CAS: 12014-93-6; Cerium(3+),Trisulfide

该化合物是一种由两个原子(Ce) 原子和三个硫原子(S) 组成的无机化合物, 通常看上去是一个固态, 结晶结构显示暗色, 往往是黑色或深色的褐色. 这种化合物因其半导体特性而值得注意, 并具有各种用途, 包括材料科学和催化. 三硫化物在环境条件下相对稳定, 但可能与强酸或基底发生反应. 其合成通常涉及氧化和硫之间的高温反应. 化合物的特性, 如电导性和热稳定性, 使它成为固态化学和浓缩物质物理领域研究的主体. 此外, 由于有, 它可能具有有趣的磁特性, 可以在磁材料中进行潜在应用. 在处理该化合物时, 需要采取安全防范措施, 与许多有机硫化物一样, 具有潜在的毒性和再活动.

结构式图片

合成工艺路线路线简述

    专利信息


    专利号:US-2002184969-A1
    优先权日:2001-03-29
    标 题 :Combinatorial synthesis of particulate materials
    发明人:KODAS TOIVO T; HAMPDEN-SMITH MARK J
    摘要:Methods for fabricating and analyzing particulates having a varying material property such that particulates having a selected desirable material property can be identified. The particulates can be analyzed to determine the particulates having the best properties for a particular application. The particulates can be metals, inorganic compounds, organic compounds and composites. The method of the present invention enables the rapid and economical fabrication and screening of a large number of different compositions.

    专利号:US-5279801-A
    优先权日:1990-01-30
    标 题:Production of binary rare earth/sulfur or transition metal/sulfur compounds
    发明人:COLOMBET PIERRE; MOLINIE PHILIPPE; SPIESSER MICHEL
    权利人:RHONE POULENC CHIMIE
    摘要:Process for the synthesis of binary sulphur compounds, such as rare-earth and transition metal sulphur compounds. This process consists in reacting a rare-earth compound, for example oxide or carbonate, or a transition metal oxide with a sulphur carbon compound such as CS2, in a closed vessel at a pressure of between 1 x 10<5> Pa and 150 x 10<5> Pa. The products obtained are either rare-earth higher sulphides or rare-earth sesquisulphides.

    专利号:US-2002176927-A1
    优先权日:2001-03-29
    标 题:Combinatorial synthesis of material systems
    发明人:KODAS TOIVO T; HAMPDEN-SMITH MARK J
    摘要:Methods for formulating material systems of varying chemistry and stoichiometry. The material systems include two or more components and can be analyzed to select the system having the best properties for a particular application. Specific examples of materials systems that can be fabricated and analyzed according to the present invention include layers for membrane electrode assemblies (MEA's) that are useful in the construction of fuel cells and similar devices.

    专利号:US-2008169449-A1
    优先权日:2006-09-08
    标 题 :Catalytic membrane reactor and method for production of synthesis gas
    发明人:MUNDSCHAU MICHAEL V
    权利人:ELTRON RESEARCH INC
    摘要:A solid state membrane for a reforming reactor is disclosed which comprises at least one oxygen anion-conducting oxide selected from the group consisting of hexaaluminates, cerates, perovskites, and other mixed metal oxides that are able to adsorb and dissociate molecular oxygen. The membrane adsorbs and dissociates molecular oxygen into highly active atomic oxygen and allows oxygen anions to diffuse through the membrane, to provide high local concentration of oxygen to deter formation and deposition of carbon on reformer walls. Embodiments of the membrane also have catalytic activity for reforming a hydrocarbon fuel to synthesis gas. Also disclosed are a reformer having an inner wall containing the new membrane, and a process of reforming a hydrocarbon feed, such as a high sulfur-containing diesel fuel, to produce synthesis gas, suitable for use in fuel cells.

    专利号:US-4540714-A
    优先权日:1979-12-18
    标 题 :Process and catalyst for the preparation of a gas mixture having a high content of methane
    发明人:PEDERSEN KARSTEN; ROSTRUP-NIELSEN JENS R; JORGENSEN IB GREVE H; ANDERSEN KJELD J
    权利人:HALDOR TOPSOE AS
    摘要:A gas rich in methane is prepared by the methanantion of a synthesis gas containing carbon oxides, hydrogen and optionally other gases in the presence of one or more gaseous sulphur compounds, normally in an amount of at least 10 ppm preferably at least 200 ppm by volume, calculated as H2S, with the aid of a catalyst comprising vanadium and/or molybdenum, which during the process is present as one or more sulphides, on a support comprising titanium dioxide. A high activity and a high selectivity for methane are obtained. A further advantage is that, by far, the main constituent of the higher hydrocarbons formed is ethane, which, by conversion into ethylene, is an important raw material in petrochemical synthesis. The selectivity for methane formation may be further improved by promoting the catalyst with compounds, especially sulphides of metals of groups IA, IIA and/or IIIB, particularly cerium. The invention also relates to the catalyst itself which may be prepared by impregnation or coprecipitation techniques.

    专利号:US-12294050-B2
    优先权日:2014-12-02
    标 题 :Lithium ion conducting sulfide glass fabrication
    发明人:VISCO STEVEN J; PETROV ALEXEI; LOGINOVA VALENTINA; NIMON VITALIY; NIMON YEVGENIY S; KATZ BRUCE D
    权利人:POLYPLUS BATTERY CO INC
    摘要:Preparation of anhydrous lithium sulfide (Li2S) purified suitably for applications in advanced batteries, and, in particular, for synthesis of solid electrolytes based on Li2S, including sulfide solid electrolytes of the type that may be described as crystalline (e.g., polycrystalline), amorphous (e.g., glass) and combinations thereof, such as sulfide glass-ceramic solid electrolyte materials.

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