CAS: 3695-77-0; Triphenylmethanethiol

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CAS号1277170-50-9 (1,1-dimethylet... | CAS号1727-15-7 三苯基甲硫醇乙酸 | CAS号76-83-5 三苯基氯甲烷 | CAS号76-84-6 三苯基甲醇 | CAS号513-81-5 2,3-二甲基-1,3-丁二烯 | CAS号30615-54-4 magnesium,diphe... | CAS号35572-83-9 氯化三苯基甲基二硫化物 | CAS号24165-03-5 三苯基硫氯甲烷 | CAS号1727-16-8 thiobenzoic aci... | CAS号76-84-6 三苯基甲醇 | CAS号104-15-4 对甲苯磺酸 | CAS号180973-24-4 (3S,4E)-3-羟基-7-... | CAS号29167-36-0 [diphenyl(prop-... | CAS号29167-28-0 Ethanol,2-[(tri... | CAS号2461-95-2 1,4-Butanedione... | CAS号79-46-9 2-硝基丙烷 | CAS号6316-86-5 Nitroso trityl ... | CAS号80441-55-0 6-(三苯甲基硫基)己酸

N-Methyl-3-(Tritylthio)-Maleimide置于dl-Dithiothreitol,三乙胺体系中,用 四氢呋喃,水 作为反应溶剂,化学反应 0.25H,以96%的收率获得产物三苯甲硫醇
参考文献:A Mild And Selective Protecting And Reversed Modification Of Thiols
标题:A Mild And Selective Protecting And Reversed Modification Of Thiols
摘要:One Selective Thiol-Protecting Study Has Been Investigated For A Wide Range Of Thiols Including General Thiols And Thiols Containing Multiple Functional Groups. The Reactions Of Bromomaleimides And Thiols Under The Mild Condition Afforded The Protected Products In Excellent Yields. The Thiols Can Be Recovered Very Quickly Using Dithiothreitol (Dtt) Under The Mild Condition. (C) 2016 Elsevier Ltd. All Rights Reserved.
DOI:10.1016/j.Tetlet.2016.05.027

专利信息

专利号:US-2006287520-A1
优先权日:2005-05-16
标 题 :Synthesis of salinosporamide A and analogues thereof
发明人：DANISHEFSKY SAMUEL J; ENDO ATSUSHI
权利人:DANISHEFSKY SAMUEL J; ENDO ATSUSHI
摘要:A novel synthesis of salinosporamide A is provided. Salinospoamide A as well as structurally related natural products, omuralide and lactacystin, have been shown to be proteasome inhibitors. Therefore, these compounds as well as analogues of these natural products may be useful in the treatment of proliferative diseases such as cancer, autoimmune diseases, diabetic retinopathy, etc. The invention provides for the synthesis of salinosporamide A as well as analogs thereof using a convenient point for derivatization of the bicyclic core. Pharmaceutical compositions and method of using the inventive compounds are also provided.

专利号:US-11370736-B2
优先权日:2019-04-01
标 题:Synthesis of fluoro hemiacetals via transition metal-catalyzed fluoro ester and carboxamide hydrogenation
发明人：DUB PAVEL A; BATRICE RAMI J; GORDON JOHN C
权利人:TRIAD NAT SECURITY LLC
摘要:This application is directed to use of transition metal-ligand complexes to hydrogenate fluorinated esters and carboxamides into fluorinated hemiacetals. Methods for synthesis of certain ligands are also provided.

专利号:US-4783529-A
优先权日:1985-12-03
标题 :Rapid synthesis of radiolabeled porphyrin complexes for medical application
发明人：LAVALLEE DAVID K; MANSUY DANIEL; BATTIONI JEAN-PAUL
权利人:RES CORP TECHNOLOGIES INC
摘要:This invention relates to a novel method for the rapid synthesis of radiolabeled porphyrin complexes which are highly useful for biomedical application, i.e. conjugation to protein antibodies for use in tumor imaging and internal radiation therapy.

专利号:WO-9915510-A1
优先权日:1997-09-24
标 题:Protecting and linking groups for organic synthesis
发明人：TOTH ISTVAN; DEKANY GYULA; KELLAM BARRY
权利人:ALCHEMIA PTY LTD; TOTH ISTVAN; DEKANY GYULA; KELLAM BARRY
摘要:This invention relates to methods for synthesis of organic compounds, and in particular to compounds useful as protecting and linking groups for use in the synthesis of peptides, oligosaccharides, glycopeptides and glycolipids. The invention provides protecting and linking groups which are useful in both solid phase and solution synthesis, and are particularly applicable to combinatorial synthesis. In its most general aspect, the invention provides a cyclic compound of general formula (I).

专利号:US-6765089-B1
优先权日:1997-09-24
标 题 :Protecting and linking groups for organic synthesis on solid supports
发明人：TOTH ISTVAN; DEKANY GYULA; KELLAM BARRY
权利人:ALCHEMIA PTY LTD
摘要:This invention relates to methods for synthesis of organic compounds, and in particular to compounds useful as protecting and linking groups for use in the synthesis of peptides, oligosaccharides, glycopeptides and glycolipids. The invention provides protecting and linking groups that are useful in both solid phase and solution synthesis, and are particularly applicable to combinatorial synthesis.

专利号:US-2005014954-A1
优先权日:2001-11-22
标 题:Pyrrole synthesis
发明人：OHRLEIN REINHOLD; BAISCH GABRIELE
摘要:The invention relates to a novel process for the preparation of N-substituted pyrroles, especially of formula (V), wherein the radicals are as defined in the description, by intermolecular aza-Wittig reaction starting from organic azides and 1,4-dioxo compounds. The invention relates also to novel iminophosphorane intermediates for this synthesis. The resulting pyrroles are useful, for example, in the organic synthesis of pharmaceuticals or other active substances and chemicals.