CAS: 2203-80-7; 5-Methyl-1-Hexyne

该化合物是具有分子式C7H12的终端烷,这种不饱和的碳氢化合物的特点是处于终端位置,具有三联性,在第五碳上具有甲基替代成分.它是有机合成的多功能中间体,特别是在点击化学,金属催化的混合反应和复杂分子结构的准备方面.它与Huisgen循环增生中的亚化物发生反应,对生物合成和聚合物的应用很有价值.该化合物在受控条件下的明确界定的结构和稳定性确保了研究和工业过程的一贯性.由于其易燃性和潜在再活性,需要妥善处理.

结构式图片

欧盟法规

ECHA物质C&L通报

上下游产品

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合成工艺路线路线简述

    📜Alkaline Earth Salt Of/the/ Methylsulfuric Acid置于氢氧化钾体系中,化学反应生成5-甲基-1-已炔
    参考文献:Andre,Annales De Chimie (Cachan,France),1913,Vol. <8> 29,P. 553
    标题:Andre,Annales De Chimie (Cachan,France),1913,Vol. <8> 29,P. 553

    海关参考信息

    专利信息


    专利号:US-9879043-B1
    优先权日:2013-06-06
    标 题:Synthesis of non-natural cofactor analogs of S-adenosyl-L-methionine using methionine adenosyltransferase
    发明人:THORSON JON; HUBER TYLER; ZHANG JIANJUN; Singh Shanteri
    权利人:UNIV KENTUCKY RES FOUND
    摘要:The present disclosure relates to the synthesis of non-natural analogs of S-adenosyl-L-methionine (SAM) and/or of Se-adenosyl-L-methionine (SeAM) by reacting a methionine analog and adenosine triphosphate (ATP) in the presence of at least one methionine adenosyltransferase (MAT), and to use thereof with downstream SAM and/or SeAM utilizing enzymes. The non-natural analogs of SAM and/or SeAM have the general formula: n nwhere X is S or Se, and R 1 is an alkyl group.

    专利号:US-9988349-B2
    优先权日:2014-01-03
    标 题:Direct stereospecific synthesis of unprotected aziridines from olefins
    发明人:ESS DANIEL HALSELL; FALCK JOHN RUSSELL; JAT JAWAHAR LAL; KURTI LASZLO
    权利人:ESS DANIEL HALSELL; FALCK JOHN RUSSELL; JAT JAWAHAR LAL; KURTI LASZLO
    摘要:A method for the direct stereospecific conversion of structurally diverse mono-, di-, tri- and tetra-substituted olefins to N—H, N-alkyl, N-cycloalkyl, or N-aralkyl aziridines using a hydroxylamine amination agent with transition metal catalyst. The method is operationally simple (i.e., one-pot), scalable and fast at ambient temperature.

    专利号:US-7999090-B2
    优先权日:2000-07-07
    标 题:Fungal cell wall synthesis gene
    发明人:TSUKAHARA KAPPEI; HATA KATSURA; SAGANE KOJI; NAKAMOTO KAZUTAKA; TSUCHIYA MAMIKO; WATANABE NAOAKI; OHBA FUMINORI; TSUKADA ITARU; UEDA NORIHIRO; TANAKA KEIGO; KAI JUNKO
    权利人:EISAI R&D MAN CO LTD
    摘要:The present invention provides isolated DNA encoding a GWT1 protein having activity to confer resistance of a fungus against a compound of formula Ia, and wherein a defect of a function of the GWT1 protein leads to a decrease in the amount of a glycosylphosphatidylinositol (GPI)-anchored protein in the cell wall of a fungus.

    专利号:US-2016340305-A1
    优先权日:2014-01-03
    标题 :Direct stereospecific synthesis of unprotected aziridines from olefins

    专利号:CN-107428649-B
    优先权日:2015-03-13
    标题:Process for the synthesis of novel compounds derived from 3-hydroxy-cyclopentylacetic acid

    专利号:RU-2726412-C2
    优先权日:2015-03-13
    标题:Method of synthesis of novel compounds obtained from 3-hydroxycyclopentylacetic acid

    供应商参考报价(招募中)

    品牌试剂参考报价(招募中)

    📌 第三方产品分析报告

    ✅ COA系统入驻 | 共享模式

    合成参考文献


    摘要:Aitken, R. A.; Aitken, K., Science of Synthesis, (2008) 43, 622.
    摘要:Yoshida, H., Science of Synthesis Knowledge Updates, (2022) 3, 8.
    摘要:Celik, I.; Hummel, S.; Kirsch, S. F., Science of Synthesis Knowledge Updates, (2019) 1, 15.
    摘要:Yoshida, H., Science of Synthesis: Advances in Organoboron Chemistry towards Organic Synthesis, (2019) 1, 68.
    摘要:Bellanger, C.; Chelli, S.; Lakhdar, S., Science of Synthesis, (2021) , 232.
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