CAS: 822-67-3; Cyclohex-2-Enol

该化合物是有机化合物,其特点是环己环状结构,附于第一个碳,在室温下,这种化合物无色可粉黄,在室内温度下是黄色液体,具有独特,舒适的气味,由于存在氢氧功能组,它被归类为酒精,有助于极地溶剂中的再活性和溶解性.2-Cyclohexen-1-ol因其在有机合成中的作用而闻名,可以参与各种化学反应,包括氧化和脱水,其沸点和密度在小型循环酒精中很常见,在标准条件下一般稳定,但应谨慎处理,因为它可能会对皮肤和眼睛产生刺激.此外,必须指出,2-Cyclohexen-1-ol在某些条件下可以发生聚合和其他变异,使其在工业和实验室环境中成为兴趣的复合物.

结构式图片

相似化合物

822-66-2 3413-44-3 2699-13-0

物理性质

MSDS等安全信息

欧盟法规

ECHA物质C&L通报REACH预注册

上下游产品

methyl magnesium iodide diethyl ether cyclohex-2-enyl hydroperoxide cyclohexenone 1,2,3-trihydroxycyclohexane 2-ethoxycyclohex-1-ene cyclohexenone bis(cyclohex-2-en-1-yl) ether

合成工艺路线路线简述

  • 合成目标产物 2-Cyclohexen-1-Ol 主要起始原料 Cyclohexene
  • 670227-73-3 = 822-67-3
    反应条件:1.1 Catalysts: Grubbs' Catalyst Solvents: Dichloromethane; < 10 Min,Reflux
    标题:Asymmetric Synthesis Of Cyclic β-Hydroxyallylsilanes Via Sequential Allyltitanation-Ring Closing Metathesis
    作者:Adam,Jean-Michel; Et Al
    参考文献:Tetrahedron 日期:2004 卷标:60(34) 页码:7325-7344]

    930-68-7 = 822-67-3
    反应条件:1.1 Reagents: Sodium Triacetoxyborohydride,(4R,5R)-2-(3-Nitrophenyl)-1,3,2-Dioxaborolane-4,5-Dicarboxylic Acid; 12 H,0 °C1.2 Solvents: Water1.3 Reagents: Sodium Hydroxide Solvents: Water; Basified
    标题:Highly Enantioselective And Regioselective Carbonyl Reduction Of Cyclic α,β-Unsaturated Ketones Using Tarb-No2 And Sodium Borohydride
    作者:Kim,Jinsoo; Et Al
    参考文献:Organic Letters 日期:2009 卷标:11(19) 页码:4358-4361]

    = 822-67-3
    反应条件:1.1 Reagents: Tert-Butyl Hydroperoxide Catalysts: Iron(1+),[5,10,15,20-Tetrakis(Pentafluorophenyl)-21H,23H-Porphinato(2-)-Kn21,Kn... Solvents: Acetonitrile,Water; 10 Min,24 - 26 °C
    标题:The Mechanistic Aspects Of Iron(Iii) Porphyrin Catalyzed Oxidation Reactions In Mixed Solvents
    作者:Singh,Amit; Et Al
    参考文献:Inorganica Chimica Acta 日期:2011 卷标:372(1) 页码:295-303]

    1192-78-5 = 822-67-3
    反应条件:1.1 5 Min,50 °C
    标题:An Efficient Protocol For The Eliminative Deoxygenation Of Aliphatic And Aromatic Epoxides To Olefins With Polyphosphoric Acid As A Promoter
    作者:Pathe,Gulab Khushalrao; Et Al
    参考文献:Tetrahedron Letters 日期:2015 卷标:56(45) 页码:6202-6206]

    = 822-67-3
    反应条件:1.1 Reagents: Tert-Butanol,Butyllithium,Diethylamine Solvents: Tetrahydrofuran
    标题:Studies In The Rearrangement Of Epoxides With Lithium Dialkylamide-Lithium Tert-Butoxide
    作者:Saravanan,Parthasarathy; Et Al
    参考文献:Tetrahedron 日期:1997 卷标:53(5) 页码:1855-1860]

