专利号:US-4820309-A 优先权日:1987-03-05 标题 :1:2-chromium complex dyes for tanned leather 发明人:HOLLIGER HERBERT 权利人:SANDOZ LTD 摘要:Complexes of the formula ##STR1## wherein each R 1 is independently (a) the radical of a coupling component of the active methylene non-cyclic or homocyclic series, (b) the radical of a coupling component of the heterocyclic series or (c) the radical of a coupling component of the monocyclic benzene series, n with the proviso that at least one R 1 is the radical of a coupling component of the active methylene non-cyclic or homocyclic series, n each R 2 is independently hydrogen, C 1-4 alkyl or --SO 2 NR 4 R 5 , n each R 3 is independently hydrogen, halo, C 1-4 alkyl or --SO 2 NR 4 R 5 , and n each M and M 1 is independently hydrogen or a cation, n wherein each R 4 is independently hydrogen, C 1-4 alkyl or C 2-3 hydroxyalkyl, and n each R 5 is independently hydrogen, C 1-4 alkyl, C 2-3 hydroxyalkyl, cyclohexyl, cyclohexyl substituted by methyl, phenyl or phenyl substituted by methyl, with the proviso that at least one of Ring A and R 1 of each disazo ligand bears an --SO 2 NR 4 R 5 group, n and mixtures of such or containing such complexes, the use of such complexes and mixtures for dyeing substrates dyeable with anionic dyes (e.g., tanned leather and pelts), substrates dyed therewith, processes for synthesizing such complexes and mixtures and disazo compounds useful in their synthesis.
参考文献:10.1007/bf02784540 摘要:McNall AD, Fosmire GJ. Zinc status does not affect aluminum deposition in tissues of rats. Biological Trace Element Research. 1996 Jun;53(1-3):7–18. doi: 10.1007/bf02784540. 参考文献:10.1007/bf02784562 摘要:Miller GD, Keen CL, Stern JS, Uriu-Hare JY. Copper absorption, endogenous excretion, and distribution in Sprague-Dawley and lean (Fa/Fa) Zucker rats. Biological Trace Element Research. 1996 Jun;53(1-3):261–79. doi: 10.1007/bf02784562. 参考文献:10.1007/s11064-006-9060-8 摘要:Wu WC, Lai CC, Liu JH, Singh T, Li LM, Peumans WJ, Van Damme EJ, Wu AM. Differential binding to glycotopes among the layers of three mammalian retinal neurons by man-containing N-linked glycan, T(alpha) (Galbeta1-3GalNAcalpha1-), Tn (GalNAcalpha1-Ser/Thr) and I (beta)/II (beta) (Galbeta1-3/4GlcNAcbeta-) reactive lectins. Neurochem Res. 2006 May;31(5):619–28. doi: 10.1007/s11064-006-9060-8. 参考文献:10.1007/bf02159274 摘要:SANDRITTER W, DIEFENBACH H, KRANTZ F. [Quantitative binding of ribonucleic acid with gallocyanin chrome alum]. Experientia. 1954 May 15;10(5):210–2. doi: 10.1007/bf02159274. 参考文献:10.1007/s12011-012-9580-9 摘要:Herring BJ, Logsdon AL, Lockard JE, Miller BM, Kim H, Calderon EA, Vincent JB, Bailey MM. Long-term exposure to [Cr(3)O(O (2)CCH (2)CH (3)) (6)(H (2)O) (3)] (+) in Wistar rats fed normal or high-fat diets does not alter glucose metabolism. Biol Trace Elem Res. 2013 Mar;151(3):406–14.