CAS: 879-05-0; Magnesium,1,2,3,4,5-Pentafluorobenzene-6-Ide,Bromide

该化合物是一种高度活性有机金属化合物,主要用于合成有机物和有机素化学,其主要优点包括能够作为多用途核素或交叉反应基体,特别是将五氟联苯组引入目标分子.该化合物的强电子退出五氟联苯运动会增强青光度型变异的回动性,使其对建筑复杂的氟化结构很有价值.由于对水分和空气的敏感性,它通常在惰性条件下处理. 这种试剂在制药和材料科学研究中特别有用,因为精确的氟化对于分子特性的调控至关重要.

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上下游产品

CAS号344-04-7 溴五氟苯 | CAS号363-72-4 五氟苯 | CAS号75-26-3 2-溴丙烷 | CAS号925-90-6 乙基溴化镁 | CAS号392-56-3 六氟苯 | CAS号814-68-6 丙烯酰氯 | CAS号344-07-0 氯五氟苯 | CAS号927-77-5 丙基溴化镁 | CAS号1015-53-8 Trimethyl(penta... | CAS号1110-39-0 2,4,6-tris(2,3,... | CAS号10177-65-8 dibromo-bis(2,3... | CAS号1065-49-2 四(五氟苯基)锡烷 | CAS号1452-12-6 Germane,tetraki... | CAS号5122-16-7 2-溴-2',3',4',5'... | CAS号22474-69-7 Bis(pentafluoro... | CAS号18005-77-1 1-bis(2,3,4,5,6... | CAS号1799-90-2 二(五氟苯基)锌 | CAS号1944-05-4 2,3,4,5,6-五氟二苯基甲醛

合成工艺路线路线简述

  • 344-04-7 = 879-05-0
    反应条件:1.1 Reagents: Ethylmagnesium Bromide Solvents: Tetrahydrofuran
    标题:Syntheses And Spectroscopic Characteristics Of Bis-[dimethyl(Aryl)Silylmethyl]Platinum(Ii) And Bis-[dimethyl(Benzyl)Silylmethyl]Platinum(Ii) Complexes With Diene-,Nitrogen-,And Phosphorus-Donor Ligands
    作者:Ankianiec,Bernardeta C.; Et Al
    参考文献:Polyhedron 日期:1995 卷标:14(2) 页码:249-65]

    344-04-7 = 879-05-0 + 17436-90-7
    反应条件:1.1 Reagents: Ethylmagnesium Bromide Solvents: Diethyl Ether; 2 H,22 °C
    标题:Preparation Of Heptafluoronaphthyllithiums And -Magnesiums: An Unexpected Difference In The Reactivity Of Isomers C10F7H And C10F7Br Towards Organolithium And Organomagnesium Compounds
    作者:Shmakov,Mikhail M.; Et Al
    参考文献:Journal Of Organometallic Chemistry 日期:2019 卷标:899]

    925-90-6 + 363-72-4 = 879-05-0 + 17436-90-7
    反应条件:1.1 Solvents: Tetrahydrofuran
    标题:Method Of Producing Pentafluorophenylmagnesium Derivatives Using Pentafluorobenzene
    参考文献:European Patent Organization]

    941-78-6 = 879-05-0 + 17436-90-7
    反应条件:1.1 Solvents: Diethyl Ether,Tetrahydrofuran; 3 H,22 °C2.1 Reagents: Phenylmagnesium Bromide Solvents: Diethyl Ether; 3 H,22 °C
    标题:Transmetalation Of Pentafluorophenylmercury Derivatives With Organylmagnesium Bromides
    作者:Bardin,V. V.
    参考文献:Russian Journal Of General Chemistry 日期:2019 卷标:89(7) 页码:1406-1408]

    925-90-6 + 941-78-6 = 879-05-0 + 17436-90-7
    反应条件:1.1 Solvents: Diethyl Ether,Tetrahydrofuran; 5 H,22 °C2.1 Solvents: Diethyl Ether; 3 H,22 °C3.1 Reagents: Phenylmagnesium Bromide Solvents: Diethyl Ether; 3 H,22 °C
    标题:Transmetalation Of Pentafluorophenylmercury Derivatives With Organylmagnesium Bromides
    作者:Bardin,V. V.
    参考文献:Russian Journal Of General Chemistry 日期:2019 卷标:89(7) 页码:1406-1408]

    363-72-4 = 879-05-0
    反应条件:1.1 Reagents: Magnesium Solvents: Diethyl Ether
    标题:Process For The Preparation Of Fluorinated Arylmagnesium Derivatives And Fluorinated Arylboron Compounds
    参考文献:World Intellectual Property Organization]