    6510-92-5 = 822-67-3
    反应条件:1.1 Reagents: Potassium Carbonate
    标题:Fluoro Alcohol As Reaction Medium: One-Pot Synthesis Of β-Hydroxy Sulfoxides From Epoxides
    作者:Kesavan,Venkitasamy; Et Al
    参考文献:Tetrahedron Letters 日期:2000 卷标:41(16) 页码:2895-2898]

    190134-35-1 = 822-67-3
    反应条件:1.1 Reagents: Sodium Carbonate,Chlorosulfonyl Isocyanate Solvents: Dichloromethane; Rt; 20 H,-78 °C1.2 Reagents: Sodium Hydroxide Solvents: Methanol; 1 H,Rt1.3 Reagents: Hydrochloric Acid Solvents: Water; Neutralized
    标题:Deprotection Of Benzyl And P-Methoxybenzyl Ethers By Chlorosulfonyl Isocyanate-Sodium Hydroxide
    作者:Kim,Ji Duck; Et Al
    参考文献:Tetrahedron Letters 日期:2003 卷标:44(4) 页码:733-735]

    57713-26-5 = 822-67-3
    反应条件:1.1 Catalysts: Tributyl Phosphate,Dibutyltin Oxide Solvents: Methanol
    标题:Deprotection Of Tetrahydropyranyl And Silyl Ethers Catalyzed By Organotin Phosphate Condensates
    作者:Otera,Junzo; Et Al
    参考文献:Synthesis 日期:1988 卷标:(4) 页码:328-9]

    57713-26-5 = 822-67-3
    反应条件:1.1 Catalysts: Tin Dichloride Dihydrate Solvents: Methanol; 3 - 4 Min
    标题:Efficient And Ecofriendly Protocol For Tetrahydropyranylation/depyranylation Of Alcohols In The Presence Of Tin(Ii) Chloride Dihydrate
    作者:Gogoi,Dipankoj; Et Al
    参考文献:Synthetic Communications 日期:2007 卷标:37(4) 页码:593-597]

    846539-20-6 = 822-67-3
    反应条件:1.1 Reagents: 2,3-Dichloro-5,6-Dicyano-1,4-Benzoquinone Solvents: Dichloromethane,Water; 15 - 60 Min,Rt
    标题:The Trimethylsilyl Xylyl (Tix) Ether: A Useful Protecting Group For Alcohols
    作者:Reddy,Ch. Raji; Et Al
    参考文献:Tetrahedron 日期:2005 卷标:61(5) 页码:1289-1295]

    930-68-7 = 822-67-3
    反应条件:1.1 Reagents: Silica (Chlorinated Silica),Lithium Aluminum Hydride Solvents: Diethyl Ether; 15 Min,Rt
    标题:Lialh4/silica Chloride As A New Chemoselective System For Reduction Of Carbonyl Compounds And Phosphine Oxides
    作者:Khalilzadeh,M. A.; Et Al
    参考文献:Journal Of The Iranian Chemical Society 日期:2008 卷标:5(4) 页码:699-705]

    930-68-7 = 822-67-3
    反应条件:1.1 Reagents: (T-4)-Trihydro(Tricyclohexylphosphine)Indium Solvents: Toluene
    标题:Selective Reductions With Stable Indium Trihydride Reagents
    作者:Abernethy,C. D.; Et Al
    参考文献:Tetrahedron Letters 日期:2000 卷标:41(39) 页码:7567-7570]

    = 822-67-3
    反应条件:1.1 Reagents: Tert-Butyl Hydroperoxide Catalysts: 5,10,15,20-Tetrakis(Pentafluorophenyl)Porphyrinatoiron(Iii) Chloride Solvents: Acetonitrile,Water; 10 Min,25 °C
    标题:The Radical Versus Non-Radical Reactive Intermediates In The Iron(Iii) Porphyrin Catalyzed Oxidation Reactions By Hydroperoxides,Hydrogen Peroxide And Iodosylarene
    作者:Agarwala,Arunava; Et Al
    参考文献:Catalysis Letters 日期:2008 卷标:124(3-4) 页码:256-261]

