CAS: 78-35-3; Linalyl Isobutyrate
该化合物是一种单极酯酯,产自异丁醇和异丁酸,通常用于香味和口味配方,其化学结构(C14H24O2)具有甜,果和花粉芳香,含有微妙的草药底,在香水和食品口味中具有价值;该化合物在典型的加工条件下具有良好稳定性,确保各种应用的一贯性;其低挥发性和中度耐久性有助于化妆品和家用产品中长期的气味保持;作为合成替代品,利那利异丁酸提供了与自然提取物相比的可复制性和成本效率,同时保持类似的有机植物特性;该化合物一般认为在符合浓度的条件下使用该酯是安全的.
- 英文名称Linalyl Isobutyrate
- 中文名称3,7-二甲基辛-1,6-二烯-3-基异丁酸盐
- IUPAC名称3,7-dimethylocta-1,6-dien-3-yl isobutyrate
- 其它别名1,5-Dimethyl-1-Vinyl-4-Hexenyl 2-Methylpropanoate; 1,6-Octadien-3-Ol, 3,7-Dimethyl-, Isobutyrate; 3,7-Dimethyl-1,6-Octadien-3-Yl Isobutyrate; 3,7-Dimethyl-1,6-Octadien-3-Ylisobutyrate; 3,7-Dimethyl-1,6-Octadienyl Isobutyrate; 3,7-Dimethyl-1,6-Octadienylisobutyrate; Linalyl Isobutyrate; 1,5-Dimethyl-1-Vinylhex-4-Enyl Isobutyrate
- CAS编号78-35-3
- MFCD编号:MFCD00048312
- EINECS号:201-108-2
- FDA UNII编号:8867Y4G46L
- 分子式:C14H24O2分子量:224.34
- 产品CID: 1778728
- 产品分类有机原料→分子砌块→脂肪链类化合物
相似化合物
115-95-7 144-39-8 144-39-8物理性质
- 熔点< -20 °C
- 沸点305.75 °C at 760 mmHg
- 闪点73.3°C
- 密度0.89g/cm3
- PSA:26.3
- LogP:3.8767
- 折射率1.453
- 蒸汽压3.5-6.1Pa at 20-25°C
- 溶解性insoluble in water; miscible with alcohol and ether
- 储存条件2-8°C, stored under nitrogen
- 产品应用异丁酸芳樟酯(78-35-3)的用途:GB 2760―1996规定为允许使用的食用香料.主要用以配制黑穗状醋栗,樱桃和浆果类等型香精.
- 性质描述异丁酸芳樟酯(78-35-3)的性状:1.无色至微黄色液体.呈水果和鲜玫瑰花香气,有水果甜味.2.沸点230°C.混溶于乙醇,乙醚和氯仿,不溶于水.毒性:1.LD5015100mg/kg(小鼠,经口).2.GRAS(FEMA).
MSDS等安全信息
欧盟法规
REACH注册ECHA物质C&L通报REACH预注册上下游产品
isobutyric acid-(1-ethynyl-1,5-dimethyl-hex-4-enyl ester) 3,7-dimethyl°Cta-1,6-dien-3-ol isobutyryl chloride 3,7-dimethyl°Ct-6-en-1-yn-3-ol(5E)-3-hydroxy-3,7-dimethyl-3-hydroxy-1,5,7-°Ctatriene合成工艺路线路线简述
- 合成目标产物 Linalyl Isobutyrate 主要起始原料 3,7-Dimethyloct-6-En-1-Yn-3-Ol
- (文献来源)合成步骤主要原料 3,7-Dimethyloct-6-En-1-Yn-3-Ol
📜3,7-二甲基-6-辛烯-1-炔基-3-醇置于喹啉,Lindlar'S Catalyst,正己烷,磷酸体系中,化学反应生成 异丁酸芳樟酯
参考文献:Tertiary Esters And Preparation Thereof
标题:Tertiary Esters And Preparation Thereof
海关参考信息
- 2901210000-乙烯
2901220000-丙烯
2905122000-异丙醇
2905143000-叔丁醇 - 💡 提示：海关信息按照顺序优先匹配，如需确认的海关信息，请参考相关资料。
- 详情请参考：📖 海关编码查询和海关进出口税则
专利信息
专利号:US-2021206711-A1
优先权日:2020-01-03
标 题:Synthesis of the Grape Mealybug Pheromone trans-alpha-Necrodyl Isobutyrate
发明人：CHEBNY VINCENT JAMES
权利人:TRECE INC
摘要:Methods are provided for synthesizing the grape mealybug pheromone, trans-α-necrodyl isobutyrate, starting with essential plant oils that contain trans-α-necrodyl acetate. The synthesis method, in two steps, converts the trans-α-necrodyl acetate to trans-α-necrodol and then converts the trans-α-necrodol to the desired trans-α-necrodyl isobutyrate. The first step can be achieved by either of a hydrolysis reaction or a reduction reaction. In the hydrolysis reaction, the essential oil is mixed in an alcohol solvent with a hydroxide base, or by mixing the essential oil in an aqueous acid. A reduction reaction can instead by performed in an organic solvent in the presence of a reducing agent. The trans-α-necrodol is converted to the desired trans-α-necrodyl isobutyrate by an esterification reaction with a carboxylic acid, an acyl halide, or an acid anhydride.
专利号:US-4294727-A
优先权日:1979-05-05
标 题 :Perfume composition containing 4,5-dioxa-5-alkyl-tricyclo[7.2.1.0 2,8 ]dodec-10-enes and its use as an odorant
发明人：CONRAD JENS; UPADEK HORST; BRUNS KLAUS
权利人:HENKEL KGAA
摘要:This invention is directed to perfume compositions comprising 4,6-dioxa-5-C1-C8-alkyl or C2-C8-alkenyl-tricyclo[7.2.1.02,8]dodec-10-enes, the use of said tricyclododecenes as an odorant, the synthesis of said tricyclododecenes, and novel tricyclododecenes.
供应商参考报价(招募中)
品牌试剂参考报价(招募中)
📌 第三方产品分析报告
合成参考文献
摘要:Food and Cosmetics Toxicology., 2(327), 1964
摘要:Food and Cosmetics Toxicology., 13(835), 1975
📝 需求与反馈
尽可能描述清楚需求与问题信息
