CAS: 1123-85-9; 2-Phenylpropan-1-Ol

相似化合物

37778-99-7 19141-40-3 492-37-5

上下游产品

CAS号34713-70-7 2-苯基丙醛 | CAS号2085-88-3 2-苯基环氧丙烷 | CAS号4217-66-7 2-苯基-1,2-丙二醇 | CAS号624286-52-8 trimethyl(2-phe... | CAS号492-37-5 2-苯基丙酸 | CAS号292638-84-7 phenylene-ethylene | CAS号201230-82-2 carbon monoxide | CAS号110-89-4 六氢吡啶 | CAS号98-83-9 α-甲基苯乙烯 | CAS号31508-44-8 Alpha-甲基苯乙酸甲酯 | CAS号3910-35-8 1,3,3-三甲基-1-苯基茚满 | CAS号1459-01-4 1-iodopropan-2-... | CAS号492-37-5 2-苯基丙酸 | CAS号98-86-2 苯乙酮 | CAS号101-41-7 苯乙酸甲酯 | CAS号34713-70-7 2-苯基丙醛 | CAS号637-50-3 β-甲基苯乙烯 (顺反混合物)... | CAS号98-83-9 α-甲基苯乙烯 | CAS号873-66-5 反-β-甲基苯乙烯 | CAS号766-90-5 顺-β-甲基苯乙烯

2-苯基丙醛置于[ir(2,2':6',2''-Terpyridine)(Me2Phen)Cl](Pf6)2,Sodium Formate体系中,用 乙醇,水 用作溶剂,化学反应 0.42H,以94%的收率获得2-苯基-1-丙醇
参考文献:基于聚吡啶基铱(III)的醛的高度化学选择性加氢催化剂
标题:基于聚吡啶基铱(III)的醛的高度化学选择性加氢催化剂
摘要:使用hcoor(r = H,Na,Nh 4)作为氢源的铱催化的羰基化合物的转移加氢(th)是关键过程,因为它提供了清洁的过程并且易于执行.但是,现有的高效铱催化剂只能在较窄的ph值下工作.因此,不适用于各种各样的基板.因此,开发在宽ph范围内工作的新型催化剂是必不可少的,因为它可以获得更广阔的应用范围.在这里我们报告了高效的聚吡啶基铱(III)催化剂[ir(tpy)(l)cl](pf 6)2 {其中tpy = 2,2':6',2''-三联吡啶,L = Phen(1,10-菲咯啉),Me 2 Phen(4,7-二甲基-1,10-菲咯啉),Me 4苯(3,4,7,8-四甲基-1,10-菲咯啉),Me 2Bpy(4,4'-Dimethyl-2-2'-Dipyridylyl)}用于将乙醛在乙醇水溶液和甲酸钠作为氢化物来源中化学选择性还原为醇.该反应可在ph范围6至11的宽ph范围内有效地进行.这
Doi:10.1016/j.Jcat.2019.08.025

专利信息

专利号:US-6600040-B2
优先权日:2000-06-08
标 题:Process for the synthesis of (2R, 2-alpha-R, 3A)-2-[1-(3,5-bis(trifluoromethyl)phenyl)ethoxy]-3-(4-fluorophenyl)-1, 4-oxazine
发明人：BRANDS KAREL M JOS; TSAY FUH-RONG; CONRAD KAREN M; ZHAO MATTHEW M
权利人:MERCK & CO INC
摘要:The present invention is concerned with novel processes for the preparation of (2R, 2-alpha-R, 3a)-2-[1-[3,5-bis(trifluoromethyl)phenyl]ethoxy-3-(4-fluorophenyl)-1,4-oxazine. This compound is useful as an intermediate in the synthesis of compounds which possess pharmacological activity.

专利号:US-6469164-B2
优先权日:2000-06-08
标题:Process for the synthesis of (2R, 2-alpha-R)-4-benzyl-2-[1-(3,5-bis (trifluoromethyl)phenyl)ethoxy]-1,4-oxazine-3-one
发明人：BRANDS KAREL M JOS; PAYACK JOSEPH F; PYE PHILIP J
权利人:MERCK & CO INC
摘要:The present invention is concerned with novel processes for the preparation of (2R, 2-alpha-R)-4-benzyl-2-[1-[3,5-bis(trifluoromethyl)phenyl]ethoxy-1,4-oxazin-3-one. This compound is useful as an intermediate in the synthesis of compounds which possess pharmacological activity.

