydric phenols. In addition, the oganomercaptophenols are also useful as antioxidants.

专利号:US-4064158-A
优先权日:1974-07-01
标题:Process for the preparation of an organomercaptophenol from sulfur, a 2,6-disubstituted phenol, and an activated olefin or an epoxy compound
发明人：HAY ALLAN S
权利人:GEN ELECTRIC
摘要:A process for the preparation of an organomercaptophenol is described which comprises the reaction of sulfur with a 2,6-disubstituted phenol carried out in the presence of (1) a base, (2) an activated olefin or an epoxy compound, (3) and a solvent with a high dielectric constant. The organomercaptophenols produced by this process are useful as monomers in the synthesis of esters, carbonates, ethers, epoxy compounds, among many other chemicals synthesized from monohydric phenols. In addition, the organomercaptophenols are also useful as antioxidants.

专利号:US-6124418-A
优先权日:1992-06-11
标题 :Selective catalysts for the synthesis of epoxysilicone monomers and polymers
发明人：CRIVELLO JAMES VINCENT; FAN MINGXIN
权利人:GEN ELECTRIC
摘要:The invention provides a method for making a curable epoxysilicone composition through the hydrosilation reaction between an ethylenically unsaturated epoxide and an SiH-containing silicone to produce an epoxysilicone product, and catalyzed by a quaternary ammonium, phosphonium or arsonium hexahaloplatinate which does not promote the oxirane ring-opening reaction of either the ethylenically unsaturated epoxide starting material or the epoxysilicone product. The invention also provides for a curable epoxysilicone composition made by the above method.