CAS: 13718-94-0; Isomaltulose

该化合物是一种来自苏格罗塞的分解糖,其特点是其独特的结构,由葡萄糖和葡萄糖组成,由-1,6-glycosidi联结联系在一起,区别于苏格罗塞,后者具有-1,2-glycosidic 联结.这一结构差异使巴拉蒂诺斯与传统糖相比具有较低的甘糖指数,使得它成为寻求较慢释放能量的人的首选,使它成为寻求较慢释放能量的人的首选.帕拉蒂诺斯在水中溶,具有甜味,大约50-60%如苏格罗内,经常用于食品,特别是体育营养和功能食品,因为它能够提供持续的能源释放,而不会导致血液甘蔗含量的快速上升.此外,巴拉蒂素不致癌,因此它不会导致牙齿腐烂,从而有利于牙科健康.在热和酸性条件下,它的稳定性能进一步增强它适用于各种食品配制.

结构式图片

相似化合物

63-42-3 66009-10-7 34980-39-7

上下游产品

CAS号20942-99-8 1-O-(α-葡萄糖基糖基)-D-甘露醇 | CAS号69-65-8 甘露醇 | CAS号50-70-4 山梨醇 | CAS号534-73-6 异麦芽糖醇

合成工艺路线路线简述

  • 合成目标产物 Palatinose 主要起始原料 Sucrose
  • (文献来源)合成步骤主要原料 Sucrose
Alkaline Earth Salt Of/the/ Methylsulfuric Acid置于ammonium Hydroxide体系中,化学反应生成帕拉金糖
参考文献:Avigad,Biochemical Journal,1959,Vol. 73,P. 587,589
标题:Avigad,Biochemical Journal,1959,Vol. 73,P. 587,589

海关参考信息

专利信息


专利号:WO-2023118363-A1
优先权日:2021-12-22
标题:Method for the synthesis of a carbonyl-functionalised adduct
发明人:GODEHARD SIMON P; PELZER ALEXANDER
权利人:BRAIN Biotech AG
摘要:The invention relates to a method for the synthesis of a carbonyl-functionalised adduct.

专利号:US-2024209018-A1
优先权日:2021-03-22
标题:Universal linker reagents for dna synthesis
发明人:REED MICHAEL W; WU CHENG-HSIEN; COOPER JOHN; DEMPCY ROBERT O
权利人:GENSCRIPT USA INC; CUSTOMARRAY INC
摘要:Provided herein are methods and compositions for oligonucleotide synthesis utilizing universal linker phosphoramidites. Methods and reagents are described with DNA synthesis using controlled pore glass (CPG) solid supports, and on platinum coated electrodes for electrochemical DNA synthesis. The universal linkers can be used as spacers in single-column PCR primer synthesis to generate 2 strands with free 3′-hydroxy termini after cleavage. The methods and compositions utilize a solid support system for synthesis of oligonucleotides, wherein the support has platinum electrodes and a universal linker, optionally wherein the platinum electrode is coated with an amine. The methods and compositions further describe use of universal linker phosphoramidites and the platinum electrode is coated with a monosaccharide, or a disaccharide.

专利号:US-2024199566-A1
优先权日:2022-11-16
标题:Catalytic synthesis of delta-valerolactone (dvl) from furfural-derived 2-hydroxytetrahydropyran (hthp)
发明人:HUBER GEORGE; DASTIDAR RAKA; JOHNSTONE SAM; MCCLELLAND DANIEL
权利人:WISCONSIN ALUMNI RES FOUND
摘要:A method to make delta-valerolactone (“DVLâ€?) by dehydrogenating 2-hydroxytetrahydropyran (“HTHPâ€?). The HTHP is contacted with a supported-metal catalyst for a time, at a temperature, and at a pressure wherein at least a portion of the HTHP is converted to DVL via dehydrogenation of the HTHP. The HTHP may be derived from biomass. Thus, the method yields DVL without requiring a petroleum-based feedstock.

