CAS: 769-78-8; Vinyl Benzoate

该化合物其结构特征为:附着在苯甲酸酯的乙烯组(Eurosch=CH2),其颜色无色可粉黄液,有香味的香味;该化合物以活性闻名,特别是聚合物化学,可进行聚合,以形成聚乙烯苯酸酯,一种涂层,粘合剂和催化剂中应用的材料.乙烯苯甲酸酯在乙醇和乙醚等有机溶剂中可溶解,但水溶性有限.其化学特性包括能够参与各种反应,包括补充和替代反应,因为有乙烯组的存在.处理乙烯苯甲酸酯的安全考虑包括避免吸入和皮肤接触,因为它可能引起刺激.

结构式图片

欧盟法规

REACH注册ECHA物质C&L通报REACH预注册

上下游产品

CAS号65-85-0 苯甲酸 | CAS号74-86-2 乙炔 | CAS号98-88-4 苯甲酰氯 | CAS号108-05-4 乙酸乙烯酯 | CAS号7127-19-7 2-苯基-2-恶唑啉 | CAS号64-19-7 冰醋酸 | CAS号1119-20-6 bis(ethenyl)mercury | CAS号147092-04-4 2-(phenylselany... | CAS号85-44-9 苯酐 | CAS号75-07-0 乙醛 | CAS号93-89-0 苯甲酸乙酯 | CAS号55-21-0 苯甲酰胺 | CAS号94-50-8 苯甲酸辛酯 | CAS号94-48-4 (E)-3,7-二甲基-2,6... | CAS号32651-37-9 benzoic acid,bu... | CAS号19224-27-2 4-benzoyloxybut... | CAS号120-51-4 苯甲酸苄酯 | CAS号1445-91-6 (S)-(-)-1-苯基乙醇 | CAS号1517-69-7 (R)-(+)-1-苯基乙醇 | CAS号13358-49-1 1-phenylethyl b...

合成工艺路线路线简述

    苯甲酸乙二酯 反应生成 苯甲酸乙烯酯
    参考文献:Process For Making Vinyl Esters And Other Esters Of Unsaturated Alcohols
    标题:Process For Making Vinyl Esters And Other Esters Of Unsaturated Alcohols

    海关参考信息

    专利信息


    专利号:US-8669356-B2
    优先权日:2009-10-21
    标 题 :Linker and support for solid phase synthesis of nucleic acid
    发明人:HAYAKAWA YOSHIHIRO; TSUKAMOTO MASAKI; MORI KENJIRO; MINOMI KENJIRO; MAETA ERI; KONISHI TATSUYA
    权利人:HAYAKAWA YOSHIHIRO; TSUKAMOTO MASAKI; MORI KENJIRO; MINOMI KENJIRO; MAETA ERI; KONISHI TATSUYA; NITTO DENKO CORP; UNIV NAGOYA NAT UNIV CORP
    摘要:The invention provides a universal linker capable of synthesizing nucleic acid having a phosphate group at the 3′ terminal, a universal support carrying the linker, and a synthesis method of nucleic acid using the universal support. The linker for solid phase synthesis of nucleic acid contains a compound represented by at least one of the following formulae n nwherein each symbol is as defined in the specification.

    专利号:US-8222458-B2
    优先权日:2008-06-13
    标题 :Process or synthesis of (3S)- and (3R)-3-hydroxy-beta-ionone, and their transformation to zeaxanthin and beta-cryptoxanthin
    发明人:KHACHIK FREDERICK; CHANG AN-NI
    权利人:KHACHIK FREDERICK; CHANG AN-NI; UNIV MARYLAND
    摘要:Disclosed is a process for the synthesis of (3R)-3-hydroxy-β-ionone and its (3S)-enantiomer in high optical purity from commercially available (rac)-α-ionone. The key intermediate for the synthesis of these hydroxyionones is 3-keto-α-ionone ketal that was prepared from (rac)-α-ionone after protection of this ketone as a 1,3-dioxolane. Reduction of 3-keto-α-ionone ketal followed by deprotection, lead to 3-hydroxy-α-ionone that was transformed into (rac)-3-hydrox-β-ionone by base-catalyzed double bond isomerization in 46% overall yield from (rac)-α-ionone. The racemic mixture of these hydroxyionones was then resolved by enzyme-mediated acylation in 96% ee. (3R)-3-Hydroxy-β-ionone and its (3S)-enantiomer were respectively transformed to (3R)-3-hydroxy-(β-ionylideneethyl)triphenylphosphonium chloride [(3R)-C 15 -Wittig salt] and its (3S)-enantiomer [(3S)-C 15 -Wittig salt] according to known procedures. Double Wittig condensation of these Wittig salts with commercial available 2,5- dimethtylocta-2,4,6-triene-1,8-dial provided all 3 stereoisomers of zeaxanthin. Similarly, (3R)-C 15 -Wittig and its (3S)-enantiomer were each coupled with β-apo-12′-carotenal.

