CAS: 4373-60-8; 2-(3-Bromophenyl)Pyridine

相似化合物

63996-36-1 98420-98-5 27012-25-5

上下游产品

2-苯基吡啶 2-Phenylpyridine 1008-89-5
2-(5-Bromo-2-Methoxyphenyl)Pyridine

2-苯基吡啶置于ruthenium On Silica,N-溴代丁二酰亚胺(Nbs)体系中,用 N,N-二甲基乙酰胺 作为反应溶剂,化学反应 20.0H,以57%的收率获得产物2-(3-溴苯)吡啶
参考文献:异质钌催化在嘌呤碱基上进行间-C-H溴化反应
标题:异质钌催化在嘌呤碱基上进行间-C-H溴化反应
摘要:对位置选择性远程ch功能化的方法有很高的要求.在本文中,我们公开了用于第一多相钌催化剂元-选择性c-H官能化,这使遥控卤化具有优异的部位选择性和足够的范围.通用的非均质ru @ Sio 2催化剂具有广泛的适用性,易于回收和再利用,为嘌呤的直接荧光标记奠定了基础.与钯,铑,铱或钴络合物相反,仅钌催化歧管提供了对间卤代嘌呤衍生物的访问,这说明了钌ch活化催化的独特能力.
DOI:10.1002/anie.201609014

专利信息

专利号:WO-2009073246-A1
优先权日:2007-12-06
标 题 :Method for the synthesis of iridium (iii) complexes with sterically demanding ligands

专利号:US-9312503-B2
优先权日:2014-05-13
标 题 :Green light iridium (III) complex and a method of preparing the same
发明人：ZHAO QIANG; HUANG WEI; LIU SHUJUAN; WANG YIFAN; ZOU QINGHUA
权利人:SHENZHEN CHINA STAR OPTOELECT; SHENZHEN CHINA STAR OPTOELECT
摘要:The present invention provides a green light iridium (III) complex and a method of preparing the same, which has a formula as follows: n n n n n n n n n n n n wherein m is 2 or 3; at least one of Ar 1 , Ar 2 , Ar 3 , Ar 4 , and Ar 5 is a group containing fluorophenyl unit, which has a formula as follows: n n n n n n n n n n n n n n n n wherein R 1 , R 2 , R 3 , R 4 , R 5 are H, CH 3 , or FCF 3 , and at least one of R 1 , R 2 , R 3 , R 4 , R 5 is F or CF 3 . The green light iridium (III) complex of the present invention has higher light emitting efficiency; the method of preparing the same has tender reaction conditions, simple synthesis steps and easy to handle. Due to the fluorophenyl unit capable of transporting electrons introduced therein, carrier current mobility and exciton transporting equilibrium are increased to contribute better exciton recombination so as to enhance performance of an organic electroluminescent device.

专利号:US-2009124805-A1
优先权日:2006-12-08
标题 :Method for synthesis of iriduim (iii) complexes with sterically demanding ligands

专利号:US-8519130-B2
优先权日:2006-12-08
标 题 :Method for synthesis of iriduim (III) complexes with sterically demanding ligands
发明人：ALLEYNE BERT
权利人:ALLEYNE BERT; UNIVERSAL DISPLAY CORP
摘要:Phosphorescent materials and devices with improved device manufacturing, fabrication, stability, efficiency, and/or color.

专利号:TW-200925150-A
优先权日:2007-12-06
标 题 :Method for the synthesis of iridium (III) complexes with sterically demanding ligands