    1534-67-4 = 879-05-0 + 17436-90-7
    反应条件:1.1 Reagents: Phenylmagnesium Bromide Solvents: Diethyl Ether; 3 H,22 °C
    标题:Transmetalation Of Pentafluorophenylmercury Derivatives With Organylmagnesium Bromides
    作者:Bardin,V. V.
    参考文献:Russian Journal Of General Chemistry 日期:2019 卷标:89(7) 页码:1406-1408]

    973-17-1 = 879-05-0 + 17436-90-7
    反应条件:1.1 Solvents: Diethyl Ether; 3 H,22 °C2.1 Reagents: Phenylmagnesium Bromide Solvents: Diethyl Ether; 3 H,22 °C
    标题:Transmetalation Of Pentafluorophenylmercury Derivatives With Organylmagnesium Bromides
    作者:Bardin,V. V.
    参考文献:Russian Journal Of General Chemistry 日期:2019 卷标:89(7) 页码:1406-1408]

    973-17-1 = 879-05-0 + 1534-67-4 + 17436-90-7
    反应条件:1.1 Solvents: Diethyl Ether; 3 H,22 °C
    标题:Transmetalation Of Pentafluorophenylmercury Derivatives With Organylmagnesium Bromides
    作者:Bardin,V. V.
    参考文献:Russian Journal Of General Chemistry 日期:2019 卷标:89(7) 页码:1406-1408]

    1534-67-4 + 6507-52-4 = 879-05-0 + 363-72-4 + 17436-90-7
    反应条件:1.1 Reagents: Ethylmagnesium Bromide Solvents: Diethyl Ether; 18 H,22 °C
    标题:Transmetalation Of Pentafluorophenylmercury Derivatives With Organylmagnesium Bromides
    作者:Bardin,V. V.
    参考文献:Russian Journal Of General Chemistry 日期:2019 卷标:89(7) 页码:1406-1408]

    925-90-6 + 6507-52-4 = 879-05-0 + 17436-90-7
    反应条件:1.1 Solvents: Diethyl Ether; 5 H,22 °C
    标题:Transmetalation Of Pentafluorophenylmercury Derivatives With Organylmagnesium Bromides
    作者:Bardin,V. V.
    参考文献:Russian Journal Of General Chemistry 日期:2019 卷标:89(7) 页码:1406-1408
📜五氟苯置于magnesium,2-溴丙烷体系中,用 四氢呋喃 作为反应溶剂,化学反应 2.0H,反应生成 五氟苯基溴化镁
参考文献:Process For Preparing A Tetrakis(Fluoroaryl) Borate Derivative
标题:Process For Preparing A Tetrakis(Fluoroaryl) Borate Derivative
摘要:通式(1)所表示的是一种氟芳基镁衍生物,其中r1-R5分别表示氢原子,氟原子,烃基或烷氧基,而至少有一个r1-R5表示氟原子,Xa表示氯原子,溴原子或碘原子; 通式(2)所表示的是一种硼卤化物:Bxb3(2),其中xb表示氟原子,氯原子,溴原子或碘原子.它们在含有乙醚和/或四氢呋喃的溶剂(a)中反应,然后将所得的反应溶液加入沸点高于乙醚和/或四氢呋喃的溶剂(b)中,同时蒸馏出乙醚和/或四氢呋喃.因此,现在可以得到一种(氟芳基)硼烷化合物,其通式为(3):其中r1-R5和xb的含义与上述相同,N表示2或3,从中可以以低成本简单地选择性地分离和去除作为副产物的镁卤化物.

专利信息


专利号:WO-9817611-A1
优先权日:1996-10-25
标题 :Synthesis of perfluoro aromatic boranes and borates

专利号:WO-9822475-A1
优先权日:1996-11-21
标题:Synthesis of fluorophenyl boranes

专利号:EP-0880490-A4
优先权日:1996-10-25
标 题 :Synthesis of perfluoro aromatic boranes and borates

专利号:EP-0901495-A4
优先权日:1996-11-21
标题:SYNTHESIS OF FLUOROPHENYL-BORANES

专利号:EP-0901495-A1
优先权日:1996-11-21
标 题 :Synthesis of fluorophenyl boranes

专利号:EP-0880490-A1
优先权日:1996-10-25
标 题:Synthesis of perfluoro aromatic boranes and borates

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合成参考文献


摘要:Gagnon, A.; Benoit, E.; Le Roch, A., Science of Synthesis Knowledge Updates, (2018) 4, 2.
摘要:Gagnon, A.; Benoit, E.; Le Roch, A., Science of Synthesis Knowledge Updates, (2018) 4, 23.
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