Magnesium,Ethoxybenzene,Bromide置于环氧乙烷,氢氧化钾,乙醚,对苯二酚体系中,化学反应生成 4-乙氧基苯乙烯 参考文献:Seeing Is Believing: Questions Of Archaeological Visibility In The Mediterranean 标题:Seeing Is Believing: Questions Of Archaeological Visibility In The Mediterranean 摘要: DOI:10.1017/s0003598X00090402
专利号:US-5510516-A 优先权日:1990-07-06 标 题 :Process for selective epoxidation of unsaturated (meth)acrylates, new functional (meth)acrylates obtained and their application to the synthesis of new polymers 发明人:CAUBERE PAUL; FORT YVES; ORTAR AGNES 权利人:ATOCHEM 摘要:An unsaturated (meth) acrylic compound of formula: (I) (X=O, S, NH, NR3 (R3=C1-12-alkyl) or O-(CH2)n (where n=1-16 approximately); R2=C2-20 straight-chain or branched alkyl, monocyclic or polycyclic cycloalkyl or heterocycloalkyl, or alkylaryl hydrocarbon chain, comprising an olefinic double bond in the chain, or at the end of the chain in the case of alkyl or alkylaryl, or an exocyclic or endocyclic olefinic double bond in the case of monocyclic or polycyclic cycloalkyl or heterocycloalkyl; and R1=H or C1-5-alkyl), is reacted at 10 DEG -60 DEG C. with at least one oxidising compound (hydrogen peroxide) in the presence of at least one catalyst (alkali metal molybdates and tungstates) and in the presence of at least one phase transfer agent and when R2=polycyclic cycloalkyl or hetercycloalkyl, an organic peracid or hydrogen peroxide in the presence of at least one heteropolyacid. To open the epoxide function, the epoxide obtained is reacted with a compound chosen from strong inorganic acids, boron trifluoride etherate complexes, acid salts in the presence of the corresponding acid, halides of trialkylsilanes or trialkoxysilanes, and ketones in the presence of cationic resins.
专利号:US-3573253-A 优先权日:1968-11-18 标题:Preparation of cross-linked poly (4-hydroxy - 3 - nitro) (nonsubstituted or alpha and/or beta substituted) stryene 发明人:GRAY DON N 权利人:DON N GRAY 摘要:THERE IS DISCLOSED A PROCESS FOR PREPARING A SOLID PHASE, POLYMERIC SUBSTRATE COMPRISING A CROSS-LINKED POLY (4HYDROXY-3-NITRO) STYRENE WHICH IS ESPECIALLY SUITABLE FOR THE SYNTHESIS OF POLYPEPTIDES. THE POLYSTYRENE MAY BE NONSUBSTITUTED OR SUBSTITUTED (ALPHA AND/OR BETA).
专利号:JP-H0778100-B2 优先权日:1990-06-27 标题 :Novel sulfur-containing acrylic compounds, a process for their preparation and their use in the synthesis of new polymers
专利号:FR-2664272-A1 优先权日:1990-07-06 标 题:PROCESS FOR THE SELECTIVE EPOXIDATION OF UNSATURATED (METH) ACRYLATES, FUNCTIONAL (METH) ACRYLATES OBTAINED AND THEIR APPLICATION TO THE SYNTHESIS OF NEW POLYMERS.
专利号:IT-SA20120007-A1 优先权日:2012-05-16 标题 :SYNTHESIS OF POLIALCHILSOLFONATI TO BE INTENDED FOR THE PRODUCTION OF IONOMERS AND POLYELETTROLITES BY SELECTIVE SULFONATION OF POLYDIENES AND COPOLYMERS OF CONJUGATED DIENS.
专利号:CN-107602415-A 优先权日:2017-09-25 标 题:A kind of Fe(â…¢) porphyrin-catalyzed method for the one-pot synthesis of aromatic nitriles by oxidizing aromatic olefins with nitrite