    = 822-67-3
    反应条件:1.1 Reagents: Tert-Butyl Hydroperoxide Catalysts: 5,10,15,20-Tetrakis(Pentafluorophenyl)Porphyrinatoiron(Iii) Chloride Solvents: Acetonitrile,Water; 10 Min,Rt
    标题:Cytochrome P-450 Model Compound Catalyzed Selective Hydroxylation Of C-H Bonds: Dramatic Solvent Effect
    作者:Agarwala,Arunava; Et Al
    参考文献:Chemical Communications (Cambridge 日期:2006 卷标:(46) 页码:4823-4825]

    71352-18-6 = 822-67-3
    反应条件:1.1 Reagents: Tetrabutylammonium Fluoride Solvents: Acetonitrile
    标题:The Electrophilic Substitution Of Allylsilanes And Vinylsilanes
    作者:Fleming,Ian; Et Al
    参考文献:Organic Reactions (Hoboken 日期:1989 卷标:37]

    1192-78-5 = 822-67-3
    反应条件:1.1 Reagents: Carbon Monoxide Catalysts: Gold Solvents: Acetone,Water; 4 H,10 Atm,25 °C
    标题:Mild And Efficient Co-Mediated Eliminative Deoxygenation Of Epoxides Catalyzed By Supported Gold Nanoparticles
    作者:Ni,Ji; Et Al
    参考文献:Chemical Communications (Cambridge 日期:2011 卷标:47(2) 页码:812-814]

    32700-48-4 = 822-67-3
    反应条件:1.1 Reagents: Ammonia
    标题:Cohalogenation Of Olefins: Application To The Synthesis Of Allyl Alcohols
    作者:Rodriguez,J.; Et Al
    参考文献:Tetrahedron Letters 日期:1984 卷标:25(5) 页码:527-8]

    1426254-41-2 = 822-67-3
    反应条件:1.1 Reagents: Chlorosuccinimide,Water Catalysts: Boron Trifluoride Etherate Solvents: Acetonitrile; 18 H,25 °C1.2 Reagents: Sodium Bicarbonate,Sodium Sulfite Solvents: Water; Rt
    标题:Lewis Basic Selenium Catalyzed Chloroamidation Of Olefins Using Nitriles As The Nucleophiles
    作者:Tay,Daniel Weiliang; Et Al
    参考文献:Organic Letters 日期:2013 卷标:15(6) 页码:1310-1313]

    766-07-4 = 822-67-3
    反应条件:1.1 Catalysts: Magnesium Acetate,Silica,Palladium Chloride,Lead Acetate Solvents: Hexane
    标题:Process For Producing 2-Cyclohexen-1-Ol By Catalytic Hydrogenolysis Of Cyclohexenyl Hydroperoxide
    参考文献:World Intellectual Property Organization]

    = 822-67-3
    反应条件:1.1 Reagents: 2-Propanamine,N-(1-Methylethyl)-,Sodium Salt (1:1) Catalysts: Pentamethyldiethylenetriamine Solvents: Dimethylethylamine; 25 °C
    标题:Reactions Of Sodium Diisopropylamide: Liquid-Phase And Solid-Liquid Phase-Transfer Catalysis By N,N,N',N'',N''-Pentamethyldiethylenetriamine
    作者:Ma,Yun; Et Al
    参考文献:Journal Of The American Chemical Society 日期:2021 卷标:143(33) 页码:13370-13381]

