CAS: 77117-48-7; (Perfluoro-N-Octyl)Ethane

该化合物是一种高度氟化的有机化合物,其化学和热稳定性非常高,完全氟化的碳链具有很强的疏水性和疏离性,使其在需要抵抗严酷环境的应用中有用.该化合物的地表能源低,有助于其作为阻燃涂层或添加剂的功效.其惰性能确保其与各种工业工艺的兼容性,而其全氟结构对氧化和降解具有抗力.该化合物在极端条件下的稳定性使其适合电子,航空航天和高性能材料的专门应用.其分子结构允许精确控制氟特性至关重要的配方.

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上下游产品

CAS号21652-58-4 全氟辛基乙烯

合成工艺路线路线简述

    1H,1H,2H-全氟-1-癸烯置于palladium On Activated Charcoal 氢气体系中,用 乙醚 作为反应溶剂,25.0 °C,100.0 Kpa 条件下,反应 6.0H,以97%的收率获得产物1H,1H,2H-全氟-1-癸烷
    参考文献:在超声辐射下通过全氟烷基烯烃的氢化方便地合成氟化烷烃和环烷烃
    标题:在超声辐射下通过全氟烷基烯烃的氢化方便地合成氟化烷烃和环烷烃
    摘要:在室温下,在大气压下,在室温下,通过氢化位阻和电子贫乏的全氟烷基烯烃,合成几种1,4-二取代的环己烷.如果不使用超声波,无论使用何种催化剂和压力(1至120 Bar),都难以实现加氢.超声辐射与金属催化的耦合极大地提高了全氟烷基烯烃的氢化效率.
    DOI:10.1016/j.Jfluchem.2005.07.006

    海关参考信息

    专利信息


    专利号:US-8299139-B1
    优先权日:2009-09-08
    标 题:Process and reactor for synthesis of ultra-high molecular weight acrylic polymers
    发明人:TARANEKAR PRASAD; SCHUMAN AUSTIN L; BANERJIE ASIS
    权利人:TARANEKAR PRASAD; SCHUMAN AUSTIN L; BANERJIE ASIS; OVATION POLYMER TECHNOLOGY AND ENGINEERED MATERIALS INC
    摘要:This invention relates to a process for producing high molecular weight (HMW) and ultra-high molecular weight (UHMW) acrylic polymers having unique polymer tacticity and exhibiting enhanced thermal and mechanical properties. This process comprises polymerizing ethylenically unsaturated monomer in the presence of a free radical initiator that results in a “living-like polymer†utilizing a multi-step approach. In conducting the process of this invention the “living-like polymer†is further dissolved in a liquid carrier, wherein the said liquid carrier is a reactive diluent that can be reacted subsequently by an addition polymerization process to create a block- or multi-block, copolymer or homopolymer. This process can be progressively repeated with the same or various different reactive diluents to generate desired architecture and molecular weight polymer(s) which can be used in further processing procedures to be manufactured directly into finished articles.

    专利号:WO-2010113188-A1
    优先权日:2009-03-31
    标题 :Fluorurated siliconic polymer, synthesis method and use
    发明人:CAPORICCIO GERARDO; MANIERO FRANCESCO; BEVILACQUA MARCO
    权利人:MAFLON S R L; CAPORICCIO GERARDO; MANIERO FRANCESCO; BEVILACQUA MARCO
    摘要:The present invention relates to a fluorurated siliconic polymer with controlled molecular weight and viscosity having a structure composed by means of the chaining of oligo-dialkylsiloxane building-blocks having a limited and selected molecular weight and alternated mainly with siloxane units containing a fluorurated substituent and - to a marginal degree - inert siloxane units or substituted by unsaturated groups. When the latter are present -they are used for subsequent reactions of clamping or cross-linking. The present invention relates, moreover, to a synthesis method of the mentioned polymer and its use.

    专利号:US-2023366125-A1
    优先权日:2003-03-31
    标 题:Compartmentalised combinatorial chemistry by microfluidic control
    发明人:GRIFFITHS ANDREW DAVID; WEITZ DAVID A; LINK DARREN ROY; AHN KEUNHO; BIBETTE JEROME
    权利人:HARVARD COLLEGE; RES & INNOVATION UK
    摘要:The invention describes a method for the synthesis of compounds comprising the steps of: (a) compartmentalising two or more sets of primary compounds into microcapsules; such that a proportion of the microcapsules contains two or more compounds; and (b) forming secondary compounds in the microcapsules by chemical reactions between primary compounds from different sets; wherein one or both of steps (a) and (b) is performed under microfluidic control; preferably electronic microfluidic control The invention further allows for the identification of compounds which bind to a target component of a biochemical system or modulate the activity of the target, and which is co-compartmentalised into the microcapsules.

    专利号:US-11807596-B2
    优先权日:2017-10-26
    标题:Thiol compounds, synthesis method therefor, and utilization of said thiol compounds
    发明人:OKUMURA NAOTO; OTSUKA AKIHITO; KUMANO TAKESHI; FUJIKAWA KAZUYUKI; ARAKI YUSUKE
    权利人:SHIKOKU CHEM
    摘要:The purpose of the present invention is to provide: novel thiol compounds; a method for synthesizing said thiol compounds; curing agents containing said thiol compounds; resin compositions containing said thiol compounds and an epoxy compound; and resin compositions containing said thiol compounds and an ene compound having a carbon-carbon double bond in a molecule. Furthermore, the purpose of the present invention is to provide adhesives and sealants having these resin compositions as ingredients. The thiol compounds of the present invention are represented by chemical formula (I) to chemical formula (VII).

    专利号:US-5650393-A
    优先权日:1992-08-06
    标 题 :Amphiphilic compounds derived from amino acids or peptides, their methods of synthesis and their application as drug delivery systems
    发明人:PAVIA ANDRE A; PUCCI BERNARD; RIESS JEAN G; ZARIF LEILA; GUEDJ CAMILLE
    权利人:ALLIANCE PHARMA
    摘要:Amphiphilic derivatives of amino acids or peptides are provided, comprising a polyhydroxylated hydrophilic part derived from a sugar, from a polyol, from an aminopolyol or from an oligosaccharide, and at least one hydrophobic part derived from a hydrocarbon, fluorocarbon, or a mixed fluorocarbon/hydrocarbon, saturated or unsaturated, having from 5 to 20 carbon atoms, the hydrophobic part(s) being linked to the hydrophilic part by a junction bearing an amino acid or a peptide.

    专利号:US-2010121022-A1
    优先权日:2006-10-17
    标 题 :1,3-dipolar cycloaddition of azides to alkynes
    发明人:MUSA OSAMA M; SRIDHAR LAXMISHA M; YUAN-HUFFMAN QINGWEN WENDY
    权利人:MUSA OSAMA M; SRIDHAR LAXMISHA M; YUAN-HUFFMAN QINGWEN WENDY
    摘要:A process for the bulk polymerization, in the absence of any solvent, of a reactant containing azide functionality and a reactant containing a terminal alkyne functionality, in the presence of Cu (I) catalyst or in the presence of a Cu(II) catalyst without a reducing agent, is described. Polymerization can be achieved at temperatures less than 100° C., which is suitable for low temperature cures. A controlled synthesis for low molecular weight oligomers is disclosed.
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    合成参考文献


    摘要:Szabó, K. J., Science of Synthesis: Cross Coupling and Heck-Type Reactions, (2012) 2, 504.
    摘要:S25 | OECDPFAS | List of PFAS from the OECD | DOI:10.5281/zenodo.2648775
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