CAS: 2633-67-2; 4-Vinylbenzenesulfonyl Chloride

上下游产品

sodium 4-styrenesulfonate N-phenylphenylene-1,4-diamine thionyl chloride styrene-4-sulfonic acidN-methyl-p-styrenesulfonamide (1R,2R,3S,4S)-3-(4-vinylbenzenesulfonyl)amino-1,7,7-trimethylbicyclo[2.2.1]heptan-2-ol (1R,2S,3R,4S)-3-(4-vinylbenzenesulfonyl)amino-1,7,7-trimethylbicyclo[2.2.1]heptan-2-ol 4-vinylbenzenesulfonamide

📜Styrene-4-Sulfonic Acid置于氯化亚砜,N,N-二甲基甲酰胺体系中,用 甲苯 用作溶剂,化学反应 15.0H,反应生成对-苯乙烯磺酰氯
参考文献:可回收的硅胶负载的binam-脯氨酰胺作为有机催化剂,用于无对映选择性的溶剂内和分子间羟醛反应
标题:可回收的硅胶负载的binam-脯氨酰胺作为有机催化剂,用于无对映选择性的溶剂内和分子间羟醛反应
摘要:硅胶负载的比纳姆衍生的脯氨酰胺是使用常规磁力搅拌在无溶剂条件下直接进行分子内和分子间羟醛直接反应的有效有机催化剂.这些与苯甲酸组合的有机催化剂显示出与使用相关结构的有机催化剂在相似的均相反应条件下获得的结果相似的结果.对于分子间方法,羟醛产物是在室温下且仅使用2当量的酮获得的,具有高产率,区域,非对映和对映选择性.在这些反应条件下,醛之间的交叉羟醛反应也是可能的.回收的催化剂最多可重复使用九次,从而获得相似的结果.更有趣的是,
Doi:10.1016/j.Tet.2012.11.097

专利信息

专利号:US-2023399294-A1
优先权日:2022-06-08
标 题 :Method for synthesis of monomer for single-ion battery
发明人：ZHAO QIUJIE; LIANG SIWEI; YANG JIN; DEGRAS Sarah; LEBLANC PATRICK
权利人:BLUE SOLUTIONS CANADA INC; CAPACITOR SCIENCES INC
摘要:The present technology relates to methods for the synthesis of a lithium single-ion monomer which comprises simultaneously reacting a sulfonyl chloride compound with i) a fluorinated sulfonamide compound and ii) a compound that is suitable to act as a quenching base and a lithium cation source. The simultaneous reaction of sulfonyl chloride with the fluorinated sulfonamide compound and the compound that is suitable to act as a quenching base and a lithium cation source yields the single-ion monomer.

专利号:US-6162882-A
优先权日:1996-07-10
标 题:Preparation of novel homo- and copolymers using atom transfer radical polymerization
发明人：MATYJASZEWSKI KRZYSZTOF; COCA SIMION; GAYNOR SCOTT G; NAKAGAWA YOSHIKI; JO SEONG MU
权利人:UNIV CARNEGIE MELLON
摘要:The present invention is directed to a process of atom (or group) transfer radical polymerization for the synthesis of novel homopolymer or a block or graft copolymer, optionally containing at least one polar group, with well defined molecular architecture and narrow polydipersity index, in the presence of an initiating system comprising (i) an initiator having a radically transferrable atom or group, (ii) a transition metal compound, and (iii) a ligand, the present invention is also directed to the synthesis of a macromolecule having at least two halogen groups which can be used as a macroinitiator component (i) to subsequently form a block or graft copolymer by an atom or group transfer radical polymerization process; the present invention is also directed to a process of atom or group transfer radical polymerization for the synthesis of a branched or hyperbranched polymer; in addition, the present invention is directed to a process of atom or group transfer radical polymerization for the synthesis of a macroinitiator which can subsequently be used to produce a block or graft copolymer.

专利号:US-2013165350-A1
优先权日:2011-12-22
标 题:Surface linkers for array synthesis
发明人：KUIMELIS ROBERT; MCGALL GLENN; PAO DEXTER; CHEN ZIHUI; AXELROD TREVOR
权利人:KUIMELIS ROBERT; MCGALL GLENN; PAO DEXTER; CHEN ZIHUI; AXELROD TREVOR; AFFYMETRIX INC
摘要:The present invention provide several methods of derivatizing a surface of a support with one or more linkers thus providing a suitable platform for synthesis of a polymer array, particular a nucleic acid array. Some methods derivatize a surface with a self-assembled monolayer (SAM) of a linker. The SAM confers advantages of hydrolytic stability, broad compatibility with synthesis and detection chemistries, and reduced emergence of latent functional groups during polymer array synthesis. Substrates can also be derivatized with multi-layers of SAMs providing greater hydrolytic stability. Substrates can also be derivatized by synthesizing a linker in situ on the substrate by atom transfer radical polymerization of functional and functional monomers. Appropriate selection of monomers reduces emergence of latent functional groups in subsequent array synthesis.

专利号:US-4752638-A
优先权日:1983-11-10
标 题:Synthesis and use of polymers containing integral binding-pair members
发明人：NOWINSKI ROBERT C; HOFFMAN ALLAN S; HOUGHTON RAYMOND L; PRIEST JOHN H; MONJI NOBUO
权利人:GENETIC SYSTEMS CORP
摘要:Conjugate monomers, polymers, and methods for the de novo synthesis of the polymers are provided. Conjugate organic monomers contain binding-pair members which upon polymerization become integrally associated with the resultant polymer. Specifically, antigens, antibodies, receptors, and ligands may be bound to organic monomers either directly by chemical reaction or indirectly by chemical spacer arms, and these conjugates may be polymerized or copolymerized with nonderivatized monomers to form polymers containing variable amounts of the binding-pair members. Such conjugate monomers and polymers find a wide variety of uses in binding to their binding-pair-member cognate which include selective removal of complementary binding-pair members from solution as well as in immunoassay procedures and in immunization regimes.

专利号:US-9771319-B2
优先权日:2014-12-10
标 题 :Cross-linker for the preparation of a new family of single ion conduction polymers for electrochemical devices and such polymers
发明人：GONZALEZ MARTINEZ JOSE ANTONIO; TRINCADO RODRIGUEZ-PICK MONICA; GRUTZMACHER HANSJORG FRIEDRICH
权利人:BELENOS CLEAN POWER HOLDING AG
摘要:A specific cross-linker, an alkaline metal bis(styrenesulfonyl)imide monomer, is used in the synthesis of single ionic conductive copolymers that are non-fluorinated and non-PEO based. Such copolymers meet the security and costs requirements to be used as solid polymers electrolytes (SPE). They are promising alternatives to standard liquid electrolytes in alkaline metal-ion batteries because of their improved security and inflammability properties. The copolymers described are either polyvinylsulfonates or acrylate vinylsulfonate block-copolymers. Preferred acrylate monomers are methacrylates and preferred vinylsulfonates are styrene sulfonates. The copolymer is prepared by radical polymerization of the vinyl sulfonate and the cross-linker and optionally the acrylate, in particular radical photopolymerization using a functionalized bis(acyl)phosphane oxide (BAPO) as photoinitiator. Also described is the use of such copolymer as solid polymer electrolyte in a lithium ion battery.

专利号:CN-104803969-B
优先权日:2015-03-05
标题 :A kind of acrylic type containing thiosulfonate group high refractive index monomer and its synthesis method