    = 822-67-3
    反应条件:1.1 Reagents: Tert-Butyllithium Catalysts: Cyclohexylamine (Merrifield Resin-Supported) Solvents: Tetrahydrofuran; 5 Min,Rt; Rt -> -78 °C; -78 °C; 30 Min,-78 °C; 90 Min,Rt1.2 Solvents: Tetrahydrofuran; 8 H,Reflux
    标题:Rearrangement Of Epoxides To Allylic Alcohols In The Presence Of Reusable Basic Resins
    作者:Smith,Keith; Et Al
    参考文献:Catalysis Letters 日期:2009 卷标:128(1-2) 页码:101-105]

    944064-52-2 = 822-67-3
    反应条件:1.1 Reagents: Chlorosuccinimide,Water Catalysts: Indium Trichloride Solvents: Acetonitrile; 18 H,25 °C1.2 Reagents: Sodium Bicarbonate,Sodium Sulfite Solvents: Water; Rt
    标题:Lewis Basic Selenium Catalyzed Chloroamidation Of Olefins Using Nitriles As The Nucleophiles
    作者:Tay,Daniel Weiliang; Et Al
    参考文献:Organic Letters 日期:2013 卷标:15(6) 页码:1310-1313]

    190134-35-1 = 822-67-3
    反应条件:1.1 Reagents: 1,3,5-Trimethoxybenzene Catalysts: Silver Hexafluoroantimonate Solvents: Dichloromethane; 20 H,40 °C
    标题:Silver(I)-Catalyzed Deprotection Of P-Methoxybenzyl Ethers: A Mild And Chemoselective Method
    作者:Kern,Nicolas; Et Al
    参考文献:Journal Of Organic Chemistry 日期:2012 卷标:77(20) 页码:9227-9235]

    51918-79-7 = 822-67-3
    反应条件:1.1 Reagents: Sodium Borohydride Catalysts: Indium Trichloride Solvents: Acetonitrile; 30 Min,-10 °C1.2 Solvents: Acetonitrile; -10 °C; -10 °C -> Rt; 6 H,Rt1.3 Solvents: Water; Rt
    标题:Selective Reductive Cleavage Of 2,3-Epoxybromides By The Incl3-Nabh4 Reagent System
    作者:Ranu,Brindaban C.; Et Al
    参考文献:Tetrahedron Letters 日期:2004 卷标:45(46) 页码:8579-8581]

    = 822-67-3
    反应条件:1.1 Reagents: Tris(Trimethylsilyl)Silane Catalysts: Azobisisobutyronitrile Solvents: Toluene; 1 H,Reflux
    标题:Se-Phenyl Prop-2-Eneselenoate: An Ethylene Equivalent For Diels-Alder Reactions
    作者:Jung,Michael E.; Et Al
    参考文献:Angewandte Chemie 日期:2013 卷标:52(7) 页码:2060-2062]

    2699-13-0 = 822-67-3 [标题:Reaction Conditions
    标题:Cohalogenation Of Olefins: Application To The Synthesis Of Allyl Alcohols
    作者:Rodriguez,J.; Et Al
    参考文献:Tetrahedron Letters 日期:1984 卷标:25(5) 页码:527-8
📜2-环己烯-1-酮置于n-Methylpyrrolidine Zinc Borohydride体系中,用 四氢呋喃 作为反应溶剂,化学反应 1.0H,以95%的收率获得产物2-环己烯醇
参考文献:N-甲基吡咯烷-硼氢化锌:一种新型稳定高效的有机合成还原剂
标题:N-甲基吡咯烷-硼氢化锌:一种新型稳定高效的有机合成还原剂
摘要:摘要 N-甲基吡咯烷-硼氢化锌很容易制备并用于还原各种有机化合物,如醛,酮,酰氯和酯.反应在室温或回流条件下在thf中进行,产率从好到极好.在 α,β-不饱和羰基化合物的还原中观测到完全的区域选择性.
DOI:10.1081/scc-120015705

