CAS: 105598-27-4; Dipyrazino[2,3-F:2',3'-H]Quinoxaline-2,3,6,7,10,11-Hexacarbonitrile

该化合物是一种复杂的有机化合物,其独特结构特征包括多双子素和五氯线藻类.该化合物有6个西亚诺(EuroCN)组,其稳定性和溶解性特征取决于溶剂和环境条件,而这些条件对实际应用至关重要.

结构式图片

相似化合物

2379-55-7 105598-27-4 105598-29-6

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CAS号527-31-1 环己六酮水合物 | CAS号1187-42-4 二氨基马来腈

合成工艺路线路线简述

  • 合成目标产物 Hexaazatriphenylenehexacabonitrile 主要起始原料 Hexaketocyclohexane Octahydrate And Diaminomaleonitrile
  • (文献来源)合成步骤主要原料 Hexaketocyclohexane Octahydrate 和 Diaminomaleonitrile
📜在 硝酸,溶剂黄146体系中,用 水 用作溶剂,化学反应 2.0H,反应生成2,3,6,7,10,11-六氰基-1,4,5,8,9,12-六氮杂苯并菲; 2,3,6,7,10,11-六氰基-1,4,5,8,9,12-六氮杂三亚苯
参考文献:平面卟啉和六氮杂苯并菲衍生物的面对面电荷转移π配合物中的超快光致电子转移
标题:平面卟啉和六氮杂苯并菲衍生物的面对面电荷转移π配合物中的超快光致电子转移
摘要:平面卟啉和具有大形成常数(例如10 4 M-1)的 1,4,5,8,9,12-六氮杂苯并菲 (Hat) 衍生物之间形成电荷转移 (Ct) π 配合物,表现出广泛的 Ct吸收乐队.异常大的形成常数是由卟啉和 Hat 衍生物的两个平面 π 平面之间的紧密面对面接触造成的.通过循环伏安法测量的卟啉和hat衍生物的氧化还原电位表明卟啉和hat衍生物分别充当电子供体和受体.通过uv-Vis,荧光和1 H NMR测量在非极性溶剂中检查卟啉和hat衍生物之间1 : 1 Ct复合物的形成.通过飞秒激光闪光光解测量观测到在 Ct π 复合物中发生了前所未有的从卟啉单元到 Hat 单元的超快光诱导电子转移.通过透射电子显微镜 (Tem) 和原子力显微镜 (Afm) 观测到由平面卟啉和 Hat 衍生物组成的高度线性聚集体.
Doi:10.1039/c4Sc02787F

专利信息


专利号:WO-2014004985-A1
优先权日:2012-06-29
标题 :1,4-azaborine compounds and methods of synthesis
发明人:LIU SHIH-YUAN; XU SENMIAO; KWONG RAYMOND C
权利人:STATE OF OREGON ACTING BY & THROUGH THE ST BOARD OF HIGHER EDUCATION ON BEHALF OF THE UNIVERSITY OF; UNIV DISPLAY CORP
摘要:A compound comprising a structure of formula A

专利号:US-8987451-B2
优先权日:2012-01-03
标题 :Synthesis of cyclometallated platinum(II) complexes
发明人:TSAI JUI-YI; KOTTAS GREGG; YEAGER WALTER
权利人:UNIVERSAL DISPLAY CORP
摘要:A single-step method of making tetradentate platinum complexes is disclosed. The method advantageously allows the formation of a platinum complex in a single step, even with sterically hindered ligands, without the use of highly reactive intermediates. The compounds made by the disclosed method are useful in OLED applications.

专利号:US-2024215280-A1
优先权日:2022-10-31
标 题:In situ core/shell perovskite nanocrystal material, method of preparation thereof, and light emitting device comprising the same
发明人:LEE TAE-WOO; KIM JOO SUNG
权利人:SEOUL NAT UNIV R&DB FOUNDATION; PEROLED CO LTD
摘要:The present inventive concept relates to an in situ core/shell perovskite nanocrystal film formed by an in situ nanocrystal synthesis process, a method for producing the same, and a light emitting device comprising the same as a light-emitting layer. The in situ core/shell perovskite nanocrystal film formed by the in situ nanocrystal synthesis process according to the present inventive concept exhibits a strong charge confinement effect by nanocrystal formation, and can simultaneously greatly improve the luminescence efficiency and lifetime by maintaining the fast charge transport capability of polycrystalline perovskite.

专利号:WO-2021017274-A1
优先权日:2019-07-30
标 题 :Thermally activated delayed fluorescent molecular material and synthesis method therefor, and electroluminescent device
发明人:WANG YANJIE
权利人:WUHAN CHINA STAR OPTOELECTRONICS SEMICONDUCTOR DISPLAY TECH CO LTD
摘要:The present invention provides a thermally activated delayed fluorescent molecular material and a synthesis method therefor, and an organic electroluminescent device. Boron-nitrogen containing thermally activated delayed fluorescent molecules are synthesized. Such molecules have an intramolecular multiple resonance effect, and can well narrow the luminescence spectrum. Such molecules have a super-large plane and exhibit great rigidity, so that the molecules have high intersystem crossing rate constant and reverse intersystem crossing rate constant, thereby effectively inhibiting the reduction of radiation transition rate caused by the energy gap law, and obtaining high PLQY.

专利号:US-2013172561-A1
优先权日:2012-01-03
标 题:Synthesis of cyclometallated platinum(ii) complexes

专利号:US-10577325-B2
优先权日:2017-03-28
标 题 :Method for preparing a series of carbazole derivatives and use thereof in organic light-emitting diodes
发明人:CAO JIANHUA; WANG SHIBO; HUA RUIMAO
权利人:SHIJIAZHUANG CHENGZHI YONGHUA DISPLAY MATERIALS CO LTD
摘要:Disclosed are a method for preparing a series of carbazole derivatives and use thereof in organic light-emitting diodes. The structure of the material is as shown in Formula I. An organic electroluminescent device prepared by the material can have a significantly improved power efficiency and an external quantum efficiency for the device and an extended life for an orange light or red light device; moreover, the material has characteristics, for example, methods for the synthesis and purification of the material are simple and suitable for large-scale production, and is an ideal choice as a luminescent material for organic electroluminescent devices. The use of the organic electroluminescent diode material as a carrier transport material or as a luminescent material alone or as a host material in a light-emitting layer also falls within the scope of protection.

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品牌试剂参考报价(招募中)

📌 第三方产品分析报告

✅ COA系统入驻 | 共享模式

合成参考文献


参考文献:10.1021/acsami.0c12388
摘要:Yadav A, Panda DK, Zhang S, Zhou W, Saha S. Electrically Conductive 3D Metal-Organic Framework Featuring π-Acidic Hexaazatriphenylene Hexacarbonitrile Ligands with Anion-π Interaction and Efficient Charge-Transport Capabilities. ACS Appl Mater Interfaces. 2020 Sep 09;12(36):40613–9.
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