专利号:US-6916982-B2 优先权日:2000-07-21 标题:Synthesis of perylene-porphyrin building blocks and polymers thereof for the production of light-harvesting arrays 发明人:LOEWE ROBERT S; TOMIZAKI KIN-YA; LINDSEY JONATHAN S 权利人:UNIV NORTH CAROLINA STATE 摘要:The present invention provides methods, compounds, and compositions for the synthesis of light harvesting arrays, such arrays comprising: (a) a first substrate comprising a first electrode; and (b) a layer of light harvesting rods electrically coupled to said first electrode, each of said light harvesting rods comprising a polymer of Formula I:n nX 1 X m+1 ) m   (I)n nwherein m is at least 1; X 1 is a charge separation group, and X 2 through X m+1 are chromophores. At least one of X 2 through X m+1 has at least one perylene group coupled thereto.
专利号:US-2003075216-A1 优先权日:2000-07-21 标题 :Synthesis of perylene-porphyrin building blocks and polymers thereof for the production of light-harvesting arrays
专利号:US-7329769-B2 优先权日:2001-07-13 标 题:Catalytic boronate ester synthesis from boron reagents and hydrocarbons 发明人:SMITH III MILTON R 权利人:UNIV MICHIGAN STATE 摘要:A process for producing a ring-substituted arene borane which comprises reacting a ring-substituted arene with an HB organic compound in the presence of a catalytically effective amount of an iridium or rhodium complex with three or more substituents, excluding hydrogen, bonded to the iridium or rhodium and a phosphorus organic ligand, which is at least in part bonded to the iridium or rhodium, to form the ring-substituted arene borane. Also provided are catalytic compounds for catalyzing the process comprising an iridium or rhodium complex with three or substituents, excluding hydrogen, bonded to the iridium or rhodium and optionally, a phosphorus organic ligand, which is at least in part bonded to the iridium or rhodium.
专利号:US-7122694-B2 优先权日:1998-11-06 标 题 :Hydroboronation process 发明人:MARCUCCIO SEBASTIAN MARIO; RODOPOULOS MARY; WEIGOLD HELMUT 权利人:BORON MOLECULAR PTY LTD 摘要:The invention relates to processes for the synthesis of aryl or alkene borates which comprises reacting: (i) an olefinic compound having a halogen or halogen-like substituent in a vinylic substitution position, or (ii) an aromatic ring having a halogen or halogen-like substituent in a ring substitution position, with a disubstituted monohydroborane in the presence of a Group 8-11 metal catalyst. The invention also relates to the use of these borates in coupling reactions. The invention further relates to certain disubstituted monohydroboranes and aryl or alkene borates.
专利号:WO-03105237-A1 优先权日:2002-06-06 标 题:Synthesis of perylene-porphyrin building blocks and polymers thereof for the production of light-harvesting arrays
专利号:US-7102017-B2 优先权日:2004-06-10 标 题 :Processes to prepare small molecular thiophene compounds 发明人:LIU PING; WU YILIANG; ONG BENG S; BIRAU MARIA 权利人:XEROX CORP 摘要:A process composed of subjecting a reaction mixture comprising a reaction medium, a coupling agent, and a precursor to a coupling temperature to preferentially form a desired small molecular thiophene compound in a single-step synthesis, wherein the precursor consists of: (i) an optional divalent linkage, and (ii) a plurality of thiophene units, each thiophene unit being represented by structure (A) n nwherein each thiophene unit is bonded at either or both of the second ring position and the fifth ring position.