海关参考信息

专利信息


专利号:US-11926589-B2
优先权日:2019-07-09
标 题 :Process for the synthesis of non-racemic cyclohexenes
发明人：REISMAN SARAH; ROMBOLA MICHAEL; LADD CAROLYN L; MCLAUGHLIN MARTIN JOHN; ZUEND STEPHAN; GOETZ ROLAND
权利人:BASF CORP; CALIFORNIA INST OF TECHN
摘要:This invention relates to a process for the synthesis of a non-racemic cyclohexene compound of formula (I) by a Diels-Alder reaction of a compound of formula (II) with a compound of formula (III) wherein R 1 , R 2 , R 3 , R 4 , R 5 , R 6 , R 7 , R 8 , R 9 and Y have the meanings as defined in the description in the presence of a catalyst comprising at least one m-valent metal cation M m+ wherein the metal M is selected from Scandium (Sc), Yttrium (Y), Lanthanum (La), Cerium (Ce), Praseodymium (Pr), Neodymium (Nd), Promethium (Pm), Samarium (Sm), Europium (Eu), Gadolinium 15 (Gd), Terbium (Tb), Dysprosium (Dy), Holmium (Ho), Erbium (Er), Thulium (Tm), Ytterbium (Yb), Lutetium (Lu), Gallium (Ga) and Indium (In), and m is an integer of 1, 2 or 3, and a chiral ligand of the formula (IV) wherein R 10a , R 10b , R 10c , R 10d , R 10a′ , R 10b′ , R 10c′ , R 10d′ , Z and Z′ have the meanings as defined in the description.

专利号:US-10981850-B2
优先权日:2019-04-15
标 题 :One-step flow-mediated synthesis of cannabidiol (CBD) and derivatives
发明人：PORCO JOHN A; BEELER AARON B; BROWN LAUREN E; TRILLES RICHARD V
权利人:UNIV BOSTON
摘要:Herein are described apparatus and processes for the preparation of cannabinoids, such as cannabidiol (CBD) and derivatives thereof. The apparatus and processes described can be used for the one-step, flow-mediated synthesis of cannabidiol and derivatives with improved overall yield, material throughput, and product purity relative to batch processes.

专利号:US-5906954-A
优先权日:1998-10-13
标 题 :Removal of titanium atoms from titanium silicate molecular sieves
发明人：KOERMER GERALD S
权利人:ENGELHARD CORP
摘要:This invention relates to the preparation of novel titanium silicate molecular sieves with modified properties such as adsorption, ion-exchange and catalytic behavior by selective extraction of framework titanium atoms after synthesis of the sieves.

专利号:WO-2025024449-A1
优先权日:2023-07-24
标 题:Processes and intermediates for synthesis of mrtx1133
发明人：GHARBAOUI TAWFIK; SCATTOLIN THOMAS; CHEN CHENG
权利人:MIRATI THERAPEUTICS INC
摘要:The present invention relates to new synthetic routes of synthesizing MRTX1133. The invention also provides intermediates used in the provided synthetic routes.

专利号:US-4091041-A
优先权日:1977-06-13
标 题:Preparation of 1,4-diols by hydrolysis-hydrogenation of 2-alkoxytetrahydrofurans
发明人：SMITH WILLIAM EDWARD
权利人:GEN ELECTRIC
摘要:2-ALKOXYTETRAHYDROFURANS ARE CONVERTED TO 1,4-DIOLS UNDER HYDROLYSIS-HYDROGENATION CONDITIONS. The method may be coupled with the synthesis of 2-alkoxytetrahydrofurans to provide a highly efficient, two-step conversion of allylic alcohols to butanediols.

专利号:WO-2024118348-A1
优先权日:2022-11-29
标 题:Processes and intermediates for synthesis of mrtx0902
发明人：SCATTOLIN THOMAS; CHEN CHENG; ACHMATOWICZ MICHAL
权利人:MIRATI THERAPEUTICS INC
摘要:The present invention relates to new synthetic routes of manufacturing MRTX0902. The invention also provides intermediates used in the provided synthetic routes, and the fumarate salt of MRTX0902.

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参考DOI号:10.1016/j.poly.2020.114653
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