CAS: 849245-34-7; 5-Hydroxy-4-((E)-2-((1S,4As,8As)-5,5,8A-Trimethyl-2-Methylenedecahydronaphthalen-1-yl)Vinyl)Furan-2(5H)-One

英文名称5-Hydroxy-4-((E)-2-((1S,4As,8As)-5,5,8A-Trimethyl-2-Methylenedecahydronaphthalen-1-yl)Vinyl)Furan-2(5H)-One
中文名称4-[(1E)-2-[(1S,4AS,8AS)-十氢-5,5,8A-三甲基-2-亚甲基-1-萘基]乙烯基]-5-羟基-2(5H)-呋喃酮
IUPAC名称5-hydroxy-4-((E)-2-((1S,4aS,8aS)-5,5,8a-trimethyl-2-methylenedecahydronaphthalen-1-yl)vinyl)furan-2(5H)-one
其它别名Chinensine B; 4-[(1E)-2-[(1S,4As,8As)-Decahydro-5,5,8A-Trimethyl-2-Methylene-1-Naphthalenyl]Ethenyl]-5-Hydroxy-2(5H)-Furanone; 3-[(E)-2-[(1S,4As,8As)-5,5,8A-Trimethyl-2-Methylidene-3,4,4A,6,7,8-Hexahydro-1H-Naphthalen-1-Yl]Ethenyl]-2-Hydroxy-2H-Furan-5-One; 2(5H)-Furanone, 4-[(1E)-2-[(1S,4As,8As)-Decahydro-5,5,8A-Trimethyl-2-Methylene-1-Naphthalenyl]Ethenyl]-5-Hydroxy-
CAS编号849245-34-7
MFCD编号:MFCD20260696
分子式:C20H28O3分子量:316.44
产品CID: 1840724
产品分类天然产物 → 萜类

相似结构搜索
InChIKey: KJUPGEKTXQYTSU-AKHYNURPSA-N
InChI=1S/C20H28O3/c1-13-6-9-16-19(2,3)10-5-11-20(16,4)15(13)8-7-14-12-17(21)23-18(14)22/h7-8,12,15-16,18,22H,1,5-6,9-11H2,2-4H3/b8-7+/t15-,16-,18?,20+/m0/s1
计算化学: 氢键受体数3.0氢键供体数1.0可旋转键数2.0

MSDS等安全信息

危险描述H303 May be harmful if swallowed+H313 Skin contact may be harmful+H333 Inhalation may be harmful to the body
防范说明P264+P280+P305+P351+P338+P337+P313
危险品标志Xi
安全声明H303+H313+H333

上下游产品

(17),11,13,(16)14-labdatetraene[(5S,9S,10S)-11(E)]-15,16-epoxy-8(17),11,13,(16)14-labdatetraene 8α-hydroxy-15,16-epoxy-labda-13(16),14-dien-12-one (3aR)-(+)-sclareolide

合成工艺路线路线简述

117591-81-8 = 849245-34-7
反应条件:1.1 Solvents: Acetone; Cooled
标题:Cytotoxic Labdane-Type Diterpenes And Diterpene Derivative From Hedychium Villosum
作者:Zhao,Qing; Zou,Cheng; Yu,Qin; Zhao,Sheng-Ding; He,Hong-Ping; Et Al
参考文献:Gaodeng Xuexiao Huaxue Xuebao 日期:2012 卷标:33(6) 页码:1220-1225]

117591-81-8 = 849245-34-7 + 194665-46-8
反应条件:1.1 Reagents: Butyllithium Solvents: Tetrahydrofuran; -15 °C; 10 Min,-15 °C1.2 Reagents: Chlorotrimethylsilane; -15 °C -> Rt1.3 Reagents: Sodium Chloride1.4 Reagents: Oxygen Solvents: Dichloromethane; 2 Min,0 °C
标题:Synthesis Of Chinensines A-E
作者:Margaros,Ioannis; Vassilikogiannakis,Georgios
参考文献:Journal Of Organic Chemistry 日期:2007 卷标:72(13) 页码:4826-4831