CAS: 5683-31-8; 3-(Trimethylsilyl)Propiolic Acid

相似化合物

16205-84-8 2975-46-4 42201-71-8

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CAS号5272-36-6 三甲硅基丙炔醇 | CAS号124-38-9 二氧化碳 | CAS号1066-54-2 三甲基硅基乙炔 | CAS号75-77-4 三甲基氯硅烷 | CAS号42201-71-8 三甲基硅烷丙炔甲酯 | CAS号5683-30-7 3-三甲基硅基丙酸 | CAS号88946-47-8 3-trimethylsily... | CAS号58207-98-0 trans-3-(Trimet... | CAS号591-47-9 4-甲基-1-环己烯 | CAS号88946-60-5 Cyclohexanecarb... | CAS号88946-65-0 Cyclohexanecarb... | CAS号99-94-5 对甲基苯甲酸 | CAS号99-04-7 间甲基苯甲酸 | CAS号16205-84-8 3-(三甲基甲硅烷基)丙酸乙酯

📜3-(Trimethylsilyl)Propynyl Alcohol置于iron(Iii) Nitrate Nonahydrate,2,2,6,6-四甲基哌啶氧化物,Potassium Chloride,氧气体系中,用 1,2-二氯乙烷 作为反应溶剂,化学反应 36.0H,以66%的收率获得产物3-(三甲基硅基)丙炔酸
参考文献:一种氧气氧化醇或醛制备酸的方法
标题:一种氧气氧化醇或醛制备酸的方法
摘要:本发明提供一种以氧气或空气中的氧气为氧化剂氧化醇或醛制备酸的方法,系在室温下,在有机溶剂中,以硝酸铁(Fe(No3)3.9H2O),2,2,6,6‑四甲基哌啶氮氧化物(Tempo)和无机卤化物为催化剂,以氧气或空气作为氧化剂,由醇或醛氧化反应生成酸,二醇氧化反应生成内酯;或,以醛为原料,以硝酸铁作为催化剂,在中性条件下反应,所述醛氧化反应生成酸和过氧酸.本发明具有绿色环保,成本低,产率高,原子经济性高,底物官能团兼容性好,反应条件温和,反应规模可放大等优点,适合应用于工业生产.

专利信息

专利号:US-9217012-B2
优先权日:2009-04-08
标题 :Inhibitors of protein tyrosine phosphatases
发明人：ZHANG ZHONG-YIN; ZHANG SHENG
权利人:ZHANG ZHONG-YIN; ZHANG SHENG; UNIV INDIANA RES & TECH CORP
摘要:Disclosed herein are compounds that selectively inhibit members of the PTP family of enzymes. Synthesized compounds demonstrated selective inhibition of TC-PTP. Also provided are methods of using the compounds and formulations containing the compounds. Also described is a fluorescence-tagged combinatorial library synthesis and screening method. And methods of using these compounds to effect enzyme activity both in cells and in vitro as well as method of using these compounds to treat diseases in human and animals.