CAS: 94994-62-4; 2-Bromo-9-Phenyl-9H-Carbazole

• 英文名称2-Bromo-9-Phenyl-9H-Carbazole
• 中文名称2-溴-9-苯基-9H-咔唑
• IUPAC名称2-bromo-9-phenyl-9H-carbazole
• 其它别名2-溴-9-苯基咔唑; 2-Bromine-9-Phenyl-9H-Carbazole
• CAS编号94994-62-4
• MFCD编号:MFCD24387061
• EINECS号:807-971-7
• 分子式:C18H12BrN
• 分子量:322.2
• 产品CID: 2002346
• 产品分类有机原料→分子砌块→芳杂环类化合物→咔唑类化合物

• 相似结构搜索
• InChIKey: SOODLDGRGXOSTA-UHFFFAOYSA-N
• InChI=1S/C18H12BrN/c19-13-10-11-16-15-8-4-5-9-17(15)20(18(16)12-13)14-6-2-1-3-7-14/h1-12H…
• 计算化学: 氢键受体数1.0氢键供体数0.0可旋转键数1.0

相似化合物

物理性质

• 熔点88.0-92.0 °C
• 沸点461.7±27.0 °C at 760 mmHg
• 闪点233.0±23.7 °C
• 密度1.4±0.1 g/cm3
• PSA:4.93
• LogP:5.5462
• 折射率1.673
• 蒸汽压0.0±1.1 mmHg at 25°C
• 外观形态白色至几乎白色粉末至晶体
• 储存条件密封, 常温干燥保存
• 产品应用该化合物用于准备无铅化铅化铀银幕和电子装置的反应器.

MSDS等安全信息

• GHS象形图
• GHS符号GHS07;
  注释: Exclamation mark
• 危险类别皮肤腐蚀/刺激 类别2
  严重眼刺激 类别2
• 警示词Warning(警告)
• 危险描述H315 |造成皮肤刺激.
  H319 |造成严重眼刺激.
• 防范说明P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501
• 危险品标志Xi

欧盟法规

上下游产品

合成工艺路线路线简述

• 合成目标产物 2-Bromo-9-Phenyl-9H-Carbazole 主要起始原料 2-Bromocarbazole And Phenylhydrazine
• 3652-90-2 = 94994-62-4
  反应条件:1.1 Reagents: N,N,N′,N′-Tetramethylethylenediamine Catalysts: Cobalt Phthalocyanine Solvents: Acetonitrile; 12 H,60 °C
  标题:Method For Synthesizing N-Aryl Carbazole Compound By Reaction Of Carbazole With Aryl Hydrazine And Transition Metal As Catalyst
  参考文献:China]
  
  591-50-4 + 3652-90-2 = 94994-62-4
  反应条件:1.1 Reagents: Ethylenediamine,Tripotassium Phosphate Catalysts: Cuprous Iodide Solvents: Toluene; 12 H,Reflux
  标题:Novel Organic Electroluminescent Compounds And Organic Electroluminescent Devices Comprising Compounds Thereof
  参考文献:Korea]
  
  591-50-4 + 3652-90-2 = 94994-62-4
  反应条件:1.1 Reagents: Ethylenediamine,Cesium Carbonate Catalysts: Cuprous Iodide Solvents: Toluene; 4 H,Reflux
  标题:A Novel Combination Of A Host Compound And A Dopant Compound And An Organic Electroluminescence Device Comprising The Same
  参考文献:Korea]
  
  3652-90-2 = 94994-62-4
  反应条件:1.1 Reagents: Sodium Tert-Butoxide Catalysts: 1,1-Bis(Diphenylphosphino)Ferrocene,Tris(Dibenzylideneacetone)Dipalladium Solvents: Toluene; 24 H,Reflux
  标题:Organic Light Emitting Compound Having Multifused Ring For Organic Electroluminescent Device
  参考文献:Korea]
  
  591-50-4 + 3652-90-2 = 94994-62-4
  反应条件:1.1 Reagents: Potassium Carbonate Catalysts: L-Proline,Cuprous Iodide Solvents: Dimethyl Sulfoxide; 3 D,90 °C
  标题:Carbazole Containing Iridium Complexes Demonstrating Broadband Emission Through Controlled Geometric Distortion And Applications Thereof
  参考文献:United States]
  
