CAS: 100125-12-0; 3,8-Dibromo-1,10-Phenanthroline

相似化合物

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上下游产品

CAS号66-71-7 1,10-菲罗啉 | CAS号3829-86-5 邻菲啰啉盐酸盐 | CAS号139399-67-0 3-溴喹啉-8-胺 | CAS号408529-03-3 3,3-diacetoxy-2... | CAS号209795-84-6 3,8-bis(4-metho... | CAS号876661-11-9 3-bromo-8-(4-me... | CAS号1001330-07-9 3,8-bis(2,3-dih... | CAS号168003-69-8 3,8-bis(2-pheny... | CAS号676578-10-2 3,8-dibromo-2-m... | CAS号602331-25-9 3,8-二溴-1,10-菲罗啉... | CAS号602331-26-0 3,8-dibromo-1,1... | CAS号640297-84-3 3,8-二乙炔基-1,10-菲咯啉

1,10-菲罗啉置于二氯化二硫,氯丁烷,溴体系中,化学反应生成3,8-二溴菲罗啉
参考文献:二吡啶稠合喹喔啉酰亚胺 (Dpqi):N 型聚合物半导体的强吸电子结构单元
标题:二吡啶稠合喹喔啉酰亚胺 (Dpqi):N 型聚合物半导体的强吸电子结构单元
摘要:在这项工作中,我们设计并合成了一种新型的缺电子结构单元,联吡啶稠合喹喔啉酰亚胺(dpqi).随着氮原子并入喹喔啉酰亚胺的 π 共轭骨架上,前沿分子轨道 (Fmo) 能级下降.分别合成了基于dbqi和dpqi的两种受体-受体聚合物p(Bti-Dbqi)和p(Bti-Dpqi).
Doi:10.1002/asia.202301009

专利信息

专利号:US-12351548-B2
优先权日:2019-11-29
标 题:Method for preparing carbonyl sulfone
发明人：WAN XIAOBING; WANG HANGHANG; ZHENG YONGGAO; LIAN PENGCHENG; LI JINGJING
权利人:UNIV SOOCHOW
摘要:Disclosed is a method for preparing β-carbonyl sulfones. The method comprises: by taking an α-carbonyl diazo compound and sodium arylsulfinate as reaction substrates, cheap silver nitrate as an optimal catalyst, 1,10-phenanthroline as a ligand, and potassium persulfate as an oxidant, carrying out coupling reaction in a mixed solvent of acetonitrile and water to obtain a β-carbonyl sulfones compound. Compared with the prior art, the method has the following advantages: a wide range of reaction substrates, short reaction time, a relatively high reaction yield, a mild reaction condition, etc. In the present invention, non-toxic and harmless reagents are used as reaction raw materials, so that it has no harm to the environment and satisfies the requirements of contemporary green chemistry development. Post-reaction treatment is relatively simple, and is convenient for separation and purification. In addition, the reaction can achieve gram-scale synthesis, and lays a foundation for actual applications.

专利号:CN-119684290-A
优先权日:2024-12-19
标题 :Synthesis method of compound 3,8-dibromophenanthroline and compound

专利号:CN-118165288-A
优先权日:2024-03-28
标 题 :Continuous microfluidic channel synthesis method of hydrogen production catalyst