CAS: 1552-91-6; 2-Cyclohexylideneacetic Acid

该化合物是一种环己的不饱和的箱式碳酸,其特征是环己氨基酸组,附于乙酸酸协会,该化合物主要用作有机合成的中间体,特别是在生产药品,农用化学品和特殊化学品方面;其反应性双环联和盒式组能够多功能化,使其对构建复杂的分子框架很有价值;环己酰基酸有助于增强合成应用的稳定性和消毒控制.该酸的纯度和一贯质量对于研究和工业工艺的再生至关重要.建议在惰性条件下妥善处理和储存,以保持其完整性.

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1552-92-7 4435-18-1 1713-63-9

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上下游产品

methanol Z)-1,2-dibromo-vinyl)-cyclohexene1-((Z)-1,2-dibromo-vinyl)-cyclohexene sodium methylate 1-cyclohexenylacetic acidethyl cyclohexylideneacetate 1-cyclohexenylacetic acid Cyclohexylacetic acid 2-cyclohexylidene ethanol

合成工艺路线路线简述

    📜环己基亚基乙醛置于铬酸,溶剂黄146,苯体系中,化学反应生成2-环亚己基乙酸
    参考文献:Dimroth,Chemische Berichte,1938,Vol. 71,P. 1333,1345
    标题:Dimroth,Chemische Berichte,1938,Vol. 71,P. 1333,1345

    海关参考信息

    专利信息


    专利号:US-6794534-B2
    优先权日:2000-06-23
    标题:Synthesis of functionalized and unfunctionalized olefins via cross and ring-closing metathesis
    发明人:GRUBBS ROBERT H; CHATTERJEE ARNAB K; MORGAN JOHN P; SCHOLL MATTHIAS; CHOI TAE-LIM
    权利人:CALIFORNIA INST OF TECHN
    摘要:The invention is directed to the cross-metathesis and ring-closing metathesis reactions between geminal disubstituted olefins and terminal olefins, wherein the reaction employs a Ruthenium or Osmium metal carbene complex. Specifically, the invention relates to the synthesis of α-functionalized or unfunctionalized olefins via intermolecular cross-metathesis and intramolecular ring-closing metathesis using a ruthenium alkylidene complex. The catalysts preferably used in the invention are of the general formula n wherein: n M is ruthenium or osmium; n X and X 1 are each independently an anionic ligand; n L is a neutral electron donor ligand; and, n R, R 1 R 6 , R 7 , R 8 , and R 9 are each independently hydrogen or a substituent selected from the group consisting of C 1 -C 20 alkyl, C 2 -C 20 alkenyl, C 2 -C 20 alkynyl, aryl, C 1 -C 20 carboxylate, C 1 -C 20 alkoxy, C 2 -C 20 alkenyloxy, C 2 -C 20 alkynyloxy, aryloxy, C 2 -C 20 alkoxycarbonyl, C 1 -C 20 alkylthio, C 1 -C 20 alkylsulfonyl and C 1 -C 20 alkylsulfinyl.

    专利号:US-6765114-B1
    优先权日:1998-12-29
    标题 :Process for the synthesis of 1-(aminomethyl)cyclohexyl-acetic acid
    发明人:GIZUR TIBOR; LENGYEL ZOLTANNE; SZALAI KRISZTINA
    权利人:RICHTER GEDEON VEGYESZET
    摘要:The invention relates to a new process for the synthesis of 1-(aminomethyl)cyclohexyl-acetic acid of formula (I) via the new intermedier 1-(nitromethyl)cyclohexyl-acetic acid derivative of formula (II), wherein R represents hydrogen, benzyl group, diphenylmethyl group or C 1 -C 4 alkyl or alkoxy aromatic ring substituted derivatives thereof.

    专利号:WO-0039074-A1
    优先权日:1998-12-29
    标题 :Process for the synthesis of 1-(aminomethyl)cyclohexyl-acetic acid

    专利号:SK-9372001-A3
    优先权日:1998-12-29
    标题:Process for the synthesis of 1-(aminomethyl)cyclohexyl-acetic acid

    专利号:ES-2207979-T3
    优先权日:1998-12-29
    标 题:PROCESS FOR SYNTHESIS OF ACID 1- (AMINO-METIL) -CICLOHEXIL-ACETIC.

    专利号:US-2002137978-A1
    优先权日:2000-06-23
    标题:Synthesis of functionalized and unfunctionalized olefins via cross and ring-closing Metathesis

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    ✅ COA系统入驻 | 共享模式

    合成参考文献


    摘要:Michalak, M.; Gulajski, L.; Grela, K., Science of Synthesis, (2010) 47, 354.
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