  591-50-4 + 3652-90-2 = 94994-62-4
  反应条件:1.1 Reagents: Ethylenediamine,Tripotassium Phosphate Catalysts: Cuprous Iodide Solvents: Toluene; 50 °C; 14 H,50 °C
  标题:Aromatic Hole Injecting Or Transporting Material For Organic Electroluminescent Device
  参考文献:Korea]
  
  591-50-4 + 3652-90-2 = 94994-62-4
  反应条件:1.1 Reagents: Potassium Carbonate,Sodium Sulfate Catalysts: Copper Solvents: Nitrobenzene; 200 °C
  标题:Preparation Of Carbazole-Containing Arylamine Compounds For Organic Electroluminescent Devices
  参考文献:Korea]
  
  591-50-4 + 3652-90-2 = 94994-62-4
  反应条件:1.1 Reagents: Ethylenediamine,Tripotassium Phosphate Catalysts: Cuprous Iodide Solvents: Toluene; 12 H,Reflux
  标题:Aromatic Electroluminescent Compounds For Organic Electroluminescent Device
  参考文献:Korea]
  
  591-50-4 + 3652-90-2 = 94994-62-4
  反应条件:1.1 Reagents: Potassium Hydroxide Catalysts: 1,10-Phenanthroline,Cuprous Iodide Solvents: M-Xylene; 48 H,140 °C
  标题:Preparation Of Thiophene Derivatives For Perovskite Solar Cells
  参考文献:China]
  
  591-50-4 + 3652-90-2 = 94994-62-4
  反应条件:1.1 Reagents: Ethylenediamine,Cesium Carbonate Catalysts: Cuprous Iodide Solvents: Toluene; 3 H,Reflux
  标题:Aromatic Compound As Hole Transport Layer Materials For Organic Electroluminescent Device
  参考文献:Korea]
  
  591-50-4 + 3652-90-2 = 94994-62-4
  反应条件:1.1 Reagents: 1,10-Phenanthroline,Potassium Hydroxide,Cuprous Iodide Solvents: P-Xylene; 2 D,140 °C
  标题:Carbazole-Based Coplanar Molecule (Cminf) As A Universal Host For Multi-Color Electrophosphorescent Devices
  作者:Ho,Cheuk-Lam; Chi,Liang-Chen; Hung,Wen-Yi; Chen,Wei-Jiun; Lin,Yu-Cheng; Et Al
  参考文献:Journal Of Materials Chemistry 日期:2012 卷标:22(1) 页码:215-224]
  
  591-50-4 + 3652-90-2 = 94994-62-4
  反应条件:1.1 Reagents: Potassium Carbonate Catalysts: Copper,Cuprous Iodide Solvents: O-Xylene; 24 H,Reflux
  标题:Pyridine Derivative Compound As Electroluminescent Material For Organic Electroluminescent Device
  参考文献:Korea]
  
  591-50-4 + 3652-90-2 = 94994-62-4
  反应条件:1.1 Reagents: Ethylenediamine,Cesium Carbonate Catalysts: Cuprous Iodide Solvents: Toluene; 14 H,50 °C
  标题:Novel Compounds For Organic Electronic Materials For Organic Electroluminescent Devices
  参考文献:Korea]
  
  591-50-4 + 3652-90-2 = 94994-62-4
  反应条件:1.1 Reagents: Ethylenediamine,Cesium Carbonate Catalysts: Cuprous Iodide Solvents: Toluene; 50 °C; 14 H,Reflux
  标题:Triphenylene Conjugated Heterocyclic Compounds Organic Electroluminescent Compounds For Organic Electroluminescent Devices
  参考文献:World Intellectual Property Organization]
  
  591-50-4 + 3652-90-2 = 94994-62-4
  反应条件:1.1 Reagents: Sodium Tert-Butoxide Catalysts: Triphenylphosphine,Tris(Dibenzylideneacetone)Dipalladium Solvents: Toluene; 100 °C
  标题:Carbazole Compounds For Organic Electric Element Materials And Electronic Device Thereby
  参考文献:Korea]
  
  591-50-4 + 3652-90-2 = 94994-62-4
  反应条件:1.1 Reagents: Potassium Carbonate Catalysts: 1,10-Phenanthroline,Cuprous Iodide Solvents: Dimethylformamide; 24 H,80 °C
  标题:Compound For Organic Electroluminescent Device And Organic Electroluminescent Device Comprising The Same
  参考文献:World Intellectual Property Organization

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• ➥ 象形图和危险代码
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