CAS: 50286-30-1; (E)-9-Tetradecenoicacid

上下游产品

Ethyl-tetradec-9-enoate 9-tetradecenyl alcohol(E)-Tetradec-9-enoyl chloride azelaic acid valeric acid

📜9,10-十四碳烯醇置于重铬酸吡啶体系中,用 N,N-二甲基甲酰胺 作为反应溶剂,化学反应 12.0H,反应生成 肉豆蔻烯酸
参考文献:亚洲玉米螟ostrinia Furnacalis 用于信息素生物合成的乙酰转移酶和还原酶系统的底物特异性.
标题:亚洲玉米螟ostrinia Furnacalis 用于信息素生物合成的乙酰转移酶和还原酶系统的底物特异性.
摘要:通过局部应用信息素腺体的前体,在体内研究了乙酰转移酶和还原酶系统在信息素生物合成中使用的 Ostrinia Furnacalis (Lepidoptera: Pyralidae) 的底物特异性.每个十四烯醇,双键位置(从 7 到 13)和双键的几何形状不同,都被乙酰转移酶转化为相应的乙酸盐.所有测试的脂肪醇转化率的相似性表明乙酰转移酶具有低底物特异性.大多数相应的十四碳烯酸也可以转化为相应的乙酸酯.然而,测试的脂肪酸之间非常不同的转化率表明还原酶系统比乙酰转移酶具有更高的底物特异性.大多数 E 异构体的转化率高于相应的 Z 异构体的转化率,但 (Delta)-11-十四碳烯酸除外,其中更多的 Z 异构体转化为产物.饱和十四烷酸以高速率转化为相应的乙酸盐;较短的同系物十三烷酸的转化率较低 (56%),而较长的同系物十五烷酸和十六烷酸各自的乙酸酯的转化率是微不足道的 (<5%).本研究的结果表
DOI:10.1007/bf02035148

专利信息

专利号:US-9643915-B2
优先权日:2013-03-15
标题:Methods for the synthesis of sphingomyelins and dihydrosphingomyelins
发明人：ONICIU DANIELA CARMEN; HECKHOFF STEFAN; OSWALD BENOIT; REBMANN PETER; PEER ANDREAS; GONZALEZ MIGUEL; SAUTER PATRIK
权利人:CERENIS THERAPEUTICS HOLDING SA
摘要:The present invention includes methods for the synthesis of sphingomyelins and dihydrosphingomyelins. The present invention also includes methods for the synthesis of sphingosines and dihydrosphingosines. The present invention further includes methods for the synthesis of ceramides and dihydroceramides.

专利号:US-9708354-B2
优先权日:2013-03-15
标 题:Methods for the synthesis of sphingomyelins and dihydrosphingomyelins
发明人：ONICIU DANIELA CARMEN; HECKHOFF STEFAN; OSWALD BENOIT; REBMANN PETER; PEER ANDREAS; GONZALEZ MIGUEL; SAUTER PATRIK
权利人:CERENIS THERAPEUTICS HOLDING SA
摘要:The present invention includes methods for the synthesis of sphingomyelins and dihydrosphingomyelins. The present invention also includes methods for the synthesis of sphingosines and dihydrosphingosines. The present invention further includes methods for the synthesis of ceramides and dihydroceramides.

专利号:EP-2198036-B1
优先权日:2007-09-20
标 题:Method for the synthesis of omega-unsaturated fatty acids
发明人：DUBOIS JEAN-LUC
权利人:ARKEMA FRANCE
摘要:The invention relates to a method for the synthesis of short-chain ω-unsaturated fatty acids of general formula CH2â•?CH—(CH2)n—COOR in which n is an integer between 2 and 11 and R is H or an alkyl radical containing from 1 to 4 carbon atoms, from long-chain monounsaturated fatty acids or esters of formula CH3—(CH2)m—CHâ•?CH—(CH2)p—COOR in which m and p are integers, either identical or different, between 2 and 11, such that the molecule contains at least 10 adjacent carbon atoms in the main chain, said method comprises the first step of submitting the long-chain monounsaturated fatty acid charge to an oxidation by fermentation using a microorganism containing enzymes of oxygenase type, thus leading to the formation of α,ω-diacids, and then a second step of subjecting the product from the first step to a catalytic metsthesis crossed with ethylene for forming two short-chain ω-unsaturated fatty acids having a main chain length relative to that of the starting unsaturated fatty acid or ester of beteen 0.2 and 0.8, and preferably 0.35 and 0.75.

专利号:US-2008300418-A1
优先权日:2004-11-08
标 题:Synthesis of Cardiolipin Analogues and Uses Thereof
发明人：AHMAD MOGHIS U; UKKALAM MURALI K; ALI SHOUKATH M; AHMAD IMRAN
权利人:AHMAD MOGHIS U; UKKALAM MURALI K; ALI SHOUKATH M; AHMAD IMRAN
摘要:The invention provides novel synthetic methodologies for preparing cardiolipin, migrated caridiolipin (1,2-positional isomer of cardiolipin) and their analogues having varying fatty acids and/or alkyl chains with varying length and degrees of saturation/unsaturation. The method comprises (a) reacting an optically pure 1,2-O-dialkyl-sn-glycerol or 1,2-O-dialkyl-sn-glycerol with one or more phosphoramidite reagent(s), wherein a phosphite triester is produced; (b) coupling the product of (a) with glycerol, wherein a protected cardiolipin is produced; and (c) deprotecting the protected cardiolipin, such that cardiolipin is prepared. The cardiolipins and analogues thereof, prepared by the present methods, can be incorporated into liposomes, which can also include active agents such as hydrophobic or hydrophilic drugs, antisense nucleotides or diagnostic agents. Such liposomes can be used to treat diseases or can be used in diagnostic and/or analytical assays.

专利号:US-2023330642-A1
优先权日:2020-02-18
标 题 :Synthesis of metallic materials imbedded in activated carbon to degrade chlorinated and fluorinated organic pollutants
发明人：AL-ABED SOUHAIL; MCKERNAN JOHN; LOMNICKI SLAWOMIR
权利人:US GOV AS REPRESENTED BY THE ADMINISTRATOR OF THE U S EPA
摘要:Catalyst materials comprising iron and palladium are described. Also described are methods for preparing such materials. In addition, methods for remediating materials such as sediments and groundwater using the catalyst materials are described.

专利号:US-2009099061-A1
优先权日:2006-01-27
标 题:Synthesis of carotenoid analogs or derivatives with improved antioxidant characteristics
发明人：FOSS BENTE J; NADOLSKI GEOFFRY T; LOCKWOOD SAMUEL F
权利人:FOSS BENTE J; NADOLSKI GEOFFRY T; LOCKWOOD SAMUEL F
摘要:A method is described for synthesizing and administering carotenoid compounds with improved antioxidant characteristics. In some embodiments, extension or improvement of conjugation may be employed in structural modification of carotenoids. In other embodiments, reduction of ring/chain steric hindrance may improve the lambda max, and hence, the overall antioxidant capability, of particular compounds. In other embodiments, introduction and/or increase in synthetic handles for conjugation may improve the stoichiometric ratios of conjugating moieties to the polyene backbone. The methods may be used to improve natural and/or synthetic compounds for medicinal application in the treatment of disease.