CAS: 929626-27-7; Potassium Benzofuran-2-Yltrifluoroborate

相似化合物

98437-24-2 331833-99-9 223576-64-5

📜2,3-苯并呋喃置于[ir(Cod)(Ome)]2 Potassium Hydrogen Difluoride,4,4'-二叔丁基-2,2'-二吡啶体系中,用 四氢呋喃,水 作为反应溶剂,化学反应 21.0H,反应生成 苯并呋喃-2-三氟硼酸钾
参考文献:One-Pot Synthesis Of Arylboronic Acids And Aryl Trifluoroborates By Ir-Catalyzed Borylation Of Arenes
标题:One-Pot Synthesis Of Arylboronic Acids And Aryl Trifluoroborates By Ir-Catalyzed Borylation Of Arenes
摘要:The Synthesis Of Arylboronic Acids And Aryl Trifluoroborates In A One-Pot Sequence By Ir-Catalyzed Borylation Of Arenes Is Reported. To Prepare The Arylboronic Acids,The Ir-Catalyzed Borylation Is Followed By Oxidative Cleavage Of The Boronic Ester With Naio4. To Prepare The Aryltrifluoroborate,The Ir-Catalyzed Borylation Is Followed By Displacement Of Pinacol By Khf2. These Two-Step Sequences Give Products That Are More Reactive Toward Subsequent Chemistry Than The Initially Formed Pinacol Boronates.
DOI:10.1021/ol062903O