    专利号:WO-2023102600-A1
    优先权日:2021-12-06
    标题:Synthesis of amphiphilic block copolymers and polymeric nanofibers produced therefrom
    发明人:ZETTERLUND PER B; ISHIZUKA FUMI; KIM HYUN JIN; CHATANI SHUNSUKE; NIINO HIROSHI
    权利人:NEWSOUTH INNOVATIONS PTY LTD
    摘要:The present disclosure relates to the field of synthesis of block copolymers, and polymeric nanofibers having a core-shell morphology produced therefrom. The present disclosure relates to the field of synthesis of block copolymers where one block is more hydrophobic than the other block and is a different composition. The disclosure also relates to uses of these polymeric nanofibers in various applications, such as reinforcing a polymeric matrix and for coatings applications.

    专利号:US-6512081-B1
    优先权日:1997-07-21
    标题:Synthesis of dithioester chain transfer agents and use of bis(thioacyl) disulfides or dithioesters as chain transfer agents
    发明人:RIZZARDO ENZIO; THANG SAN HOA; MOAD GRAEME
    权利人:E I DUPONT NEMOURS AND COMPANY; COMMW SCIENT IND RES ORG
    摘要:This invention relates to the synthesis of dithiocarboxylic acid esters by reaction of bis(thioacyl) disulphides, thioacetals or vinylidane bis(thioether) with free-radicals (optionally in the presence of monomers). The invention also relates to processes for the synthesis of polymers utilising these dithioesters as polymerisation regulators (chain transfer agents) or to the use of bis(thioacyl) disulphides to generate dithioester chain transfer agents in situ.

    专利号:US-7268144-B2
    优先权日:2004-04-14
    标 题 :Regiospecific synthesis of rapamycin 42-ester derivatives
    发明人:GU JIANXIN; CAI PING; RUPPEN MARK E
    权利人:WYETH CORP
    摘要:A method for the regiospecific synthesis of rapamycin 42-ester derivatives is described. The method involves lipase-catalyzed acetylation of 42-hydroxy of rapamycin with an acyl donor such as a vinyl ester, an isopropenyl ester or an anhydride in a suitable organic solvent.

    专利号:EP-2128179-B1
    优先权日:2008-05-26
    标 题:Solid-phase support for nucleic acid synthesis
    发明人:MORI KENJIRO; MAETA ERI
    权利人:NITTO DENKO CORP
    摘要:According to the invention, there is provided a solid-phase support for nucleic acid synthesis, which is constituted of a porous copolymer particle containing a multifunctional vinyl monomer unit having two or more vinyl groups in one molecule and a monofunctional vinyl monomer unit having one vinyl group in one molecule, in which the solid-phase support has a swelling volume when soaked in acetonitrile of 3.5 ml/g or more and has a median particle diameter measured by a laser scattering particle size distribution measuring method within a range of from 50 to 120 µm. According to the solid-phase support for nucleic acid synthesis of the invention, a high-purity nucleic acid can be synthesized with a high yield.
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    合成参考文献


    摘要:Roy, M.-N.; Lindsay, V. N. G.; Charette, A. B., Science of Synthesis: Stereoselective Synthesis, (2011) 1, 760.
    摘要:Roy, M.-N.; Lindsay, V. N. G.; Charette, A. B., Science of Synthesis: Stereoselective Synthesis, (2011) 1, 771.
    摘要:Garve, L. K. B.; Werz, D. B., Science of Synthesis: Metal-Catalyzed Cyclization Reactions, (2016) 2, 62.
    摘要:Garve, L. K. B.; Werz, D. B., Science of Synthesis: Metal-Catalyzed Cyclization Reactions, (2016) 2, 61.
    摘要:Chen, P.; Liu, G., Science of Synthesis: Modern Strategies in Organofluorine Chemistry , (2024) 1, 19.
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