专利号:US-2023278976-A1
优先权日:2021-07-05
标题:Synthesis Of Beta-Glycolipid Compounds
发明人:BOXLEY CHETT; STOLLEY RYAN; BRUGGEMAN ROBERT
权利人:GLYCOSURF INC
摘要:Methods of forming a glycolipid are disclosed. A method may include glycosylating a sugar with a beta-hydroxyester using BF3-L as a glycosylation promoter. L may include one or more of Diethylether, Tetrahydrofurn, Dimethyle Sulfide, or combinations thereof. The beta-hydroxyester may include a carbon length ranging from C2 to C24. The sugar may be a protected sugar that includes peracetylated-rhamnose, peracetylated-xylose, peracetylated-glucose, peracetylated-galactose or combinations thereof. The beta-hydroxyester and sugar may be combined in a reaction vessel to form a mixture. A solvent may be added to the mixture to substantially dissolve the mixture. The glycosylation promoter may be added to the solution such that the solution is maintained withing a desired temperature range.

专利号:US-10745675-B2
优先权日:2017-05-02
标题:Modified enzymes for producing increased isomelezitose
发明人:COTE GREGORY L; SKORY CHRISTOPHER D
权利人:THE UNITED STATES OF AMERICA AS REPRESENTED BY THE SECRETARY OF AGRICULTURE
摘要:Provided herein are compositions and methods for the synthesis of the trisaccharide, isomelezitose, using genetically modified glucansucrase enzymes from representative microorganisms, including lactic acid bacteria such as Leuconostoc mesenteroides . Various modified enzymes are detailed, increasing isomelezitose yields and provide the foundation for large-scale production of isomelezitose for food, industrial and biomedical applications.

专利号:US-11473116-B2
优先权日:2018-02-23
标题 :Synthesis of glucan comprising alpha-1,3 glycosidic linkages with phosphorylase enzymes
发明人:YU ZHEYONG; KRALJ SLAVKO; ZHANG ZHENGHONG; HOWE LAURIE A
权利人:NUTRITION & BIOSCIENCES USA 4 INC
摘要:Reaction compositions are disclosed herein comprising at least water, beta-glucose -1-phosphate (beta-G1P), an acceptor molecule, and an alpha-1,3-glucan phosphorylase enzyme. These reactions can synthesize oligosaccharides and polysaccharides with alpha-1,3 glycosidic linkages. Further disclosed are alpha-1,3-glucan phosphorylase enzymes and methods of use thereof.
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主要参考文献

[参考文献]: Ooshima T, Et Al. Non-Cariogenicity Of The Disaccharide Palatinose In Experimental Dental Caries Of Rats. Infect Immun. 1983 Jan;39(1):43-9.

合成参考文献


参考文献:10.1007/bf01308064
摘要:Ringrose RE, Preiser H, Welsh JD. Sucrase-isomaltase (palatinase) deficiency diagnosed during adulthood. Digestive Diseases and Sciences. 1980 May;25(5):384–7. doi: 10.1007/bf01308064.
参考文献:10.1007/s00253-014-5816-2
摘要:Mu W, Li W, Wang X, Zhang T, Jiang B. Current studies on sucrose isomerase and biological isomaltulose production using sucrose isomerase. Applied Microbiology and Biotechnology. 2014 May 28;98(15):6569–82. doi: 10.1007/s00253-014-5816-2.
参考文献:10.1007/s00394-015-1072-1
摘要:Tey SL, Van Helvoort A, Henry CJ. Glycaemic responses to liquid food supplements among three Asian ethnic groups. European Journal of Nutrition. 2015 Oct 14;55(8):2493–8. doi: 10.1007/s00394-015-1072-1.
参考文献:10.1007/s13197-021-05067-8
摘要:Laokuldilok N, Surin S, Damrongwattanakool N. Effect of using riceberry flour and xanthan gum on physical properties and estimated glycemic index of steamed rice cakes: optimization by D-optimal mixture design approach. Journal of Food Science and Technology. 2021 Apr 20;59(2):724–34. doi: 10.1007/s13197-021-05067-8.
参考文献:10.1007/s00792-006-0021-6
摘要:Jorge CD, Sampaio MM, Hreggvidsson GO, Kristjánson JK, Santos H. A highly thermostable trehalase from the thermophilic bacterium Rhodothermus marinus. Extremophiles. 2007 Jan;11(1):115–22. doi: 10.1007/s00792-006-0021-6.
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