CAS: 36159-03-2; 5,5',6,6'-Tetramethoxy-2,3-Dihydro-[1,2'-Biindenylidene]-1'(3'H)-One

该化合物是配对替代的异丙酮衍生物,其特点是其角氧功能组,由于它的同质系统和硬性双环结构,该复合物具有明显的稳定性,适合有机合成和材料科学的应用,其扩展的 --电子系统表明,在光电子材料方面可能具有潜在效用,这种结构往往显示出可取的电子特性,甲氧基组的存在增加了极有机溶剂中的溶性,有利于进一步的化学修改.该化合物可以作为合成更复杂的多环系统或协调化学的结链的前体,其明确界定的分子结构可以对先进的材料设计进行精确的结构控制.

英文名称5,5',6,6'-Tetramethoxy-2,3-Dihydro-[1,2'-Biindenylidene]-1'(3'H)-One
中文名称茚酮二聚体
IUPAC名称(E)-5,5',6,6'-tetramethoxy-2,3-dihydro-[1,2'-biindenylidene]-1'(3'H)-one
其它别名Donepezil Impurity 22; Donepezil Impurity 25/2-(2,3-Dihydro-5,6-Dimethoxy-1H-Inden-1-Ylidene)-2,3-Dihydro-5,6-Dimethoxy-1H-Inden-1-One; 1H-Inden-1-One, 2-(2,3-Dihydro-5,6-Dimethoxy-1H-Inden-1-Ylidene)-2,3-Dihydro-5,6-Dimethoxy-; (Z)-5,5',6,6'-Tetramethoxy-2,3-Dihydro-[1,2'-Biindenylidene]-1'(3'H)-One; 2-(2,3-Dihydro-5,6-Dimethoxy-1H-Inden-1-Ylidene)-2,3-Dihydro-5,6-Dimethoxy-1H-Inden-1-One; 5,5',6,6'-Tetramethoxy-2,3-Dihydro-[1,2'-Biindenylidene]-1'(3'H)-One; 5,5',6,6'-Tetramethoxy-2,3-Dihydro-[1,2'-Biindenylidene]-1'(3'H)-One
CAS编号36159-03-2
分子式:C22H22O5分子量:366.41
产品CID: 1370902
产品分类分析化学 → 标准品 → 药典标准品和杂质标准品

相似结构搜索
InChIKey: PNWVEHIOIQBPKR-SAPNQHFASA-N
InChI=1S/C22H22O5/c1-24-18-8-12-5-6-14(15(12)10-20(18)26-3)17-7-13-9-19(25-2)21(27-4)11-16(13)22(17)23/h8-11H,5-7H2,1-4H3/b17-14+
计算化学: 氢键受体数5.0氢键供体数*可旋转键数4.0

MSDS等安全信息

警示词warning
危险描述H303May be harmful if swallowed+H313Skin contact may be harmful+H333Inhalation may be harmful to the body
防范说明P264Thoroughly clean after treatmentP280Wear protective gloves/Wear protective clothing/Wear protective goggles/Wear a protective maskP305If it enters the eyesP351Rinse carefully with water for a few minutesP338Remove the contact lens(If any)And easy to operate,Continue flushingP337If eye irritation persistsP313Obtain medical advice/care
安全声明H303May be harmful if swallowed+H313Skin contact may be harmful+H333Inhalation may be harmful to the body

上下游产品

5,6-dimethoxy-1-indanone 5-methoxy-1-indanone

合成工艺路线路线简述

📜5,6-二甲氧基茚酮置于三氯化铝体系中,化学反应 0.25H,以65%的收率获得产物茚酮二聚体
参考文献:Indane Dimerization Products Obtained By Treatment Of N-Acylindan-1-Amines With Ethyl Polyphosphate (Epp)
标题:Indane Dimerization Products Obtained By Treatment Of N-Acylindan-1-Amines With Ethyl Polyphosphate (Epp)
摘要:本报告描述了将n-酰基印豆铵-1-胺与乙基聚磷酸酯在氯仿-二乙醚溶液中于80oc反应8小时所获得的多样化二聚体产物.讨论了这种反应的可能机制.
DOI:10.1039/a804707C