专利号:US-2008242866-A1
优先权日:2007-03-30
标 题 :Synthesis of anthranilamides
发明人：SCHMEES NORBERT; PETROV ORLIN
权利人:SCHMEES NORBERT; PETROV ORLIN
摘要:The present invention relates to a novel method of preparing anthranilamides of formula I: n n n n n n n n n n in which R 1 , R 2 , R 3 , A, E, Q, X, and W are defined in the claims, to a novel intermediate compound, and to the use of said novel intermediate compound for the preparation of said anthranilamides of formula I.

专利号:US-2004110228-A1
优先权日:2002-04-01
标 题:Combinatorial organic synthesis of unique biologically active compounds
发明人：MCALPINE SHELLI R; TAYLOR RACHEL E; BOLLA MEGAN L; SEGALL ANCA M
摘要:The invention provides a method for making a combinatorial library of cyclic compounds, such as Holliday junction-trapping compounds, comprising the steps of (a) obtaining a plurality of trimers according to the generic structure X 1- X 2- X 3 , wherein X 1 , X 2 and X 3 can be independently any naturally or nonnaturally occurring amino acids or peptidomimetics thereof; (b) optionally coupling a spacer S to the trimer at either end; (c) cyclizing two trimers or trimer-spacer conjugates in a head-to-tail orientation; thereby obtaining a combinatorial library of compounds, wherein the library does not include an unmodifed or naturally occurring Holliday Junction-trapping compounds. The invention additionally provides methods macrocyclic compounds that are synergimycin derivatives.

专利号:US-8455655-B2
优先权日:2010-05-07
标题:Preparation of dihydropyridines
发明人：VISHNU NEWADKAR RAVINDRANATH; PURUSHOTTAM JOSHI ANIL; KUMAR SINGH SANTOSH
权利人:VISHNU NEWADKAR RAVINDRANATH; PURUSHOTTAM JOSHI ANIL; KUMAR SINGH SANTOSH; LESVI LABORATORIOS SL
摘要:The invention relates to a method and compounds for the preparation of clevidipine butyrate, a very short acting hypertensive calcium antagonist, as well as the synthesis of these compounds useful for the preparation of clevidipine (also known as clevidipine butyrate). Moreover the invention also discloses polymorphic forms of clevidipine butyrate, useful for the preparation of pharmaceutical compositions, and processes to prepare them.

专利号:US-4980291-A
优先权日:1988-02-10
标 题 :Process for the enzymatic separation of the optical isomers of racemic α-alkyl-substituted primary alcohols
发明人：BIANCHI DANIELE; CESTI PIETRO; FRANCALANCI FRANCO; CABRI WALTER
权利人:DONEGANI GUIDO IST
摘要:Biotechnological resolution by means of enzymatic transesterification of the relevant racemic mixture of the optical isomers of α-alkyl-substituted primary alcohols having the formula (I): ##STR1## wherein: R represents a linear or branched (C 1 -C 20 )-alkyl or alkenyl group or an aryl group, also substituted or condensed with other groups, in particular a group of formula (II) or (III): ##STR2## wherein: R ii represents a (C 1 -C 8 )-alkyl group, a (C 1 -C 4 )-alkenyl group, an alkoxy, phenyl, phenoxy, benzoyl, or heterocyclic group; n R iii represents a hydrogen or halogen atom; n R iv represents a (C 1 -C 4 )-alkyl group, n and wherein n R i represents a (C 1 -C 4 )-alkyl group either equal to, or different from, R, n in the presence of an enzyme either free or immobilized on a support capable of selectively causing the S isomer to be esterified, with the R isomer being left substantially unchanged, said isomers being then separated according to techniques known from the prior art. The process is used in the synthesis of antiinflammatory agents.