CAS: 14243-64-2; Chloro(Triphenylphosphine)Gold(I)

该化合物是一个协调化合物,其特点是黄金在+1氧化状态下具有一种协调化合物,其特点是存在一个金原子,该原子与三苯基苯基苯基离心和氯化离子相协调,该化合物一般是黄色至橙色固态,以其稳定性和溶解性在二氯甲烷和氯仿等有机溶剂中闻名.氯(三苯基硫酸)gold经常用于有机合成和催化,特别是在涉及金催化的反应中,因为其能够激活 alkynes和 alkenes.三苯基苯基离子和增强黄金中心的再活动性,使其成为各种化学变异的一种有价值的试剂.此外,该化合物可以作为其他金化合物的前体,有助于其在学术研究和工业应用中的重要性.在处理该化合物时,应当注意安全防范,因为如果浸入或吸入,可能会对健康造成危害.

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CAS号39929-21-0 氯(四氢噻吩)金(I) | CAS号603-35-0 三苯基膦 | CAS号616-47-7 N-甲基咪唑 | CAS号37822-98-3 cis-[AuIII(C6F5... | CAS号866395-16-6 三苯基膦金(I)双(三氟甲磺酰... | CAS号29892-37-3 氯化(二甲硫醚)金(I) | CAS号1582-24-7 2,3,4,5,6-五氟苯基硼酸 | CAS号69462-32-4 [AuCl(2,2'-thio... | CAS号185119-04-4 gold,2-[4-[2-(4... | CAS号20224-83-3 Gold, azido(tri... | CAS号18024-34-5 二氯(DPPE)二金(I) | CAS号75-36-5 乙酰氯 | CAS号24228-71-5 (4-fluorophenyl... | CAS号12092-47-6 (1,5-环辛二烯)氯铑(I)二聚体 | CAS号143890-25-9 | CAS号14853-97-5 gold(1+),triphe... | CAS号21209-78-9 gold,iodo(triph...

合成工艺路线路线简述

    📜Chloroauric Acid置于triphenylphosphine体系中,用89%的收率获得三苯基膦氯金
    参考文献:Schmidbaur,Hubert; Inoguchi,Yoshio,Chemische Berichte,1980,Vol. 113,# 5,P. 1646-1653
    标题:Schmidbaur,Hubert; Inoguchi,Yoshio,Chemische Berichte,1980,Vol. 113,# 5,P. 1646-1653

    海关参考信息

    专利信息


    专利号:US-10174008-B2
    优先权日:2014-12-03
    标题:Synthesis of cyclopropyl indoles and cyclohepta[B]indoles, pharmaceutical compositions containing them and method of using them
    发明人:TANG WEIPING; LI XIAOXUN
    权利人:WISCONSIN ALUMNI RES FOUND
    摘要:Methods of making indole analogs using a rhodium-containing catalyst are described, along with methods of using the compounds to treat hyperglycemic, hyperlipidemic, or autoimmune disorders in mammals, and corresponding pharmaceutical compositions. Disclosed herein is a method of making indoles. The method comprises contacting a reactant of formula I wherein E is a protecting group, —SO2-Aryl, or —SO2-substituted-Aryl; and R and R2 are independently selected from the group consisting of hydrogen, halo, C1-C12-alkyl and aryl; with a rhodium(1)-containing catalyst.

    专利号:US-2024067779-A1
    优先权日:2021-03-01
    标题:Metallopolymers and iclick synthesis thereof
    发明人:BETO CHRISTOPHER; SCHANZE KIRK S; VEIGE ADAM S; YANG YAJING
    权利人:UNIV FLORIDA; UNIV OF TEXAS SAN ANTONIO
    摘要:Provided herein are various metallopolymers and methods of making the same.

    专利号:US-9272260-B2
    优先权日:2009-08-14
    标 题 :Methods of synthesis and purification by use of a solid support
    发明人:HAMMOND GERALD B; XU BO
    权利人:HAMMOND GERALD B; XU BO; UNIV LOUISVILLE RES FOUND
    摘要:Disclosed herein are novel methods of using polymeric adsorbent resin for chemical synthesis and the purification of product therefrom. Also disclosed herein is a novel method of using silica gel for the combination of chemical reaction and chromatography into a single step. The methods disclosed herein increase the efficiency of chemical synthesis processes. Accordingly, the utility of the methods disclosed herein includes the ability to automate chemical synthesis and purification of the resulting products.

    专利号:US-4387208-A
    优先权日:1981-12-21
    标 题:Phosphorous containing polymers as carriers for transition metals
    发明人:ALLCOCK HARRY R; FULLER TIMOTHY J; EVANS THOMAS L
    权利人:US NAVY
    摘要:Synthesis of new (lithiophenoxy)phosphazene high polymers is described whin polymers such as poly(dichlorophosphazene) are used as the starting material to prepare poly(organophosphazenes) by reaction thereof with sodium para-bromophenoxide. Poly(organophophazenes) thus obtained are used in a metal-halogen exchange reaction with n-butyllithium. The lithio derivatives thus obtained are used as reactive intermediates for the synthesis of polymers of formulas [NP(OC 6 H 4 X-p) x (OC 6 H 4 Br)y] n and [NP(OC 6 H 4 Li-p) x (OPh) y ] n , where X is PPh 2 , PPh 2 C 4 H 9 + Br - , SnPh 3 , AuPPh 3 , or COOH.

    专利号:CN-114874141-A
    优先权日:2022-06-02
    标题:Synthesis of phenanthrene compounds by ring-opening cyclization of alkenyl benzotriazole under visible light catalysis

    专利号:US-10494392-B2
    优先权日:2017-04-17
    标题 :Method of treating cancer with a two-component anti-cancer composition
    发明人:ISAB ANVARHUSEIN A; ALTAF MUHAMMAD; SELIMAN ADAM AHMED ABDALLAH
    权利人:UNIV KING FAHD PET & MINERALS
    摘要:Gold(I) complexes and gold(I) dithiocarbamate polymers as anticancer therapeutics. The Au(I) ion within the gold(I) complexes is coordinated to two phosphine ligands. The repeating unit formed by Au(I) ion coordinating to dithiocarbamate ligands are connected by Au(I)—Au(I) interactions within the gold(I) dithiocarbamate polymers. Also disclosed are methods of synthesis, pharmaceutical compositions incorporating the gold(I) complexes, pharmaceutical compositions incorporating the gold(I) dithiocarbamate polymers, and methods of treating cancer.

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    📌 第三方产品分析报告

    ✅ COA系统入驻 | 共享模式

    合成参考文献


    参考文献:10.1007/bf02910903
    摘要:Mingos DMP, Powell HR, Stolberg TL. Synthesis and structural characterization of the tetrahedral cluster [Au4(PPh3)4(μ2-SnCl3)2]. Transition Metal Chemistry. 1992 Aug;17(4):334–7. doi: 10.1007/bf02910903.
    参考文献:10.1007/bf00905829
    摘要:Nesmeyanov AN, Grandberg KI, Baukova TV, Kosina AN, Perevalova ÉG. [(Tricarbonylmanganese)cylclopentadienyl] (triphenylphosphine)gold. Russian Chemical Bulletin. 1969 Sep;18(9):1879–81. doi: 10.1007/bf00905829.
    参考文献:10.1007/bf00905828
    摘要:Nesmeyanov AN, Perevalova ÉG, Lemenovskii DA, Kosina AN, Grandberg KI. Feerocenyl(triphenylphosphine)gold. Russian Chemical Bulletin. 1969 Sep;18(9):1876–8. doi: 10.1007/bf00905828.
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